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1.
寒区河道凌汛灾害河势“弯道效应”的量化评估十分重要。基于分形理论提出河道横断面-纵剖面-平面多维度河势分形维数计算方法及其物理机制,并探讨黄河内蒙古段不同维度河势演变分形特征及其与凌汛灾害的关联关系。结果表明,黄河内蒙古段不同维度河势均具有多尺度自相似分形特征,且具有多年记忆周期的长程相关性;冰坝(严重性冰塞)发生频次与河道主槽弯曲分形维数呈正相关指数型函数关系,与河相系数、深泓点高程和河段平均底坡分形维数负相关,与水深-面积分形维数正相关,总体表明冰坝灾害更易发生于主槽偏移摆动大、蜿蜒曲折、河湾发育程度高的宽浅型弯曲河道,研究成果可为凌汛期冰塞冰坝灾害易发河段诊断及预测提供重要理论依据。 相似文献
2.
Can Ercan S. Esra Safran Artuğ Türkmenoğlu Uğur Karabakal 《Journal of surfactants and detergents》2021,24(1):139-147
Garzan oil field is located at the south east of Turkey. It is a mature oil field and the reservoir is fractured carbonate reservoir. After producing about 1% original oil in place (OOIP) reservoir pressure started to decline. Waterflooding was started in order to support reservoir pressure and also to enhance oil production in 1960. Waterflooding improved the oil recovery but after years of flooding water breakthrough at the production wells was observed. This increased the water/oil ratio at the production wells. In order to enhance oil recovery again different techniques were investigated. Chemical enhanced oil recovery (EOR) methods are gaining attention all over the world for oil recovery. Surfactant injection is an effective way for interfacial tension (IFT) reduction and wettability reversal. In this study, 31 different types of chemicals were studied to specify the effects on oil production. This paper presents solubility of surfactants in brine, IFT and contact angle measurements, imbibition tests, and lastly core flooding experiments. Most of the chemicals were incompatible with Garzan formation water, which has high divalent ion concentration. In this case, the usage of 2-propanol as co-surfactant yielded successful results for stability of the selected chemical solutions. The results of the wettability test indicated that both tested cationic and anionic surfactants altered the wettability of the carbonate rock from oil-wet to intermediate-wet. The maximum oil recovery by imbibition test was reached when core was exposed 1-ethly ionic liquid after imbibition in formation water. Also, after core flooding test, it is concluded that considerable amount of oil can be recovered from Garzan reservoir by waterflooding alone if adverse effects of natural fractures could be eliminated. 相似文献
3.
针对常见泥石流防治结构被冲击破坏的问题,基于“柔性消能”理念,结合张弦梁结构和竖向预应力锚杆技术,提出一种既能改善结构受力性能、增加结构整体抗冲击能力、保证结构安全可靠,又能减小结构构件截面尺寸、节约成本、便于现场施工组装和后期运营维护的新型地锚张弦梁式泥石流格栅坝,并阐述其技术原理。根据泥石流荷载分布和新型地锚张弦梁式泥石流格栅坝的受力特征,给出其简化的内力计算方法;并利用SAP2000建立新结构有限元模型,分析了结构的整体受力,验证了构件简化计算方法的合理性;结合Python语言和Qt De? signer软件开发了相应的设计计算软件,对新型地锚张弦梁式泥石流格栅坝的内力进行求解。结果表明:提出的新结构抗冲击性能好,构件受力均匀;以后设计中应关注竖杆的剪切脆性破坏和立柱偏心受力情况,保证结构安全;变形协调仅使底层张弦梁与竖杆内力偏大,实际工程应用时,应着重验算底层构件,防止其破坏;文中提出的简化计算方法能较准确的反映结构的受力特性,具有一定的合理性,研究可为新型地锚张弦梁式泥石流格栅坝的设计计算和推广应用提供理论依据和技术支持。 相似文献
4.
《International Journal of Hydrogen Energy》2022,47(16):9566-9578
The construction of heterostructure is an effective strategy to synergetically couple wide-band-gap with the narrow-band-gap semiconductor with a mediate optical property and charge transfer capability. Herein, the Z-Scheme CdS/ZnSnO3 (CdS/ZSO) heterostructures were constructed by anchoring CdS nanoparticles on the surface of double-shell hollow cubic ZnSnO3 via the hydrothermal method. The direct recombination of excited electrons in the conduction band (CB) of ZSO and holes in the valence band (VB) of CdS via d-p conjugation at the interface greatly accelerated the internal electric field (IEF). The transfer mode follows the Z-Scheme mechanism, where CdS/ZSO synergistically facilitates the efficient charges transfer from CdS to ZnSnO3 through the intimate interface. Here, ZnSnO3 and CdS serve as an oxidation photocatalyst (OP) and reduction photocatalyst (RP), respectively. Thus, it can promote synergistically the oxidation half-reaction and reduction half-reaction of H2 evolution. The density-functional theory (DFT) calculation further confirms the charges transfer from CdS to ZnSnO3. The hydrogen evolution of 5% CdS/ZSO heterostructure reached 1167.3 μmol g?1, which was about 8 and 3 folds high compared to pristine ZSO (141.9 μmol g?1) and CdS (315.5 μmol g?1), during 3 h of reaction respectively. Furthermore, the CdS/ZSO heterostructures could suppress the photo corrosion of CdS, resulting in its high stability. This work is expected to enlighten the rational design of heterostructure for OP and RP to promote the hybrid heterostructures photocatalytic H2 evolution. 相似文献
5.
