全文获取类型
收费全文 | 2447篇 |
免费 | 169篇 |
国内免费 | 138篇 |
专业分类
电工技术 | 87篇 |
综合类 | 89篇 |
化学工业 | 541篇 |
金属工艺 | 224篇 |
机械仪表 | 92篇 |
建筑科学 | 288篇 |
矿业工程 | 23篇 |
能源动力 | 111篇 |
轻工业 | 213篇 |
水利工程 | 166篇 |
石油天然气 | 148篇 |
武器工业 | 14篇 |
无线电 | 193篇 |
一般工业技术 | 170篇 |
冶金工业 | 91篇 |
原子能技术 | 62篇 |
自动化技术 | 242篇 |
出版年
2024年 | 4篇 |
2023年 | 29篇 |
2022年 | 54篇 |
2021年 | 85篇 |
2020年 | 42篇 |
2019年 | 66篇 |
2018年 | 61篇 |
2017年 | 91篇 |
2016年 | 97篇 |
2015年 | 95篇 |
2014年 | 106篇 |
2013年 | 128篇 |
2012年 | 165篇 |
2011年 | 220篇 |
2010年 | 142篇 |
2009年 | 143篇 |
2008年 | 131篇 |
2007年 | 170篇 |
2006年 | 156篇 |
2005年 | 123篇 |
2004年 | 79篇 |
2003年 | 81篇 |
2002年 | 76篇 |
2001年 | 44篇 |
2000年 | 47篇 |
1999年 | 37篇 |
1998年 | 22篇 |
1997年 | 30篇 |
1996年 | 27篇 |
1995年 | 11篇 |
1994年 | 11篇 |
1993年 | 18篇 |
1992年 | 25篇 |
1991年 | 16篇 |
1990年 | 16篇 |
1989年 | 14篇 |
1988年 | 8篇 |
1987年 | 12篇 |
1986年 | 6篇 |
1985年 | 11篇 |
1984年 | 10篇 |
1983年 | 1篇 |
1982年 | 9篇 |
1981年 | 1篇 |
1980年 | 9篇 |
1979年 | 5篇 |
1978年 | 6篇 |
1977年 | 7篇 |
1976年 | 3篇 |
1975年 | 4篇 |
排序方式: 共有2754条查询结果,搜索用时 281 毫秒
1.
Reliable joints of Ti3SiC2 ceramic and TC11 alloy were diffusion bonded with a 50 μm thick Cu interlayer. The typical interfacial structure of the diffusion boned joint, which was dependent on the interdiffusion and chemical reactions between Al, Si and Ti atoms from the base materials and Cu interlayer, was TC11/α-Ti + β-Ti + Ti2Cu + TiCu/Ti5Si4 + TiSiCu/Cu(s, s)/Ti3SiC2. The influence of bonding temperature and time on the interfacial structure and mechanical properties of Ti3SiC2/Cu/TC11 joint was analyzed. With the increase of bonding temperature and time, the joint shear strength was gradually increased due to enhanced atomic diffusion. However, the thickness of Ti5Si4 and TiSiCu layers with high microhardness increased for a long holding time, resulting in the reduction of bonding strength. The maximum shear strength of 251 ± 6 MPa was obtained for the joint diffusion bonded at 850 °C for 60 min, and fracture primarily occurred at the diffusion layer adjacent to the Ti3SiC2 substrate. This work provided an economical and convenient solution for broadening the engineering application of Ti3SiC2 ceramic. 相似文献
2.
为分析地表径流速度对城市内涝的影响,采用一维地下排水管网与二维城区地形的动态耦合模型,选取大连市某排水区块作为研究区域,设置4种地表径流速度10种设计降雨场景,模拟分析在不同重现期设计降雨及不同地表径流速度下研究区的内涝积水特性。结果表明:随着地表径流速度降低,管道排水压力变小,管道排水达标率最高可提升48.05%,且降雨重现期越短,地表径流流速对管道排水压力的削减效果越明显;地表径流流速对检查井溢流量影响显著,随着地表径流速度降低,检查井溢流量峰值最高可减小2 750 m~3,峰现时间最长可滞后56 min,同时随着降雨重现期增长,地表径流流速对检查井溢流量的削减效果减弱;研究区低、高风险区淹没面积随地表径流速度降低,最高可分别减小1.64万、8.37万m~2,但中风险区淹没面积变化反复。 相似文献
3.
