Simultaneous degradation of RhB and reduction of Cr(VI) by MIL-53(Fe)/Polyaniline (PANI) with the mediation of organic acid

MIL-53(Fe)/polyaniline (PANI) composite was prepared by in situ depositing PANI on the surface of MIL-53(Fe) and their catalytic performances on the simultaneous removal of RhB and Cr(VI) were investigated. The elimination efficiency of both RhB and Cr(VI) reached more than 98% under pH=2 where hydrochloric acid and citric acid were used to adjust the pH. The results indicated that MIL-53(Fe)/PANI revealed an obvious pH response to the degradation of RhB, while citric acid promoted the Cr(VI) photoreduction. UV-Vis spectra, EIS, and photocurrent response experiments showed that MIL-53(Fe)/PANI had a better light response and carrier migration ability than MIL-53(Fe). The transient absorption spectra also exhibited that the lifetimes of photo-generated carriers were prolonged after the conductive polymer deposition on the MIL-53(Fe) surface. Scavenger experiments demonstrated that the main active species were ·O₂^- and OH. Combined with activity evaluation results, and the possible photocatalytic mechanism of MIL-53(Fe)/PANI on RhB oxidation and Cr(VI) reduction was proposed. The addition of conductive polymer can effectively improve the light response of the catalyst under acidic conditions, and meanwhile citric acid also provided a new mediation for the synergistic degradation of multiple pollutants. Good activity and stability of the catalysts made the scale-up purification of acid water feasible under UV-Vis light.     

Nanoporous copper sonocatalysts prepared by dealloying Cu–Al–Ti amorphous ribbons

ABSTRACT

Nanoporous copper (NPC) with a controllable ligament width was prepared by chemically dealloying Cu₄₅Al₄₅Ti₁₀ amorphous ribbons in dilute HCl solution. X-ray diffraction and scanning electron microscopy analysis confirmed the 3D, bicontinuous, nanoporous structure constituting fcc-Cu ligaments of 39–79?nm thickness. The coarsening of NPC ligaments increased significantly with an increase of HCl concentration, reaction temperature or time. The surface diffusivity and activation energy of NPC were also calculated. Finally, the catalytic activity of NPC was validated with the ultrasound and H₂O₂-assisted degradation of methyl orange (MO), where 99% MO was degraded within 15?min.     

Gelation properties of goose liver protein recovered by isoelectric solubilisation/precipitation process

Isoelectric solubilisation/precipitation (ISP) process was applied to goose liver (GL) for protein extraction. The gelation properties of proteins extracted by acid processes (ACP, pH 2.0, 2.5 and 3.0) and alkaline processes (ALP, pH 11.0, 11.5 and 12.0) were estimated, where the unextracted ground GL was set as the control. Nearly 58.39~79.00% of GL proteins were recovered by ISP treatments. High molecular weight (100~250 kDa) proteins were found to be partially hydrolysed by ACP, while few changes in proteins occurred during ALP. As evidenced by rheological and textural measurements, ALP proteins formed gels with high elasticity and superior texture, whereas ACP proteins had inferior gelation properties. Moreover, ALP proteins were able to form a highly interconnected and homogeneous three‐dimensional microstructure. Predominantly, gels produced by 11.0 had optimal texture and the lowest cooking loss (P < 0.05). These results suggested that the ISP process (ALP) is a potential method to improve the economic value of GL.     

一种新型复合热泵供热系统研究

为打造"零能耗建筑",基于云智小镇项目,利用DeST-h建筑能耗模拟软件,模拟建立1栋2层别墅,在具体气象参数下模拟出该建筑物一年所需的生活用热水及采暖能耗情况.同时,创新性地提出了一种新型复合热泵近零能耗供热系统,应用效果明显,社会效益和经济效益较好,验证了"零能耗建筑"的可行性,可为我国建筑节能领域"零能耗建筑"的发展提供借鉴.     