Borazine rings act as a pivotal part in siliconboroncarbonitride ceramics (SiBCN) for high-temperature stability and great resistance to crystallization. A detailed investigation of the ring formation mechanism will guide the design and synthesis of SiBCN to meet application requirements under extreme conditions. Boron trichloride (BCl3) and hexamethyldisilazane (HN(SiMe3)2) are common raw materials for the synthesis of precursors for SiBCN. In this paper, quantum chemical calculation was used to study the cyclization reaction mechanism between BCl3 and HN(SiMe3)2 to form trichloroborazine (TCBZ) at the MP2/6-31G (d,p) level of theory. We discussed the structure properties, reaction pathways, energy barriers, reaction rates, and other aspects in detail. The results show that BCl3 and HN(SiMe3)2 alternately participate in the reaction process, accompanied by the release of trimethylchlorosilane (TMCS), and that the entire reaction shows an absolute advantage in terms of energy. In the Step by step reaction, lower reaction barriers are formed due to the introduction of BCl3 with more heat released compared to that for the introduction of HN(SiMe3)2. The final single-molecule cyclization and TMCS elimination steps are found to be faster compared to all previous bimolecular reactions. 相似文献
6.
Amino acid modified polyaspartic acids were evaluated as calcium-scale inhibitors. Feasibility of scale inhibition experiments was analyzed by molecular dynamics simulation and Gaussian optimization, and the scale inhibition mechanism was theoretically analyzed. Scale inhibition performance was studied by scanning electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, static scale inhibition experiments, and electrochemical performance testing, which provided an experimental basis for the molecular dynamics simulation. The experimental results showed that Arg-SA-PASP has better scale inhibition and corrosion inhibition performance than His-SA-PASP. The scale inhibition effect increased with increasing concentration. Electrochemical tests indicated that Arg-SA-PASP is an excellent scale and corrosion inhibitor. 相似文献
7.
氢工质在新能源与动力、航天推进、化工材料等领域有着广泛应用。通过开展高温氢工质热力学与输运性质研究,建立了原子态氢、分子态氢、热解平衡态氢的热物理性质计算模型,开发了热物性计算程序Prop_H_H2,适用范围为温度100~3 500 K、压力104~5×107 Pa 。验证表明,Prop_H_H2在适用范围内计算氢工质的物性参数合理可靠,在温度200~3 000 K、压力104~107 Pa范围内,程序预测值更加准确,相对偏差在±5%左右。本研究可为氢工质相关的航天推进、应用物理学、能源动力等行业的科研和应用提供支持借鉴。 相似文献
8.
科学合理地确定矿山隔水护顶矿柱安全厚度是矿山安全生产的前提条件,为保障某铁矿地表民房、道路等建(构)筑物安全,防止矿山开采过程中产生的导水裂隙带贯通第四系含水层,采用荷载传递交汇线法、K.B.鲁别涅依他估算法和冒落带、导水裂隙带高度估算法3种理论分析方法对隔水护顶矿柱厚度进行计算,并利用数值模拟手段对留设隔水护顶矿柱后的开采过程安全影响进行了分析,对理论计算结果进行了验证。3种理论计算方法得出的隔水护顶矿柱厚度分别为14.3~17.3 m、17.5~31.4 m和41.8~57.4 m,推荐隔水护顶矿柱留设厚度为60 m。通过数值模拟分析得出,在留设60 m厚的隔水护顶矿柱的基础上,开采区域和隔水护顶矿柱位置产生的最大拉应力约0.47 MPa,矿山开采不会对隔水护顶矿柱造成破坏;地表产生的最大水平位移约5.8 cm,最大垂直位移约26.5 cm,最大倾斜为1.70 mm/m,最大曲率为0.20 mm/m2,最大水平变形值为0.70 mm/m,满足相关规范要求,预测矿山开采不会造成地表建(构)筑物破坏。 相似文献
9.
10.
NO2 fission is regarded to be the most important initial decomposition process of 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (CL-20). In this study, four CL-20 conformers based on the ε-CL-20 were obtained after the optimization at m062x/cc-pvtz level, and the bond length, bond order and bond dissociation energy of the N-N bonds were examined to investigate the stability of these bonds. In addition, the rate constants and activation energy of the NO2 fission were evaluated using the microcanonical variational transition state theory (μVT). The calculation results have shown that N-N bonds in the case of pseudo-equatorial and axial of nitro groups are the most stable and the least stable, respectively, by evaluating the bond length, bond order and minimum energy path (MEP). The NO2 fission rate constants are affected by not only the stability of N-N bonds but also the repulsion forces from the other nitro groups, and the fission process for pseudo-equatorial positioning of nitro groups is easier to be accelerated due to the increase of the repulsion forces. The decomposition of CL-20 conformer may mainly originate from the fission of the pseudo-equatorial positioning of nitro groups, especially for CL-20 III conformer because of the significant low activation energy. 相似文献