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排序方式: 共有610条查询结果,搜索用时 15 毫秒
1.
介绍了通过初级颜料的润湿、研磨与分散、稳定处理技术,使助剂和树脂均匀地包裹在颜料表面,并通过特殊工艺制得水性和油性色浆粉,并赋予了很好的速溶性和分散性。 相似文献
2.
砂岩气藏水基欠平衡钻井逆流自吸效应实验研究 总被引:2,自引:2,他引:0
采用水基钻井液欠平衡钻开砂岩气层时,欠平衡压差往往并不能完全抵消岩石的自吸毛细管力,从而产生逆流自吸效应。这种自吸效应可能对砂岩气藏水基欠平衡钻井的储层保护效果产生影响,但目前与之有关的实验研究还很缺乏。为此,设计了一套实验装置,模拟水基欠平衡条件,研究了砂岩基块孔隙逆流自吸规律及其影响因素。结果表明,水基欠平衡钻井过程的逆流自吸效应引起岩石气相渗透率降低,削弱欠平衡钻井的储层保护效果;欠平衡压差越小,逆流自吸作用越强,过小的欠压值不能起到欠平衡钻井保护储层的作用;随着逆流自吸时间延长、围压增加和黏土矿物膨胀,逆流自吸导致气相渗透率下降的程度加剧;逆流自吸引起的气相渗透率下降速率可以表示成时间的幂函数。 相似文献
3.
A series of polyesters was prepared to evaluate hydrolytic stability as a function of cyclohexyl dibasic acid content. The
three cyclohexyl dibasic acids: 1,2; 1,3; and 1,4 were formulated into polyesters with two glycols. The proportion of cis
and trans isomers was evaluated via 1H NMR. The hydrolytic stability of short chain polyesters was evaluated in an acetone/water mixture which solubilized the
polyesters to mimic oligoester behavior within a thermosetting polyester coating environment. The rate of hydrolysis was monitored
by acid titration and corroborated by GPC. Surprisingly, 1,2-cylohexyl diacid-based polyesters were robust, and 1,3-cyclohexyl
diacid-based polyesters were the most susceptible to hydrolysis. Evidently, a 1,2-anchimeric effect for cyclohexyl dibasic
acid polyesters was not an important consideration, while the 1,3-cyclohexyl ester interaction was. Consequently, an anomeric
effect was proposed.
Presented at the 81st Annual Meeting of the Federation of Societies for Coatings Technology, November 12–14, 2003, in Philadelphia,
PA. 相似文献
4.
Structure, properties and application to water-soluble coatings of complex antimicrobial agent Ag-carboxymethyl chitosan-thiabendazole 总被引:3,自引:0,他引:3
The structure, properties and application to water-soluble coatings of a new complex antimicrobial agent Ag-carboxylmethyl citosan-thiabendazole (Ag-CMCTS-TBZ) prepared from different materiel ratios were reported. The silver ions were preferably coordinated with the free-NH2 groups and the -OH groups of secondary alcohol and carboxyl in CMCTS. TBZ preferably bonded to carboxyl group in CMCTS by electrostatic force and hydrogen bonding. Increase in silver ions content in the complex agent improved to some limited extent the antibacterial activity, but enhanced coloring and cost of the complex agent. Increase in TBZ content resulted in increase of antifungal activity, but decrease of water solubility of the complex agent. The antimicrobial MICs of the complex agent to Esherichia coil, Staphylococcus aureus, Candida albicans, Aspergillus niger, Mucor sp. were 20 -80, 15 -60, 20 - 55, 40 - 250, and 400 - 1700 mg/kg, respectively. Addition of 0.1% of this complex agent to acrylic emulsion paint made the paint without substantial change in color, luster, viscosity, odor or pH value, but with an excellent and chronically persisting broad-spectra antimicrobial activity. 相似文献
5.
6.
Atar Musa Keskin Hakan Güçlü Yavuzcan H. 《Journal of Coatings Technology and Research》2004,1(3):219-224
The impacts of impregnation and bleaching on the varnish layer hardness of Oriental beech (Fagus orientalist L.) wood were investigated. A number of bleaching combinations {[NaOH−H2O2], [NaOH−Ca(OH)2−H2O2], [NaOH−MgSO4−H2O2] [NaHSO3−H2C2O4], [NaSiO3−H2O2], [KMnO4+NaHSO3+H2O3]} were applied at 18% concentration for bleaching to both impregnated and unimpregnated specimens of Oriental beech wood.
Subsequently, water-based (WB) varnish was coated over the samples and the varnish layer hardness values were determined in
accordance with ASTM D 4366-95.
