Implementation of periodic boundary conditions for loading of mechanical metamaterials and other complex geometric microstructures using finite element analysis

The implementation of periodic boundary conditions (PBCs) is one of the most important and difficult steps in the computational analysis of structures and materials. This is especially true in cases such as mechanical metamaterials which typically possess intricate geometries and designs which makes finding and implementing the correct PBCs a difficult challenge. In this work, we analyze one of the most common PBCs implementation technique, as well as implement and validate an alternative generic method which is suitable to simulate any possible 2D microstructural geometry with a quadrilateral unit cell regardless of symmetry and mode of deformation. A detailed schematic of how both these methods can be employed to study 3D systems is also presented.

     

Indoor heterogeneous photochemistry of furfural drives emissions of nitrous acid

People spend approximately 80% of their time indoor, making the understanding of the indoor chemistry an important task for safety. The high surface-area-to-volume ratio characteristic of indoor environments leads the semi-volatile organic compounds (sVOCs) to deposit on the surfaces. Using a long path absorption photometer (LOPAP), this work investigates the formation of nitrous acid (HONO) through the photochemistry of adsorbed nitrate anions and its enhancement by the presence of furfural. Using a high-resolution proton-transfer-reaction time-of-flight mass spectrometer (PTR-TOF-MS), this work also investigates the surface emissions of VOCs from irradiated films of furfural and a mix of furfural and nitrate anions. Among the emitted VOCs, 2(5H)-furanone/2-Butenedial was observed at high concentrations, leading to maleic anhydride formation after UV irradiation. Moreover, the addition of potassium nitrate to the film formed NO_x and HONO concentrations up to 10 ppb, which scales to ca. 4 ppb for realistic indoor conditions. This work helps to understand the high levels of HONO and NO_x measured indoors.     

Nonlinear theory of non-uniform torsion of thin-walled open beams

A nonlinear theory of non-uniform torsion based on finite displacements is developed. Expressions for the finite nonlinear strains in Lagrangian coordinates and the Kirchhoff stresses for thin-walled open beams are presented. Using the principle of stationary total potential, the dual forms of the beam equilibrium equations are derived. For conservatively loaded thin-walled open beams a static stability criterion, based on the positive definiteness of the second variation of the total potential, is presented. The criterion developed takes into account the effects of changes in beam geometry such as initial bending curvature, prior to instability.     

Do ‘green’ buildings have better indoor environments? New evidence

A post-occupancy evaluation (POE) of 12 green and 12 conventional office buildings across Canada and the northern United States was conducted. Occupants (N = 2545) completed an online questionnaire related to environmental satisfaction, job satisfaction and organizational commitment, health and well-being, environmental attitudes, and commuting. In each building on-site physical measurements at a sample of workstations (N= 974) were taken, including: thermal conditions, air quality, acoustics, lighting, workstation size, ceiling height, window access and shading, and surface finishes. Green buildings exhibited superior performance compared with similar conventional buildings. Better outcomes included: environmental satisfaction, satisfaction with thermal conditions, satisfaction with the view to the outside, aesthetic appearance, less disturbance from heating, ventilation and air-conditioning (HVAC) noise, workplace image, night-time sleep quality, mood, physical symptoms, and reduced number of airborne particulates. A variety of physical features led to improved occupant outcomes across all buildings, including: conditions associated with speech privacy, lower background noise levels, higher light levels, greater access to windows, conditions associated with thermal comfort, and fewer airborne particulates. Green building rating systems might benefit from further attention in several areas, including: credits related to acoustic performance, a greater focus on reducing airborne particulates, enhanced support for the interdisciplinary design process and development of POE protocols.

Il a été mené une évaluation après occupation (POE) de 12 immeubles de bureaux verts et 12 immeubles de bureaux classiques répartis à travers le Canada et le nord des Etats-Unis. Les occupants (N?=?2545) ont rempli un questionnaire en ligne portant sur la satisfaction environnementale, la satisfaction au travail et l'implication organisationnelle, la santé et le bien-être, les attitudes environnementales, et les trajets réguliers. Dans chaque immeuble, des mesures physiques in situ sur un échantillon de postes de travail (N?=?974) ont été effectuées, comprenant : les conditions thermiques, la qualité de l'air, l'acoustique, l'éclairage, la taille des postes de travail, la hauteur de plafond, l'accès aux fenêtres et leur occultation, et les finitions de surface. Les bâtiments verts ont affiché des performances supérieures par rapport aux bâtiments classiques similaires. De meilleurs résultats ont été obtenus concernant la satisfaction environnementale, la satisfaction à l'égard des conditions thermiques, la satisfaction à l'égard de la vue sur l'extérieur, l'aspect esthétique, la diminution des perturbations liées aux bruits provenant du chauffage, de la ventilation et de la climatisation (CVC), l'image du lieu de travail, la qualité du sommeil nocturne, l'humeur, les symptômes physiques, et la réduction du nombre de particules en suspension dans l'air. Différentes caractéristiques physiques ont conduit à une amélioration des résultats pour les occupants dans tous les immeubles, concernant notamment les conditions liées à la confidentialité des conversations, les niveaux inférieurs de bruit de fond, les niveaux de luminosité plus élevés, l'accès accru aux fenêtres, les conditions associées au confort thermique, et le nombre moindre de particules en suspension dans l'air. Les systèmes de notation des bâtiments verts pourraient bénéficier d'une plus grande attention apportée à plusieurs domaines, s'agissant en particulier des crédits relatifs aux performances acoustiques, d'un accent accru sur la réduction des particules en suspension dans l'air, d'un soutien renforcé en faveur du processus de conception interdisciplinaire et du développement de protocoles POE.

