Revealing active species of CePO4 catalyst for selective catalytic reduction of NOx with NH3

Revealing the active species of the catalyst is conducive to the design of more efficient catalyst. Herein, we tried to demonstrate the roles of amorphous and crystalline structures on CePO₄ catalyst during selective catalytic reduction (SCR) of NO_x by NH₃. Higher calcination temperature promotes the transfer of amorphous structure to crystalline structure on the surface of CePO₄. Both amorphous and crystalline CePO₄ species on CePO-X samples can provide acid sites for NH₃ adsorption, but the former can provide more acid sites. The superior redox property of surface amorphous CePO₄ species contributes to its high NH₃-SCR activity at low temperature, but it also leads to the decrease of high temperature (>350 °C) NH₃-SCR activity due to the oxidation of NH₃. In contrast, crystalline CePO₄ species shows high activity only at high temperature because of its poor redox property. Therefore, it can be inferred that amorphous and crystalline structures on CePO₄ catalyst can be the efficient active species of NH₃-SCR at low and high temperature, respectively.     

Optimal Design of Novel Electromagnetic-Ring Active Balancing Actuator with Radial Excitation

Imbalance vibration is a typical failure mode of rotational machines and has significant negative effects on the effii-ciency,accuracy,and service life of equipment.To automatically reduce the imbalance vibration during the opera-tional process,different types of active balancing actuators have been designed and widely applied in actual produc-tion.However,the existing electromagnetic-ring active balancing actuator is designed based on an axial excitation structure which can cause structural instability and has low electromagnetic driving efficiency.In this paper,a novel radial excitation structure and the working principle of an electromagnetic-ring active balancing actuator with a combined driving strategy are presented in detail.Then,based on a finite element model,the performance param-eters of the actuator are analyzed,and reasonable design parameters are obtained.Self-locking torque measurements and comparative static and dynamic experiments are performed to validate the self-locking torque and driving effi-ciency of the actuator.The results indicate that this novel active balancing actuator has sufficient self-locking torque,achieves normal step rotation at 2000 r/min,and reduces the driving voltage by 12.5％.The proposed novel balancing actuator using radial excitation and a combination of permanent magnets and soft-iron blocks has improved electro-magnetic efficiency and a more stable and compact structure.     

一种基于实时几何测距的船桥主动防撞方法

本文提出一种基于实时几何测距的船桥主动防撞方法。该方法对船的改动量甚微,仅需维持多项距离矩阵,通过告警逻辑矩阵进行展示与告警,能起到很好的船桥防撞提示效果。     

镓锗铜萃余液综合利用研究与应用

本文针对镓锗铜综合回收系统产出的萃余液,设计通过中和氧化除杂、锌粉置换除铜镉、有机试剂除钴镍、纯碱法生产碱式碳酸锌、高温煅烧生产活性氧化锌和一步法生产元明粉的生产工艺流程,有效的将镓锗铜萃余液分类分离富集,产出具有价值的富集渣和工业产品,进一步提升综合回收经济效益。     

Hierarchical Learning Water Cycle Algorithm

In order to improve the global searching ability of Water Cycle Algorithm (WCA), the hierarchical learning concept is introduced and the Hierarchical Learning WCA (HLWCA) is proposed in this paper. The underlying idea of HLWCA is to divide the solutions into collections and give these collections with hierarchy differences. One of the collections has a higher hierarchy than others and utilizes an exploration-inclined updating mechanism. The solutions in this high hierarchy collection are the exemplars of other collections. The other collections are sorted according to the exemplars’ function value and the solutions in these collections actively choose whether to follow their own exemplar or not. Through different updating mechanisms of collections, the global searching ability is improved while the fast convergence and strong local search ability of WCA are retained. The proposed HLWCA is firstly experimented on IEEE CEC 2017 benchmark suite to testify its performance on complex numerical optimization tasks. Then, it is tested on four practical design benchmark problems to verify its ability of solving real-world problems. The experimental results illustrate the efficiency of the proposed algorithm.     

空调中分布型主动式热回收系统的分析

利用水或乙二醇对空调系统中的余热进行回收,加热空调系统进口新风,使除湿后的新风达到升温的目的。通过余热利用降低加热新风所需要的燃料,减少了二氧化碳的排放。分析讨论了瑞士Konvekta分布型主动式热回收产品的工作原理、使用效果及发展前景。     

Active disturbance rejection control to MIMO nonlinear systems with stochastic uncertainties: approximate decoupling and output-feedback stabilisation

ABSTRACT

In this paper, we apply the active disturbance rejection control, an emerging control technology, to output-feedback stabilisation for a class of uncertain multi-input multi-output nonlinear systems with vast stochastic uncertainties. Two types of extended state observers (ESO) are designed to estimate both unmeasured states and stochastic total disturbance which includes unknown system dynamics, unknown stochastic inverse dynamics, external stochastic disturbance without requiring the statistical characteristics, uncertain nonlinear interactions between subsystems, and uncertainties caused by the deviation of control parameters from their nominal values. The estimations decouple approximately the system after cancelling stochastic total disturbance in the feedback loop. As a result, we are able to design an ESO-based stabilising output-feedback and prove the practical mean square stability for the closed-loop system with constant gain ESO and the asymptotic mean square stability with time-varying gain ESO, respectively. Some numerical simulations are presented to demonstrate the effectiveness of the proposed output-feedback control scheme.     

Evolution mechanism of active groups and thermal effects of Chinese lignite in low-temperature oxidation

Abstract

The evolution of active groups at low temperature was examined using Chinese lignite by infrared technology and X-ray photoelectron spectroscopy (XPS). The results showed that the hydroxyl, aliphatic ether, methylene, and methyl groups played important roles in the low-temperature oxidation of lignite below 200?°C. Carbonyl and carboxyl groups were important intermediates. Thus, a multi-step evolution mechanism involving the hydroxyl, aliphatic ether groups, and alkane was reasoned to describe the low-temperature oxidation of lignite. In addition, according to the oxidation kinetics experiment and the evolution laws of the active groups, the ratios of the reaction lines were determined considering the accuracy of thermal effects. The thermal effects and the heat release intensities of each temperature interval were obtained based on the evolution mechanism and the reaction ratios. The shortest spontaneous combustion period of lignite was calculated and compared with the experimental value, which proved that the reasoned evolution mechanism of the active groups and the calculations of the thermal effects were reliable.     

Tuning morphology and structure of Fe–N–C catalyst for ultra-high oxygen reduction reaction activity

Exploring efficient and durable non-precious metal catalysts for oxygen reduction reaction (ORR) has long been pursued in the field of metal-air batteries, fuel cells, and solar cells. Rational design and controllable synthesis of desirable catalysts are still a great challenge. In this work, a novel approach is developed to tune the morphologies and structures of Fe–N–C catalysts in combination with the dual nitrogen-containing carbon precursors and the gas-foaming agent. The tailored Fe–N₁/N₂–C-A catalyst presents gauze-like porous nanosheets with uniformly dispersed tiny nanoparticles. Such architectures exhibit abundant Fe-N_x active sites and high-exposure surfaces. The Fe–N₁/N₂–C-A catalyst shows extremely high half-wave potential (E_1/2, 0.916 V vs. RHE) and large limiting current density (6.3 mA cm⁻²), far beyond 20 wt% Pt/C catalyst for ORR. This work provides a facile morphological and structural regulation to increase the number and exposure of Fe-N_x active sites.