Profiling hot isostatically pressed canister–wasteform interaction for Pu-bearing zirconolite-rich wasteforms

Zirconolite-rich full ceramic wasteforms designed to immobilize Pu-bearing wastes were produced via hot isostatic pressing (HIP) using stainless steel (SS) and nickel (Ni) HIP canisters. A detailed profiling of the elemental compositions of the major and minor phases over the canister–wasteform interaction zone was performed using scanning electron microscopy combined with energy-dispersive X-ray spectroscopy (SEM-EDS) characterization. Bulk sample analyses from regions near the center of the HIP canister were also conducted for both samples using X-ray diffraction and SEM-EDS. The sample with the Ni HIP canister showed almost no interaction zone with only minor diffusion of Ni from the inner wall of the canister into the near-surface region of the wasteform. The sample with the SS HIP canister showed ∼100–120 μm of interaction zone dominated by high-temperature Cr diffusion from canister materials to the wasteform with the Cr predominantly incorporated into the durable zirconolite phase. We also examined, for the first time, changes to the HIP canister wall thickness caused by HIPing and demonstrated that no canister wall thinning occurred. Instead, in the areas examined, the canister wall thickness was observed to increase (up to ∼20%) due to the compression occurring during the HIP cycle. Further, only sparse formation of (Cr, Mn)-rich oxide particles were noted within the HIP canister inner wall area immediately adjacent to the ceramic material, with no evidence for reverse diffusion of ceramic materials. Though the HIP canister–wasteform interaction extends to ∼120 μm when using an SS HIP canister for the system investigated, this translates to <<1 vol.% for an industrial scale HIPed wasteform. Importantly, the HIP canister–wasteform interactions did not produce any obviously less durable phases in the wasteform or had any detrimental impact on the HIP canister properties.     

Conceptualizing the pedestrian mall in post-war North America and understanding its transatlantic transfer through the work and influence of Victor Gruen

Pedestrianization was an established concept among modernist architects and planners long before the first post-war pedestrian malls were built in North American downtowns. Post-war pedestrian-oriented suburban shopping malls, such as Northland near Detroit, MI and Northgate in Seattle, WA, linked retail success to the pedestrian shopping experience. This propelled the existing but then-untested assumption that planning downtowns to mimic suburban shopping centres by pedestrianizing main streets would revitalize downtown retail districts. Despite the modern origins of the pedestrianization concept, the rhetorical cues of post-war architects and planners in North America mask its modern roots and employ nostalgic imagery of pre-industrial European urbanism, implying European origin of the concept. Although imagery of European charm became a means of packaging modernist ideas of pedestrianization, the design proposals rarely referenced or replicated actual European precedents. Furthermore, while much research implies a linear transfer of pedestrianization ideas from Europe to North America, professionals in Europe also looked to North American shopping malls and pedestrian streets for guidance in addressing their own challenges with accommodating automobiles in downtowns.     

Overheating in care settings: magnitude,causes, preparedness and remedies

ABSTRACT

Research in UK and elsewhere has highlighted that older people are particularly vulnerable to negative health effects of overheating. This paper examines the magnitude, causes, preparedness and remedies for addressing the risk of summertime overheating in four case study residential care and extra-care settings across the UK, spanning different building types, construction and age. An interdisciplinary approach is adopted, drawing from building science and social science methods, including temperature monitoring, building surveys, and interviews with design and management teams. The findings suggest that overheating is a current and prevalent risk in the case study schemes, yet currently little awareness or preparedness exists to implement suitable and long-term adaptation strategies (e.g., external shading). There was a perception from designers to managers, that cold represents a bigger threat to older occupants’ health than excessive heat. A lack of effective heat management was found across the case studies that included unwanted heat gains from the heating system, confusion in terms of responsibilities to manage indoor temperatures, and conflicts between window opening and occupant safety. Given that care settings should provide protection against risks from cold and hot weather, design, management and care practices need to become better focused towards this goal.     