Mots clés: performances des bâtiments, bilan environnemental, bâtiments verts, environnement intérieur, Leadership in Energy and Environmental Design (LEED), satisfaction des occupants, évaluation après occupation     

A Methodology to Simulate the Impact of Tube Fouling on Steam Generator Performance With a Thermal-Hydraulic Code

ABSTRACT

Corrosion product deposits in the secondary side of nuclear plant steam generators may result in tube fouling. Tube fouling is a deposit that is influential for the heat exchanges between the primary and the secondary circuits. It may cause a steam pressure decrease and a power reduction. This paper presents a methodology to simulate the impact of tube fouling on steam generator performances. Simulations are performed with ThermoHYdraulique des Composants, which is Electricité de France reference code for the three-dimensional (3D) modeling of two-phase thermal-hydraulic flows in whole nuclear components such as steam generators. Tube fouling induces an additional thermal resistance on tubes. This resistance is supposed to correspond to the conductive resistance of a dense deposit by using the Maxwell model for a continuous solid phase with inclusions. As fouling deposit thicknesses are not uniformly distributed on the tube bundle, several thermal resistance distributions are investigated. In most cases, tube fouling concentrated in the hot leg is the most influential distribution. Nevertheless, for a large amount of deposits, tube fouling uniformly distributed in both hot and cold legs becomes more influential. This simulation series is an initial step. The strategy to improve the thermal resistance model is discussed.     

Using immersive virtual reality and anatomically correct computer-generated characters in the forensic assessment of deviant sexual preferences

Penile plethysmography (PPG) is the gold standard for the assessment of sexual interests, especially among sex offenders of children. Nonetheless, this method faces some ethical limitations inherent to the nature of its stimuli and could benefit from the improvement of its ecological validity. The use of computer-generated characters (CGC) in virtual immersion for PPG assessment might help address these issues. A new application developed to design made-to-measure anatomically correct virtual characters compatible with the Tanner developmental stages is presented. The main purpose of this study was to determine how the virtual reality (VR) modality compares to the standard auditory modality on their capacity to generate sexual arousal profiles and deviance differentials indicative of sexual interests. The erectile responses of 22 sex offenders of children and 42 non-deviant adult males were recorded. While both stimulus modalities generated significantly different genital arousal profiles for sex offenders of children and non-deviant males, deviance differentials calculated from the VR modality allowed for significantly higher classification accuracy. Performing receiver operating characteristic analyses further assessed discriminant potential. Auditory modality yielded an area under the curve (AUC) of 0.79 (SE = 0.059) while CGC in VR yielded an AUC of 0.90 (SE = 0.052). Overall, results suggest that the VR modality allows significantly better group classification accuracy and discriminant validity than audio stimuli, which provide empirical support for the use of this new method for PPG assessment. Additionally, the potential use of VR in interventions pertaining to self-regulation of sexual offending is addressed in conclusion.     

Analytical Models and Guidelines for the Ductility Enhancement of Circular Reinforced Concrete Single-Column Bents Using Fiber-Reinforced Polymers

The target displacement ductility requirements for circular RC single-column bridge bents are considered using a proposed multifailure mode algorithm to determine the required thickness of fiber-reinforced polymer wraps (FRPs). The procedure is developed using two in-house computer algorithms, PACCC (plastic analysis of circular concrete columns) and PACCC-FRP, to generate a moment-curvature analysis using circular segment slices and subsequent failure mode predictions in single-column bents for both FRP-wrapped and unwrapped circular RC sections. The results of the study showed good comparison to published experimental tests at the ultimate force-deflection states of RC sections and against three commercial “software test beds.” The study uses PACCC-FRP to show that single columns experiencing a brittle failure may be retrofitted with FRP wraps in order to increase the displacement ductility and satisfy target ductility values within the ductility wrap envelope, or wrap-saturation level, as established herein.     

Composites with needle-like inclusions exhibiting negative thermal expansion: A preliminary investigation

In this work a simple cylindrical structure with a stiff needle-like inclusion embedded within a much softer matrix is presented and analysed with the aim of obtaining a system with tunable thermal expansion properties. It is shown that by the correct combination of the thermal and mechanical properties of the matrix and inclusion, it is possible to design a system which can be tailor-made to exhibit particular values of the coefficient of thermal expansion (CTE) in the radial direction and also negative thermal expansion (NTE). In particular an analytical model to quantify the radial strain with changes in temperature is derived and verified through finite element analysis. The model is used to find correct property combinations which lead to particular values of thermal expansion which could also be negative or zero.     

Synthesis and optical properties of dyes encapsulated in gold hollow nanoshells

Gold nanomaterials are promising objects for applications in optics and medicine because of their unique properties related to the Surface Plasmon Resonances (SPR) phenomena. It is possible to tune these properties with the control of the size and shape of the nanomaterials. Gold hollow spheres nanomaterials are an interesting concept for encapsulation of either dyes or drugs. The study of their properties and their behavior in a bio-environment still remains scarce and some phenomena are still to be explained in particular regarding local field enhancement effect or quenching of their photophysical properties. In this work we describe a process allowing inclusion of optical dyes in gold nanoshells and evaluate the optical properties.