Jing-jie Xie Xiao-Li Zou Yan-ping Li Zhuang-Li Kang Han-jun Ma 《International Journal of Food Science & Technology》2022,57(4):2459-2466
The effects of high-pressure-modified soy 11S globulin (0.1, 200, and 400 MPa) on the gel properties, water-holding capacity, and water mobility of pork batter were investigated. The high-pressure-modified soy 11S globulin significantly increased (P < 0.05) the emulsion stability, cooking yield, hardness, springiness, chewiness, resilience, cohesiveness, the a* and b* values, and the G′ and G′′ values of pork batter at 80 °C, compared with those of 0.1 MPa-modified globulin. In contrast, the centrifugal loss and initial relaxation time of T2b, T21, and T22 significantly decreased (P < 0.05). Meanwhile, the microstructure was denser, and the voids were smaller and more uniform compared with those of 0.1 MPa-modified globulin. In addition, the sample with 11S globulin modified at 400 MPa had the best water-holding capacity, gel structure, and gel properties among the samples. Overall, the use of high-pressure-modified soy 11S globulin improved the gel properties and water-holding capacity of pork batter, especially under 400 MPa. 相似文献
4.
SeyedHosein Payandeh Daniel Rentsch Zbigniew Łodziana Ryo Asakura Laurent Bigler Radovan Černý Corsin Battaglia Arndt Remhof 《Advanced functional materials》2021,31(18):2010046
Hydroborate-based solid electrolytes have recently been successfully employed in high voltage, room temperature all-solid-state sodium batteries. The transfer to analogous lithium systems has failed up to now due to the lower conductivity of the corresponding lithium compounds and their high cost. Here LiB11H14 nido-hydroborate as a cost-effective building block and its high-purity synthesis is introduced. The crystal structures of anhydrous LiB11H14 as well as of LiB11H14-based mixed-anion solid electrolytes are solved and high ionic conductivities of 1.1 × 10−4 S cm−1 for Li2(B11H14)(CB11H12) and 1.1 × 10−3 S cm−1 for Li3(B11H14)(CB9H10)2 are obtained, respectively. LiB11H14 exhibits an oxidative stability limit of 2.6 V versus Li+/Li and the proposed decomposition products are discussed based on density functional theory calculations. Strategies are discussed to improve the stability of these compounds by modifying the chemical structure of the nido-hydroborate cage. Galvanostatic cycling in symmetric cells with two lithium metal electrodes shows a small overpotential increase from 22.5 to 30 mV after 620 h (up to 0.5 mAh cm−2), demonstrating that the electrolyte is compatible with metallic anodes. Finally, the Li2(B11H14)(CB11H12) electrolyte is employed in a proof-of-concept half cell with a TiS2 cathode with a capacity retention of 82% after 150 cycles at C/5. 相似文献
5.
Crystallization of polyamide 11 at low supercooling of the melt proceeds via heterogeneous nucleation and spherulitic growth of lamellae, while at temperatures close to the glass transition homogeneous nucleation prevails, preventing spherulite formation and leading to formation of a large number of nanometer‐sized mesophase domains. It is shown that spherulitic and non‐spherulitic crystallization at low and high supercooling of the melt, respectively, can be enforced by tailoring the cooling conditions, causing a twofold semicrystalline morphology at ambient temperature. Analysis of non‐isothermal crystallization as a function of the cooling rate, using fast scanning chip calorimetry, reveals that in the case of polyamide 11 such twofold semicrystalline morphology is predicted when cooling at rates between about 20 and 200 K s?1, since then two separate crystallization events are observed. The prediction has been confirmed by preparation of films crystallized during ballistic cooling at different rates which then were analyzed regarding their structure using optical microscopy, X‐ray diffraction and calorimetry. The study is completed by discussion of implications of twofold non‐isothermal crystallization for structure evolution in polymer processing, as well as by providing information that such behavior is not only typical for polyamide 11 but also for isotactic polypropylene or poly(butylene terephthalate) as two further examples. © 2018 Society of Chemical Industry 相似文献
6.