Phosphorous limitation in an arctic river biofilm—A whole ecosystem experiment

A fourth-order arctic river was experimentally enriched with phosphate (7.7 ± 7.0 μ g 1⁻¹) to determine the effect of such a loading (equivalent to a community of 10,000 people) upon the trophically important biofilm. The effect upon a light-grown biofilm (an autotrophic/heterotrophic assemblage) and a dark-grown biofilm (predominantly heterotrophic assemblage) was determined after 28 days of colonization. Seven attributes of the biofilms were monitored, 2 autotrophic indices, chlorophyll , [¹⁴C]HCO₃ incorporation into lipids and 5 heterotrophic indices; [¹⁴C]acetate incorporation into lipids, metabolic heat output, turn-over times of microbially labile glucose and glutamate and mineralization of microbially recalcitrant ring-labelled [¹⁴C]hydroxybenzoic acid. The findings showed that the addition of phosphorus resulted in a substantial stimulation of both autotrophic and heterotrophic processes suggesting that arctic rivers of this type would be liable to cultural eutrophication.     

Changes in coping style and treatment outcome following motor vehicle accident.

Background: Motor vehicle accidents (MVAs) are highly prevalent and can result in a complex interplay of physical injury, disability, and emotional distress. It has been suggested that the manner in which individuals cope with pain experienced after injury may determine how much recovery of function can be achieved. Only a limited number of studies have examined this process in the context of a rehabilitation program, and to date few studies have examined both functional and quality of life outcomes in MVA recovery in a tertiary level program as a function of coping style. Methods: A sample of 96 consecutive referrals to a tertiary-level multidisciplinary functional restoration program completed physical performance measures pre- and post-treatment, as well as a standardized self-report measure of quality of life (QOL) at the same time points and 6-month follow-up. Results: Findings suggested that improvements from pre- to post-treatment were evident on the 6-minute walk test, left and right grip strength, and most QOL measures. Increases in active coping during treatment were associated with pre- to post-treatment increases in QOL across most domains, and improvements in performance on the 6-minute walk test. Likewise, decreases in passive coping during the course of treatment were associated with improved performance on the 6-minute walk test, right-handed standing reach test, and most QOL indicators. Conclusion: Findings suggest that those who adopt an active approach (and avoid taking a passive approach) to rehabilitation following complex musculoskeletal injury benefit along both QOL and functional dimensions relative to those who do not. (PsycINFO Database Record (c) 2011 APA, all rights reserved)     

Directed test suite augmentation: an empirical investigation

Test suite augmentation techniques are used in regression testing to identify code elements in a modified program that are not adequately tested and to generate test cases to cover those elements. A defining feature of test suite augmentation techniques is the potential for reusing existing regression test suites. Our preliminary work suggests that several factors influence the efficiency and effectiveness of augmentation techniques that perform such reuse. These include the order in which target code elements are considered while generating test cases, the manner in which existing regression test cases and newly generated test cases are used, and the algorithm used to generate test cases. In this work, we present the results of two empirical studies examining these factors, considering two test case generation algorithms (concolic and genetic). The results of our studies show that the primary factor affecting augmentation using these approaches is the test case generation algorithm utilized; this affects both cost and effectiveness. The manner in which existing and newly generated test cases are utilized also has a substantial effect on efficiency and in some cases a substantial effect on effectiveness. The order in which target code elements are considered turns out to have relatively few effects when using concolic test case generation but in some cases influences the efficiency of genetic test case generation. The results of our first study, on four relatively small programs using a large number of test suites, are supported by our second study of a much larger program available in multiple versions. Together, the studies reveal a potential opportunity for creating a more cost‐effective hybrid augmentation approach leveraging both concolic and genetic test case generation techniques, while appropriately utilizing our understanding of the factors that affect them. Copyright © 2014 John Wiley & Sons, Ltd.     

