Effect of partial replacement of geopolymer binder materials on the fresh and mechanical properties: A review

The growth of demand for concrete raises concerns about the consumption of natural resources and ordinary Portland cement. Geopolymer composites show promise as a sustainable alternative for conventional cement concrete. Considering the wide range of potential geopolymer composites applications (including suitability for transportation infrastructure, underwater applications, repair and rehabilitation of structures as well as recent developments in 3D printing), the desired fresh and mechanical properties of the geopolymer composite may vary between applications: for example, rapid setting can be a merit for certain applications and a demerit for others. Therefore, the desired fresh and mechanical properties (e.g., workability, setting time, compressive strength, etc.) can be controlled for a given geopolymer source material through its partial substitution by natural or by-product materials. Recognizing the critical role of various replacement materials in enhancing the potential applications of geopolymer composites, the present review was undertaken to quantify and understand the effect of partial replacement by fly ash, metakaolin, kaolin, red mud, slag, ordinary Portland cement, and silica fume on the setting time, workability, compressive strength and flexural strength of various source materials addressed in the literature. The review also provides insights into research gaps in the field to promote future research.     

环境中污染源废气检测方法及影响因素分析

对污染源废气监测原理进行了简单分析,阐述了当前我国常用的环境中污染源废气检测方法,并对废气检测影响因素及质量控制进行了深入探究。     

济钢120t转炉二次烟气除尘设计

济钢120t转炉二次烟气除尘设备选用长袋低压脉冲除尘器,风机采用液力偶合器,并设计将加料系统除尘风量直接加入转炉二次烟气除尘系统。系统投产后,每炉钢节电1200kW,烟气排放浓度为47mg/m3,烟气温度在110℃以下。实践证明,该系统具有节能、捕集率高、排放浓度低、自动化程度高等特点。     

硅灰混凝土的研究及其在公路道面的应用

 了提高道路路面混凝土的抗磨能力，采用硅灰代替部分水泥的方法，对硅灰混凝土的性能进行了较系统的试验研究。成果表明其抗压强度、抗弯强度、抗磨强度等指标都得到明显提高，全面达到和超过了规范要求。并已在丹江口水利枢纽上坝公路中得到应用，实践证明硅灰混凝土技术可靠、经济合理、易于施工。特别是抗磨度的提高，对延长公路路面的使用寿命具有重要意义。     

镧系钙钛矿型氧化物（LaBO3）的催化氧化性能及其净化效果的研究

本文在气相色谱仪联用微反应器装置上,研究了LaBO_3型催化剂中的B位元素对催化氧化活性的影响规律,并进行了程序升温脱附实验。另外,还对LaBO_3型载体催化剂进行了活性筛选,并在柴油机台架上与贵金属Pt/Al_2O_3进行了有害气体净化效果的对比实验。实验结果表明,LaBO_3氧化物中LaMnO_3对CO、CH_4的催化氧化活性最高,且CO、CH_4活性中心并不一致。LaMnO_3/γ-Al_2O_3浸渍微量助化剂后,能使CO在130℃完全氧化,CH_4的氧化温度在300～500℃范围内,LaMnO_3载体催化剂对柴油机有害排放物的净化率很低,浸渍微量助化剂后,净化率提高一倍以上,特别是LaMnO_3/堇青石蜂窝陶瓷,浸渍后的净化效果同贵金属Pt/Al_2O_3接近。     

Eight-year exploration of shrinkage in high-performance concrete

In this paper, an experimental and analytical exploration on the effect of water-binder ratio (w/b), silica fume and age on autogenous, carbonation, drying and total shrinkage of high-performance concrete (HPC) is outlined. Eight types of HPC were studied. Carbonation, internal relative humidity (RH) and strength were studied on specimens from the same batch of HPC that was used in the studies of shrinkage. The results indicate fairly good correlation between carbonation, shrinkage, w/b and RH. The type and amount of silica fume affected shrinkage.     

An integrated system of biological and catalytic oxidation for the removal of o-xylene from exhaust

Biofiltration is an efficient technology for treatment of gaseous waste. Its disadvantages, however, include large volume of bioreactor and slow adaptation to fluctuating concentrations in waste gas. Catalytic oxidation offers a high destructive efficiency at relatively low operating temperature and small unit. A bench scale system integrated with a biofilter and a catalytic oxidation unit for the treatment of gases containing o-xylene was investigated in this study. The catalytic oxidation unit was packed with Cu/Al₂O₃ catalyst. The results showed that 90% of o-xylene could be removed in the biofilter at the load below 38.2 g m⁻³ h⁻¹. High o-xylene concentration in inlet gas resulted in an overload of the biofilter. Using the Cu/Al₂O₃ catalytic oxidation unit, the concentration of o-xylene could be reduced evidently. The combination of the chemical and microbial processes not only led to a high and stable efficiency of o-xylene conversion, but also improved capacity resisting the shock loads. The Cu/Al₂O₃ was studied for o-xylene oxidation in temperature range of 90–320 °C. The o-xylene conversion was improved correspondingly with the increasing of oxidation temperature. The reaction mechanism of o-xylene oxidation on Cu/Al₂O₃ was also investigated using diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS).     

焦炉装煤烟尘治理的烟气量计算

通过对焦炉装煤烟尘治理的烟气量计算和研究,提出不同治理系统的烟气量计算方法及应采取的措施。     

汽车排放控制系统中的氧传感器现状及展望

介绍了浓差型(Nernst型)、极限电流型和半导体电阻型等汽车排放控制系统中的氧传感器原理及结构。在综合该领域国内外研究现状的基础上,对氧传感器的发展进行了展望。     

整体炉外热处理法对移动烟罩实施消应力退火

为了解决武钢三炼钢厂烟罩这类大型构件不便于在常规热处理炉内进行热处理的难题，根据有关工艺和标准要求对烟罩实施了整体炉外热处理，施工中采用在烟罩中段外部包扎保温材料，同时在烟罩两端搭设简易炉体的方法对烟罩进行保温，并制定相应的热处理施工工艺，对工件进行消除应力退火。退火后进行的应力测试表明，应用此种退火技术，工件的焊接残余应力的下降率可以达到60％以上，完全可以满足大型工件的消应力退火要求。