The surface carboxyl group of carbonaceous microspheres effects on the synthesis and structure of SiOC ceramics

In this study, C/SiOC and C/SiO₂ composites were prepared by using carbonaceous microspheres with different surface functional groups. Carbonaceous microspheres based on hydrothermal reaction of glucose contains hydroxyl group, while the surface carboxyl group increases after NaOH etching. The hydroxyl group increases the oxygen-enriched structural units of SiOC ceramics, and the C spheres are closely enwrapped in SiOC matrix after pyrolysis at 900 °C. However, the interfacial reaction of surface carboxyl with Si–OH results in the formation of cristobalite SiO₂, and C spheres are not only encased inside the SiOC matrix, but also dispersed outside of SiOC ceramics. After removal of C via calcination at 500 °C for 5 h, C/SiOC and C/SiO₂ composites are transformed into amorphous SiO₂ and cristobalite SiO₂, respectively. The thermogravimetric analysis indicates the oxidation resistance of SiOC is superior to that of C and SiO₂.     

一株产羧酸酯酶菌的鉴定及酯酶特征的研究

目的:鉴定中国白酒发酵过程中的微生物种类，研究关键酶的特征与作用机制有利于提高白酒的优质品率。方法:本研究用形态学和生理学、16S rRNA、gyr B基因和antiSMASH分析的方法对酒曲中的一株微生物进行了验证；对该菌株的特性进行了研究，采用分子建模的方法获得了羧酸酯酶的3D模型，用分子对接的方法探讨了该菌株的羧酸酯酶的机理。结果:该菌株为产羧酸酯酶的革兰氏阴性菌Pb1（MW580690）；该菌株呈现典型的S型生长曲线，产物曲线为S型，羧酸酯酶活化最优pH范围为5.0~9.0。分子对接结果显示Phe21A为该酶具有催化活性的主要氨基酸，水解三丁酸甘油酯为丁酸和甘油。分子对接结果显示三丁酸甘油酯经过构象变化被转移到催化中心后，进一步被加工；酶的亲水性和疏水性的相互作用表面有利于配体向下转移，进而从疏水性通道释放产物到的酶表面。结论:产羧酸酯酶的菌株为贝莱斯芽胞杆菌，并为羧酸酯酶水解三丁酸甘油酯类物质的底物识别、转移和催化机理提供了新的见解。     

The formation of fibrous structure of polyamide 6 induced by the three-step forming process and its prominent reinforcement in nitrile rubber

Nitrile rubber (NBR) blends with excellent performance have always been a hot research topic in petroleum field. Due to the excellent performance and compatibility of polyamide 6 (PA6), it provides an opportunity for the preparation of high-performance NBR/PA6 blends. In this article, NBR/PA6 blends were prepared by the three-step molding process. Experimentally, it was found that PA6 has a prominent reinforcement effect in NBR matrix. The variation of this mechanical property was investigated from different aspects of the crystal structure, crystallinities, phase morphology, and so on. It can be cleared that the formation of fibrous structure of PA6 phase is the main factor for reinforcement of the polymer blends. Meanwhile, the formation mechanism of the special phase structure induced by the three-step process is deeply expounded and its structural evolution schematic is established. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47472.     

A regenerable Fe/AC desulfurizer for SO2 adsorption at low temperatures

A novel regenerable Fe/activated coke (AC) desulfurizer prepared by impregnation of Fe(NO₃)₃ on an activated coke was investigated. Experiment results showed that at 200 °C the SO₂ adsorption capacity of the Fe/AC was higher than that of AC or Fe₂O₃. Temperature-programmed desorption (TPD) revealed that H₂SO₄ and Fe₂(SO₄)₃ were generated on the desulfurizer upon adsorption of SO₂. Effect of desulfurization temperature was also investigated which revealed that with increasing temperature from 150 to 250 °C, the SO₂ removal ability gradually increases. The used Fe/AC can be regenerated by NH₃ at 350 °C to directly form solid ammonium-sulfate salts.     

Near-ML multiuser detection with linear filters and reliability-based processing

The prohibitive - exponential in the number of users - computational complexity of the maximum-likelihood multiuser detector for direct-sequence code-division multiple-access communications has fueled an extensive research effort for the development of low-complexity multiuser detection alternatives. We show that we can efficiently and effectively approach the error rate performance of the optimum multiuser detector as follows. We utilize a multiuser zero-forcing or minimum mean-square error (MMSE) linear filter as a preprocessor and we establish that the output magnitudes, when properly scaled, provide a reliability measure for each user bit decision. Then, we prepare an ordered, reliability-based error search sequence of length linear in the number of users; it returns the most likely user bit vector among all visited options. Numerical and simulation studies for moderately loaded systems that permit exact implementation of the optimum detector indicate that the error rate performance of the optimum and the proposed detector are nearly indistinguishable over the whole predetection. signal-to-noise ratio range of practical interest. Similar studies for higher user loads (that prohibit comparisons with the optimum detector) demonstrate error rate performance gains of orders of magnitude in comparison with straight decorrelating or MMSE multiuser detection.     

高柔韧性尼龙1010材料的制备

对尼龙1010/NBR/增塑剂体系进行了系统研究,发现在挤出机中环氧扩链剂可以对尼龙进行扩链反应,且环氧树脂对尼龙1010的扩链反应活性较高,扩链效果比较明显;N-丁基苯磺酰胺是尼龙的良好增塑剂,经增塑、增韧后可以使经扩链后的尼龙1010柔韧性有明显提高.采用SEM和TEM对所制备的材料进行了形貌分析,发现用NBR增韧尼龙,对于不同的基体材料,橡胶粒子的形貌有很大不同,粒子由增韧纯尼龙的椭球形变为在增塑尼龙基体中不规则的形状.     

鄂尔多斯盆地含油气系统

鄂尔多斯盆地含油气系统研究目前尚无成熟的划分方案和系统成果,本文主要依据油气赋存的层位并参考油气源将其划分为下古生界含气系统、上古生界含气系统及中生界含油气系统。各含油(气)系统平面分布范围主要受生油岩、储集岩分布和油气运移方向的控制;其中,下古生界含气系统、中生界含油气系统主要分布于盆地中部。上古生界含气系统主要分布于盆地北部。     

橡皮布的未来发展趋势

<正>自从1953年REEVES公司建立世界上第一条橡皮布生产线以来,橡皮布已经跨越了一个甲子的时光。橡皮布在印刷领域的地位非但没有因为时代和技术的进步而动摇,反而由于大量高新科技的引入而越来越受到各方的重视,也担负起越来越重要的作用和期望。一个重要的证明就是:世界顶级的印刷机生产厂商如曼罗兰、高斯、三菱等都在近几年花了大量的金钱和时间设计了各自的橡皮布专业测试机,系统地为他们新型印刷机选择最匹配的橡皮布。