Dr. Xiaoyun Deng Dr. Akiko Hatori Dr. Zhen Chen Dr. Katsushi Kumata Dr. Tuo Shao Dr. Xiaofei Zhang Dr. Tomoteru Yamasaki Dr. Kuan Hu Dr. Qingzhen Yu Dr. Longle Ma Dr. Gangqiang Wang Dr. Lu Wang Prof. Dr. Yihan Shao Prof. Dr. Lee Josephson Prof. Dr. Shaofa Sun Prof. Dr. Ming-Rong Zhang Prof. Dr. Steven Liang 《ChemMedChem》2019,14(3):303-309
Muscarinic acetylcholine receptors (mAChRs) have five distinct subunits (M1–M5) and are involved in the action of the neurotransmitter acetylcholine in the central and peripheral nervous system. Attributed to the promising clinical efficacy of xanomeline, an M1/M4-preferring agonist, in patients of schizophrenia and Alzheimer's disease, M1- or M4-selective mAChR modulators have been developed that target the topographically distinct allosteric sites. Herein we report the synthesis and preliminary evaluation of 11C-labeled positron emission tomography (PET) ligands based on a validated M4R positive allosteric modulator VU0467485 (AZ13713945) to facilitate drug discovery. [11C]VU0467485 and two other ligands were prepared in high radiochemical yields (>30 %, decay-corrected) with high radiochemical purity (>99 %) and high molar activity (>74 GBq μmol−1). In vitro autoradiography studies indicated that these three ligands possess moderate-to-high in vitro specific binding to M4R. Nevertheless, further physiochemical property optimization is necessary to overcome the challenges associated with limited brain permeability. 相似文献
7.
8.
基于一、二维耦合模型的某湿地公园水网规划与水力优化应用 总被引:1,自引:0,他引:1
湿地水网规划和设计需要考虑防洪排涝、生物栖息地构建及水资源调度等多个因素的协调,单一维度的数值模型难以解决河网、湖区及工程调度等多种模拟对象的尺度协调问题。针对某感潮河网区域生态湿地公园的规划设计,利用MIKE Flood软件,构建一、二维耦合水动力模型,就河网规模、堰顶高程控制、生物栖息地构建等目标开展计算分析,通过方案比选确定相关工程规模,并通过区域微地形调整对鱼类和禽类栖息地水动力条件进行优化,使其满足生境构建要求。该结果不仅为相关设计单位提供了工作思路,所采用的建模方法和参数选取也可为类似项目参考。 相似文献
9.
Yuchao Lyu Weilong Zhan Zhumo Yu Xinmei Liu Ye Yang Xiaoxing Wang Chunshan Song Zifeng Yan 《材料科学技术学报》2021,76(17):86-94
Hydroisomerization of linear alkanes to branched isomers is an important petrochemical process for production of gasoline with high octane number.Non-noble metal bifunctional catalysts used in this process always suffer from low metal dispersion and poor metal-acid synergy.Herein,a facile one-pot synthesis method was used to simultaneously regulate metal particle sizes and acidity of the Ni-SAPO-11 hydroisomerization catalyst.The physicochemical properties are investigated using XANES,EXAFS,TEM/STEM,FT-1R,XPS,UV-vis and NH3-TPD.Apart from the highly dispersed nickel nanoparticles with an average diameter of 8 nm,the framework Ni2+ions are generated via substituting framework Al3+ions of the SAPO-11.The formed NiP-OH structures have lower deprotonation energy(DPE)than the SiAl-OH ones,contributing more and stronger acid sites to the Ni-SAPO-11 catalyst.The great metal-acid synergy including high metal to acid sites ratio(nNi/nA)and close intimacy is obtained for the Ni-SAPO-11 catalyst.The Ni-SAPO-11 catalyst outperforms the counterpart prepared by the impregnation method and exhibits comparable activity and isomers selectivity to the Pt/SAPO-11 catalyst in the n-hexane hydroisomerization. 相似文献
10.
The role of starch aerogel (St-AG) and carboxymethyl cellulose (CMC) as biolgical active compounds, when they subjected for complexation with metal ions, is assessed in this work. The complexation is carried out with palladium(II) and copper(II) ions, in solid state. Different tools of analysis are carried out to characterize and elucidate the structures of these complexes, namely: elemental analysis, IR, thermal analysis, magnetic measurement and molar conductance techniques. All synthesized complexes are formed with 1:2 (metal:ligand) stoichiometry except the case of aerogel starch 1:1 (Pd:starch). All isolated complexes show a satisfactory cytotoxic effect results against colon cancer cell lines HCT11. Additionally, these complexes are screened for their antibacterial activities against two types of Gram positive and negative bacteria. Molecular docking investigation confirmed the cytotoxicity and antibacterial results. Proton–ligands association constants and their complex formation constants with some bivalent metal ions, using potentiometric method show that the complexes formed in solution have a stoichiometry of 1:1 [metal:ligand]. The effects of metal ion, ionic radius, electronegativity and nature of ligand on the formation constants are discussed. The formation constants of the complexes with 3D transition metals followed the order Mn2+ < Co2+ < Ni2+ < Cu2+ > Zn2+. 相似文献