Optimization of hydrogen enrichment via palladium membrane in vacuum environments using Taguchi method and normalized regression analysis

In this study, the separation of hydrogen from gas mixtures using a palladium membrane coupled with a vacuum environment on the permeate side was studied experimentally. The gas mixtures composed of H₂, N₂, and CO₂ were used as the feed. Hydrogen permeation fluxes were measured with membrane operating temperature in the range of 320–380 °C, pressures on the retentate side in the range of 2–5 atm, and vacuum pressures on the permeate side in the range of 15–51 kPa. The Taguchi method was used to design the operating conditions for the experiments based on an orthogonal array. Using the measured H₂ permeation fluxes from the Taguchi approach, the stepwise regression analysis was also employed for establishing the prediction models of H₂ permeation flux, followed by the analysis of variance (ANOVA) to identify the significance and suitability of operating conditions. Based on both the Taguchi approach and ANOVA, the H₂ permeation flux was mostly affected by the gas mixture composition, followed by the retentate side pressure, the vacuum degree, and the membrane temperature. The predicted optimal operating conditions were the gas mixture with 75% H₂ and 25% N₂, the membrane temperature of 320 °C, the retentate side pressure of 5 atm, and the vacuum degree of 51 kPa. Under these conditions, the H₂ permeation flux was 0.185 mol s^?1 m^?2. A second-order normalized regression model with a relative error of less than 7% was obtained based on the measured H₂ permeation flux.     

我国水-能源-粮食耦合关系及影响因素

为缓解我国水、能源和粮食资源紧张问题，促进资源可持续利用，构建水-能源-粮食系统，利用耦合协调度模型对我国的30个省（自治区、直辖市）进行测算,并利用空间杜宾模型分析主要影响因素。结果表明：2003—2017年，我国能源、粮食评价[JP]指数高于水资源评价指数，系统综合评价指数逐年递增；大部分省份耦合协调度处于初级协调水平且呈现逐年上升的态势，个别省份耦合协调度濒临失调；耦合协调度空间自相关性较强，虽有明显波动，但是呈现逐年加强的态势；影响耦合协调度的主要因素有从业人口数、固定资产投资额、人均生产总值、人口总数、[JP]文盲人口占比、工业污染排放、城镇化。     

二甲基二氯硅烷水解反应器研究进展

基于对甲基氯硅烷单体生产中水解反应特点的分析,论述了国内外几种水解反应器的结构特点,着重介绍了几种水解反应器在工业应用过程中存在的优缺点,并对水解反应器未来的发展方向进行了展望。     

脱硫胶粉在乳化改性沥青中的应用

考察了不同规格胶粉及不同脱硫程度的脱硫胶粉对橡胶改性乳化沥青性能的影响,结果表明,采用100目胶粉即可制备出橡胶改性乳化沥青,但乳化沥青的性能较差;采用活化度为50%左右的100目脱硫胶粉制备乳化沥青时,脱硫胶粉的用量相比于胶粉可大幅提高;在通过外掺100目50%左右活化度的脱硫胶粉(质量分数15%,以沥青计,下同)和质量分数2%的苯乙烯-丁二烯-苯乙烯嵌段共聚物改性的乳化沥青中添加质量分数1%的丁苯胶乳,所制备橡胶改性乳化沥青无筛上剩余物,5 d储存稳定性为2.9%,蒸发残留物的25℃针入度、软化点和5℃延度分别为55 (0.1 mm)、64.5℃和22.5 cm,能够满足乳化改性沥青的技术指标要求。     

