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排序方式: 共有1563条查询结果,搜索用时 23 毫秒
1.
Lei He Yan Xuan Feng Zhang Xue Wang Huaqing Pan Junfeng Ren Meina Chen 《International Journal of Hydrogen Energy》2021,46(1):1096-1105
Bulk and surface properties of proton stability and transportation in Y and Nd co-doped BaCeO3 (BCYN), especially the effect of Nd segregation, were investigated by first-principles calculations. Since the structure of doped BaCeO3 at the operating temperature of proton-conducting has been unclear for a long time, we have summarized the latest experimental results and calculated the structure of the asymmetric BCYN for the first time. The results show that compared with Y, Nd doping promotes oxygen vacancy formation, however reduces proton stability. Our calculation can also provide a possible explanation for the formation of space charge layer at the grain boundary of doped BaCeO3 in experiment. Unlike the stable Y in BCYN, Nd is calculated to be easily segregated, which can facilitate both proton hydration and proton transportation near the surface. Moreover, Nd segregation at the grain boundary is predicted to be beneficial for proton transportation between grains. 相似文献
2.
Yongqiang Zhang Zhiwei Zhou Weiwei Li Yu Yang Bingchu Mei Zaichun Sun 《Journal of the American Ceramic Society》2022,105(4):2932-2944
Nd3+ doped strontium fluorophosphate (S-FAP), with chemical formula Sr5(PO4)3F, nanopowders were prepared using the co-precipitation method. The prepared powders had no impurity phase with a grain size of about 30 nm and the doping limit of Nd3+ ions in strontium fluorophosphate is about 9 at.%. The morphology and particle size were determined by the doping concentration of Nd3+. Anisotropic Nd: S-FAP transparent ceramics with different Nd3+ doping concentrations were fabricated successfully by the simple hot-pressing method. The grain size of prepared S-FAP transparent ceramics decreased first and then increased with the increase of Nd3+ concentration. The 2 at.% Nd: S-FAP ceramic presented the highest optical transmittance at all wavelengths range. The characteristic transitions from the ground state to the excited states of Nd3+ ions were observed from the absorption spectra, and the absorption cross-section was calculated at 3.71 × 10–20 cm2. The influence of Nd3+ ion concentration on luminescence intensity and fluorescence lifetime was studied under 796 nm excitation. The strong emission of 4F3/2→4I9/2 transition in Nd: S-FAP was calculated by Judd–Ofelt (J-O) theory. 相似文献
3.
Wei Jing Fang Li Shengquan Yu Xiangbo Ji Tao Xu Jian Zhang Zhongben Pan Zerui Yuan Bin Kang Jianguo Deng Wenlong Yin Hui Huang 《Journal of the European Ceramic Society》2018,38(5):2454-2461
A spray co-precipitation method was developed to efficiently synthesize Nd:YAG nano-powders. The effects of spray speeds and solution concentrations on the crystallization processes of calcined precursors have been studied. The results indicated that the pure phase of YAG could be obtained by three different crystallization processes owing to different homogeneity levels of Y and Al mixing. Pure YAG powder was obtained at 850?°C and the phase purity persisted to 1600?°C. Using the obtained powders, transparent ceramics with the in-line transmittance up to 80.2%@400 nm and 83.1%@1064?nm were fabricated by gel-casting method and hot isostatic pressing sintering. Furthermore, the microstructure and laser properties of the transparent ceramics have been measured. The maximum laser output of 7.015?W has been obtained with an oscillation threshold and a slope efficiency of 0.235?W and 59.4%, respectively. 相似文献
4.
In the present work, transparent and conductive Nd doped SnO2 thin films were deposited via spray pyrolysis. Crystallographic, morphological, optical and electrical characterizations of SnO2 were researched as a function of Nd doping. The XRD analysis indicated the films had tetragonal cassiterite tin oxide structure and (211) preferential direction for NdTO-0, NdTO-1, NdTO-2 and NdTO-3 samples changed to (110) plane for NdTO-4 and NdTO-5 samples. The crystalline size and strain analysis were made by using a Williamson–Hall method. The SEM micrographs showed that all films had homogenously scattered pyramidal and small densely nanoparticles. The optical analysis indicated optical band gap value of undoped film increased with 1 at% Nd doping and then it decreased with more Nd content. The Hall measurements indicated that the highest electrical conductivity was obtained for 2 at% Nd doping content. 相似文献
5.