通风墙体的通风效果分析与数值模拟

本文根据新型空心砌块构筑成居住建筑外墙后，空心孔洞上下贯通的特点，提出了利用其中的一个空心孔洞作为通道，利用经常开启的厨房和卫生间的排风机作为动力，对室内进行通风的技术途径，并用CFD手段对某一典型房间的通风效果进行模拟。从模拟结果分析，通风效果良好，可有效解决城乡室内空气环境恶化问题，达到节能的目的。     

基于径向基概率神经网络的输电导线缺陷状态识别

输电导线作为承担电能传输任务的重要部件,及时发现其本体缺陷对指导维修避免重大电力事故的发生具有重要意义。考虑到无人机巡检中输电导线背景的复杂性和导线表面缺陷检测的困难度,提出一种基于径向基概率神经网络的输电导线缺陷状态识别方法。首先,依次采用加权色差法、最大类间方差法以及形态学滤波实现复杂背景下输电导线的准确分割。其次,将分割出的导线区域等距划分为10个导线子图像,通过Gabor滤波器获得输电导线8个角度、5个尺度的40幅纹理增强子图像,提取各个子图像的粗糙度、对比度和方向度3个纹理特征量,结合特征方差比筛选出10个强纹理特征;最后,将10个强纹理特征量作为径向基概率神经网络的输入,完成输电导线缺陷状态的识别。实验结果表明所提方法可以实现复杂背景下输电导线快速分割与缺陷状态的准确识别,为无人机巡检中输电导线的运行状态检测提供了新的思路。     

CBR和RBR融合的牵引变压器运维策略

牵引变压器在运行中易受到高电压、大电流、机械应力及其他环境因素的影响而产生发热、放电、绝缘不良等故障,为了制定合理的运维检修策略从而提高运行中牵引变压器的故障处理水平,提出一种基于规则推理(RBR)和基于案例推理(CBR)融合的牵引变压器运维决策方法:利用RBR获取能反映牵引变压器状态的关键参数,并根据规则库的知识储备得到初步检修方案;设计案例检索算法在状态检修案例库中匹配相似案例,提取检修策略;根据RBR的初步方案对CBR结果进行修改与复用,综合得到最优运维策略,指导检修工作。收集了60例目标案例验证融合决策模型的准确性,结果表明平均决策准确率可达81.67%,且通过实验可判断源案例数量的增加与决策准确率之间呈正相关关系。     

一种新型宽范围ZVS三电平全桥DC/DC变换器

现有的DC/DC变换器存在以下缺点:低功率、低效率和很差的负载适应能力。对此提出了一种新型全桥三电平DC/DC可控源电路,高频变压器的副边有三组绕组,为了提高输出电流,采用两个降压绕组并联整流输出;可控源电路采用不对称移相PWM控制方式,换流电感串接在第三个降压绕组上,空载或轻载时换流电感向滞后桥臂提供换流能量,保证在整个功率范围内实现软开关。通过实验验证提出的DC/DC变换器具有输入电压高、宽范围实现ZVS、高效率的优点。     

单轴受压混凝土的微裂缝和氯离子侵入性

采用1种无破损微裂缝估算指标-比裂缝面积来评价单轴压力作用下混凝土棱柱体的扩展微裂缝.加压卸载后试块暴露于氯离子环境中,测得试块中的氯离子含量分布.分析了单轴压力下混凝土微裂缝的发展以及荷载、微裂缝和氯离子渗透性的相关规律.试验结果表明,在大约0.3的应力水平范围内,受压并卸载后的试块表观氯离子扩散系数普遍降低,但随着应力水平的继续提高,氯离子扩散性能开始提高并超过未加载时的氯离子扩散系数.混凝土在单轴受压并卸载的情况下,其微裂缝的发展和恢复与应力水平关系密切.比裂缝面积能够较好地表征混凝土中微裂缝的发展,有助于分析混凝土在荷载作用下产生的微裂缝对氯离子传输性能的影响.