Effect of chain rigidity on block copolymer micelle formation and dissolution as observed by 1H-NMR spectroscopy

Amphiphilic copolymers poly(methyl methacrylate-b-acrylic acid), poly(methyl methacrylate-b-methacrylic acid), poly(methyl acrylate-b-acrylic acid) and poly(methyl acrylate-b-methacrylic acid) were prepared by reversible addition fragmentation chain-transfer (RAFT) polymerization. The hydrophilic polyacid blocks were either synthesized directly or formed by the hydrolysis of poly(tert-butyl acrylate) or poly(tert-butyl methacrylate) blocks. The hydrophobic blocks consisted of either the more rigid, high glass transition temperature (T _g ) poly(methyl methacrylate) or more flexible, low T _g poly(methyl acrylate) material. The hydrophilic blocks were either poly(methacrylic acid) (rigid, high T _g ) or poly(acrylic acid) (flexible, low T _g ). The micellization behavior of the polymers was studied by proton nuclear magnetic resonance (¹H-NMR) spectroscopy in mixtures of 1,4-dioxane-d₈ and D₂O. All four polymers were soluble in neat dioxane. In solutions of higher water content, the polymers with the more rigid hydrophobic blocks formed into micelles as was evidenced by broadening of the resonances resulting from the protons in those blocks. At moderate water concentration (25–50%), dissolution of the micelles was observed upon heating the solution. No micellization was observed in polymers containing the less rigid poly(methyl acrylate) hydrophobic block regardless of the identity of the hydrophilic block. As further evidence of micellization formation and dissolution, the spin-lattice (T ₁) and spin-spin (T ₂) relaxation times of protons in the hydrophobic and hydrophilic blocks were measured. Significant differences in the relaxation times as functions of temperature and solvent concentration were observed between the hydrophilic and hydrophobic blocks of the micelle-forming polymers.     

National and regional generation of municipal residue biomass and the future potential for waste-to-energy implementation

Municipal residue biomass (MRB) in the municipal solid waste (MSW) stream is a potential year-round bioenergy feedstock. A method is developed to estimate the amount of residue biomass generated by the end-user at the scale of a country using a throughput approach. Given the trade balance of food and forestry products, the amount of MRB generated is calculated by estimating product lifetimes, discard rates, rates of access to MSW collection services, and biomass recovery rates. A wet tonne of MRB could be converted into about 8 GJ of energy and 640 kg of carbon dioxide (CO₂) emissions, or buried in a landfill where it would decompose into 1800 kg of CO₂ equivalent (in terms of global warming potential) methane (CH₄) and CO₂ emissions. It is estimated that approximately 1.5 Gt y^?1 of MRB are currently collected worldwide. The energy content of this biomass is approximately 12 EJ, but only a fraction is currently utilized. An integrated assessment model is used to project future MRB generation and its utilization for energy, with and without a hypothetical climate policy to stabilize atmospheric CO₂ concentrations. Given an anticipated price for biomass energy (and carbon under a policy scenario), by the end of the century, it is projected that nearly 60% of global MRB would be converted to about 8 EJ y^?1 of energy in a reference scenario, and nearly all of global MRB would be converted into 16 EJ y^?1 of energy by the end of the century under a climate policy scenario.     

The effects of radiation on (1,3,5 - triamino - 2,4,6 - trinitrobenzene) TATB studied by time-of-flight secondary ion mass spectrometry

Abstract

Highly Charged Ion (HCI) Time-of-Flight (TOF) Secondary Ion Mass Spectrometry (SIMS) has been employed to analyze the changes in the surface composition of TATB caused by low energy electron, ultraviolet, and Gamma ray irradiation. Comparisons are made between canary yellow (not irradiated) TATB and TATB that has been “greened” by exposure to radiation. We ascribe the color change from yellow to green to a loss of oxygen. Another striking aspect of this study is the presence of a feature at m/z = 30 (NO⁺) for highly charged ion SIMS, which does not occur in singly charged ion TOF SIMS.