《Ceramics International》2022,48(7):9658-9666
Polycrystalline Nd:YAG materials have wide applications in solid-state lasers. In this study, micro hole drilling experiments were performed on polycrystalline Nd:YAG using a polycrystalline diamond micro drill. The hole diameter, edge chipping, and hole wall surface quality were examined in detail. The results showed that the hole diameter was slightly larger than tool diameter. A diameter error of less than 5.5% was achieved. The edge chipping at the entry hole was formed by the encircled petal shape exfoliations, which were produced by the indentation and rotation movement in the drilling entry stage. Edge chipping at the exit hole was generated by an entire piece of exfoliation, which was produced by a circle of microcracks around the tool tip propagating to the bottom surface in the drilling exit stage. The edge chipping width at the entry hole was smaller than that at the exit hole. Based on different material removal modes, the hole surface morphology was classified into three types: ductile removal, coexisting ductile and brittle removal, and brittle removal. The hole surface quality mainly depended on the proportion of the brittle fracture to ductile removal surface. 相似文献
6.
采用燃烧法合成出Ca12Al14O33∶Eu2+,Nd3+靛蓝色长余辉发光粉.利用XRD和FE-SEM对产物的物相结构和形貌进行了表征,用激发光谱、发射光谱和余辉衰减曲线对样品的发光性能进行了分析.通过正交试验设计,以余辉时间为指标,研究了Eu2+的掺杂量、Nd3+的掺杂量、H3B03的用量以及尿素的用量对制备条件的影响.研究结果表明:最优化方案制备的Ca12Al14O33∶Eu2+,Nd3+长余辉发光粉的发射光谱呈宽发射谱带,波长范围为390~530 nm,发光峰值位于443 nm,余辉时间长达3240 s. 相似文献
7.
8.
Hang Liu Xiaofeng Zhao Yuancheng Teng Yuxiang Li Xiayu Zheng Shanlin Wang Lang Wu Pritam Kumar Panda Rajeev Ahuja 《Journal of the American Ceramic Society》2022,105(7):4974-4985
LnPO4 · 0.667H2O rhabdophane has been considered as a potential material for the precipitation of actinides from radioactive waste liquid, owing to its outstanding characteristics of high actinide bearing and easy synthesis in acid solutions. However, a comprehensive understanding of the actinide occupation and the precipitation response of rhabdophane to remove actinides has yet to be established. In this study, the effect of ions concentration and pH values on the detailed precipitation reaction of CexNd1-xPO4 · 0.667H2O rhabdophane in acid solutions are systematically investigated. Some specific issues such as structural distortion and flexibility, and occupation mechanism are discussed by combining with experiments and density functional theory (DFT) calculation. The results reveal that ions concentration and pH values have a significant impact on the crystallization nucleation step before 12 h. The obtained removal rate of Nd3+ is more than 99% in pH 1–5 solutions with the ions concentration of 0.05–0.1 mol/L. Moreover, incorporating Nd in CePO4 · 0.667H2O rhabdophane will easily result in the lattice distortion in b-axis. DFT calculation and X-ray photoelectron spectroscopy (XPS) results reveal that Nd is preferentially incorporated in nonhydrated site to form a weaker binding energy of NdO8 polyhedron. 相似文献
9.
利用双主相合金法制备了Ce取代的廉价(Nd,Ce)-Fe-B磁体,研究了Ce取代对永磁体烧结致密化行为、显微结构与磁性能的影响。结果表明,用Ce部分取代Nd能够促进烧结,降低烧结温度;随着Ce取代量的增加,晶粒开始明显长大,磁体晶粒尺寸变得不均匀,晶间富稀土相也开始团聚,磁体各项磁性能逐步降低,在Ce取代量为总稀土的20%时,材料剩磁为1.05T,内禀矫顽力为651.4k A/m(8.18k Oe),最大磁能积为198.4k J/m3(24.92MGOe),仍具有较好的综合磁性能。 相似文献
10.