40CrNiMo钢淬火组织的Mssbauer谱研究

用室温透射Mossbauer谱研究了不同条件下淬火处理对钢中马氏体基体组织、残留奥氏体量和其含碳量的影响规律,阐明了高温直接淬火和形变淬火处理提高强韧性的效果与残留奥氏体量无明显关系。     

Fe-Ni-Al-Ti半硬磁合金中的顺磁相和磁硬化

用穆斯堡尔谱学、X射线衍射及电解萃取等实验方法研究了Fe-Ni-Al-Ti半硬磁合金在加工过程中相结构的变化。1050℃淬火态合金为具有体心立方结构的单一的铁磁固溶体,其穆斯堡尔谱为峰形不对称的宽六指峰。第一次冷轧和700℃软化回火后有合金元素自母体脱溶,穆斯堡尔谱上开始出现顺磁峰。再经第二次冷轧和650℃最终回火,穆斯堡尔谱中的顺磁峰明显增高,而六指峰明显变窄,结合X射线衍射分析,可以确定回火时有相当多含铁的NiAl相和Ni_3Al或Ni_3(Al,Ti)相粒子生成。由透射电子显微镜观察,可看到这些细小的颗粒状粒     

MSSBAUER INVESTIGATION ON QUENCHED STRUCTURES OF 40CrNiMo STEEL

用室温透射Mossbauer谱研究了不同条件下淬火处理对钢中马氏体基体组织、残留奥氏体量和其含碳量的影响规律,阐明了高温直接淬火和形变淬火处理提高强韧性的效果与残留奥氏体量无明显关系。     

关于拟合穆斯堡尔谱的AWMI法

解非线性最小二乘问题的常用算法是高斯-牛顿法。它的缺点是迭代的每一步都要进行逆矩阵运算,对参数初估值的要求也比较严。I.A.Slavic提出的不用逆矩阵运算的方法(简记为AWMI法),已被金慧娟等用于穆斯堡尔谱的拟合,认为收敛性很好,计算量也较小。 本文通过理论分析说明按AWMI法的参数修正方向比较接近于x~2量的最快速下降方向,因此在步长不太     

A STUDY OF THE HELIUM IMPLANTED INTO HR-1 STAINLESS STEEL BY PROTON ELASTIC SCATTERING

Small discs of type HR- 1 austenitic steel (OCr17Ni14MnMo) have been irradiated with 30-170 keV He+ for doses 1015- 1×1018/cm2 at 300K. 2.5 MeV enhanced proton backscattering, TEM, SEM and CEMS are used to investigate the He trapping, bubble structures and the phase stability. It is found that a maximum He concentration of -28 at. % was obtained after implantation with 70 keV He+ at a dose just below critical. The micro- Vickers hardnesses of irradiated layers decrease with increasing dose, particularly when dense bubbles formed. The isomer shift of CEMS increases in the negative direction after irradiation. The austenite is believed to be stable against radiation induced martensitic transformation.     

样品有限厚度穆斯堡尔谱失真的修正

将穆斯堡尔谱扣除背景后,用傅立叶分析对穆斯堡尔谱进行有限厚度修正,可以得到理想单色源无限薄样品的穆斯堡尔谱。对Ure-Flinn程序进行了改进。对下列各种样品的穆斯堡尔谱进行了厚度修正:(1)α-Fe标准样品;(2)不同厚度的α-Fe_2O_3样品(3,12、48mg/cm~2);(3)退火状态的Fe-4wt％V合金样品。经修正后各     

Tb10Co90非晶态合金的结晶过程

用电子显微术和差动扫描量热计法研究了Tb_(10)Co_(90)非晶态合金的结晶过程。电子显微镜研究结果表明,在样品表面,结晶相的产生和晶粒长大是在远低于用差动扫描量热     

The Mssbauer Effect of Y-Ba-Cu-Fe-O Superconductive Oxide

We have studied the Mossbauer effect ofYBa_2Cu_(2.88)Fe_(0.12)O_(7-x) superconductive oxide from78 to 273K. Two minima of recoilless fractionand Debye temperature were found near 110K and220K. It means that lattice softening happenednear these two temperatures. We also observedminima of isomer shift near 110K and quadrupolesplitting increase when temperature is lowerthan 110K. We suggest that lattice softeningwould lead to the displacement of oxygen atoms.This may be relative to superconductivetransition.