油藏中后期减氧空气驱提高采收率机理研究

尕斯库勒油田E¹₃油藏已经进入高含水时期，储采失衡加剧，综合含水率达到了80%以上，原油产量下降，经济效益变差。为了提高油藏原油采出程度、改善油藏开发效果，调研了国内外减氧空气驱的机理研究以及现场试验的资料，建立了以油藏真实孔渗饱数据为基础的一维条形地层机理模型，并选取该油藏Y12-27井组进行了减氧空气驱可行性验证。研究表明:纵向顶部减氧空气驱驱油效果优于水驱和氮气驱；驱替压力对原油采出程度影响不大；注水转注气可以提高原油采出程度；对于减氧空气驱，由于低温氧化反应的作用，氧气浓度对原油采出程度有一定影响，但比较微弱，其中，氧气浓度为10%时，驱替结束采出程度最高；尕斯库勒油田E¹₃油藏属于注水开发“双高”油藏，适用于减氧空气驱；对于该油藏Y12-27井组，顶部减氧空气驱驱油效果好于水驱和氮气驱，建议氧气浓度超过10%时采取关井等措施。     

基于粒子群优化算法的五自由度机械臂轨迹规划

为了让机械臂的工作时间达到最优,以自主研发的抛光机器人样机为研究对象,针对手表表壳表耳部分的抛光过程,提出PSO算法对五自由度机械臂轨迹规划进行优化,并通过MATLAB软件进行机械臂的仿真与分析。仿真结果表明,基于PSO算法的轨迹规划使机械臂在工作过程中加加速度不会产生突变,运动轨迹精度高,机械臂工作时间达到最优。     

Co-precipitation of nano Mg–Y/ZrO2 ternary oxide eutectic system: Effects of calcination temperature

In the family of inorganic nanomaterials, zirconia is a highly promising functional ceramic with a high refractive index, hardness, and dielectric constant, as well as excellent chemical inertness and thermal stability. These properties are enhanced in nano-zirconia ceramics, because nanopowders have a small particle size, good morphology, and uniform and dispersive distribution. In this study, a co-precipitation process was proposed to synthesise highly dispersed MgO–Y₂O₃ co-stabilized ZrO₂ nanopowders. The effects of different calcination temperatures on the crystallisation degree and particle dispersion of zirconia nanopowders were characterised by X-ray diffraction (XRD), thermogravimetry-differential scanning calorimetry (TG-DSC), Raman spectroscopy, Fourier transform infrared spectroscopy (FTIR), nitrogen adsorption using the Brunauer–Emmett–Teller (BET) theory, transmission electron microscopy (TEM), and field emission scanning electron microscopy (FESEM). The optimum synthesis conditions were obtained as follows: 6 h of high-energy planetary grinding and calcination at 800 °C in an electric furnace. Under these optimum conditions, the average particle size of the prepared powder was 28.7 nm. This process enriches the literature on the controllable preparation of Mg–Y/ZrO₂ nanopowders obtained by the co-precipitation method.     

Design and synthesis of side-chain optimized poly(2,6-dimethyl-1,4-phenylene oxide)-g-poly(styrene sulfonic acid) as proton exchange membrane for fuel cell applications: Balancing the water-resistance and the sulfonation degree

Side-chain optimized poly (2,6-dimethyl-1,4-phenylene oxide)-g-poly (styrene sulfonic acid) (PPO-g-PSSA) is designed with balanced water-resistance and sulfonation degree. The PPO-g-PSSA is synthesized by controlled atom-transfer radical polymerization (ATRP) from brominated poly (2,6-dimethyl-1,4-phenylene oxide) (PPO-xBr) and ethyl styrene-4-sulfonate and followed by hydrolysis. A series of PPO-g-PSSA are prepared possessing different bromination degree (x) of PPO-xBr and polymerization degree (m) of the side-chains and the water-resistances of the fabricated membranes are investigated. The results show that a PPO-g-PSSA at relatively low x (x < 0.2) and high m (m > 4) exhibits good balance between the water-resistance and the sulfonation degree. Namely, it displays suitable proton conductivity with compromised water-resistance. Moreover, a maximum ion exchange capacity (IEC) of 3.24 mmol g^?1 is reached without the sacrifice of water-resistance. In addition, PPO-g-0.08PSSA-13 and PPO-g-0.14PSSA-4 are chosen characterized by thermogravimetric analysis, proton conductivities and mechanical properties. At 90% RH, the optimized PPO-g-0.08PPSA-13 possesses a proton conductivity of 37.9 mS cm^?1 at 40 °C and 45.5 mS cm^?1 at 95 °C, respectively.