All of the chemicals used for bleaching reduced the surface hardness. However, after varnish coating, the hardness of most
samples was similar to that of the varnish-coated natural (control) samples. 相似文献
7.
Hydrophobically modified alkali-soluble emulsion (HASE) polymers are an important class of rheology modifiers for waterborne
coatings applications. They are typically prepared as terpolymers by emulsion polymerization of ethyl acrylate (EA), methacrylic
acid (MAA), and an associative macromonomer. The viscosity development and shear responses of HASE solutions depend on a number
of factors. This article presents rheological data reflecting the impacts of three key variables: hydrophobe size, acid content,
and molecular weight, on model HASE thickening and rheological performance. The relative contributions of hydrophobic association,
chain expansion, and polymer chain length are discussed.
In steady shear flow, all thickener solutions approached some constant low-shear viscosity at small deformation rates. At
the same molar composition, larger hydrophobe size resulted in higher viscosity development and greater shear thinning behavior.
The amount of acid monomer in HASE polymers can influence the balance between hydrophobic attraction and electrostatic repulsion
forces. It was found that a minimum of 15 wt% MAA was required to effect dissolution and thickening of the model HASE polymers.
Increasing the MAA level yielded higher zero-shear viscosity and storage modulus G’ with maximal values being obtained at
40% MAA.
The molecular weight of the model thickeners was controlled by the amount of chain transfer agent (CTA) added during polymerization.
When the CTA level was below 0.1 wt% based on total monomers, the polymer solutions displayed shear-thinning behavior. A small
increase in CTA concentration beyond 0.1% resulted in a dramatic change to Newtonian flow, and the solution viscosity was
nearly two orders of magnitude lower.
The model thickeners were also tested in a vinyl acrylic architectural paint formulation. The effects of each individual factor
on paint thickener efficiency, high-shear, and low-shear properties are discussed and compared with solution rheology for
predictive relationships.
Presented at the 81st Annual Meeting of the Federation of Societies for Coatings Technology, November 11–12, 2003, in Philadelphia,
PA. 相似文献
8.
含活性偶联基水性氟硅聚合物的制备 总被引:1,自引:0,他引:1
采用硅氢加成法在无溶剂的条件下,将烯丙基聚氧乙烯聚氧丙烯醚,含氟单体及硅烷偶联剂与低含氢硅油发生接枝共聚,成功地制备了一系列有机氟硅聚合物。通过控制原料的投料比,可以通过自乳化法制备得到水性氟硅聚合物水分散物。采用红外光谱和透射电子显微镜对有关产物和水分散物进行了结构分析,系统研究了乳液的透光率、流变性、表面张力等性能,结果表明:质量分数为2.0%的水性氟硅水分散物的表面张力降低至20.00~26.00 N/m;当剪切速率较大时,有剪切变稠现象;是否引入偶联剂链段对水分散物的粒子粒径及形状也有影响。 相似文献
9.
高档水基油墨粘度影响因素的研究 总被引:1,自引:0,他引:1
为获得高固低粘的油墨配方体系,通过油墨的分散实验,探讨了分散树脂和乳液及其助剂对水基油墨体系粘度的影响规律,润湿分散剂对水基油墨粘度的影响,胺化剂对水基油墨粘度的影响机理。研究表明,乳液聚合物具有高固低粘特性,拼混使用不同的聚合物可获得理想粘度和应用性能;润湿分散剂能改变体系的表面张力和润湿性能,从而降低水基油墨体系的粘度;拼混使用不同的胺化剂可以获得粘度稳定的水基油墨体系。 相似文献
10.
Yinzhong Guo Vijay M. Mannari Pulin Patel John L. Massingill 《Journal of Coatings Technology and Research》2006,3(4):327-331
A series of soybean oil phosphate ester polyols (SOPEP) was prepared by reaction of fully epoxidized soybean oil with phosphoric
acid and simultanoeous hydrolysis in the presence of a polar solvent. The polyols were characterized by determination of acid
value, oxirane number, hydroxyl value, molecular weight (GPC), and FTIR spectra. These polyols with varying amounts of acid
phosphate groups could be self-emulsified to form aqueous dispersions after neutralization with organic base. These aqueous
dispersion showed varying degrees of stability and their appearance ranged from opaque dispersions to translucent to clear
solutions. Waterborne coating compositions were prepared using these aqueous dispersions as principal components and their
thermally cured film properties were studied. it was found that by careful selection and formulation, SOPEPs can be successfully
used for low-VOC waterborne coating formulations. SOPEPs with 3.5% phosphate ester content showed visibly superior corrosion
resistance properties. 相似文献