全文获取类型
收费全文 | 182423篇 |
免费 | 25472篇 |
国内免费 | 6191篇 |
专业分类
电工技术 | 9009篇 |
技术理论 | 12篇 |
综合类 | 9515篇 |
化学工业 | 40666篇 |
金属工艺 | 8337篇 |
机械仪表 | 9833篇 |
建筑科学 | 13132篇 |
矿业工程 | 4401篇 |
能源动力 | 4906篇 |
轻工业 | 16065篇 |
水利工程 | 2796篇 |
石油天然气 | 7913篇 |
武器工业 | 1078篇 |
无线电 | 24284篇 |
一般工业技术 | 28521篇 |
冶金工业 | 7979篇 |
原子能技术 | 1596篇 |
自动化技术 | 24043篇 |
出版年
2024年 | 676篇 |
2023年 | 2482篇 |
2022年 | 4257篇 |
2021年 | 6102篇 |
2020年 | 5762篇 |
2019年 | 6592篇 |
2018年 | 7025篇 |
2017年 | 7831篇 |
2016年 | 7648篇 |
2015年 | 9165篇 |
2014年 | 10407篇 |
2013年 | 12984篇 |
2012年 | 11458篇 |
2011年 | 11807篇 |
2010年 | 10890篇 |
2009年 | 10640篇 |
2008年 | 10003篇 |
2007年 | 9308篇 |
2006年 | 9426篇 |
2005年 | 8169篇 |
2004年 | 6065篇 |
2003年 | 5636篇 |
2002年 | 5456篇 |
2001年 | 5007篇 |
2000年 | 4681篇 |
1999年 | 4578篇 |
1998年 | 3493篇 |
1997年 | 3031篇 |
1996年 | 2738篇 |
1995年 | 2315篇 |
1994年 | 1833篇 |
1993年 | 1463篇 |
1992年 | 1148篇 |
1991年 | 855篇 |
1990年 | 699篇 |
1989年 | 579篇 |
1988年 | 456篇 |
1987年 | 334篇 |
1986年 | 228篇 |
1985年 | 197篇 |
1984年 | 123篇 |
1983年 | 95篇 |
1982年 | 99篇 |
1981年 | 64篇 |
1980年 | 62篇 |
1979年 | 38篇 |
1978年 | 27篇 |
1977年 | 26篇 |
1976年 | 40篇 |
1973年 | 11篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
1.
Pengfei Liang Jie Zhu Di Wu Hui Peng Xiaolian Chao Zupei Yang 《Journal of the American Ceramic Society》2021,104(6):2702-2710
Due to the demand of miniaturization and integration for ceramic capacitors in electronic components market, TiO2-based ceramics with colossal permittivity has become a research hotspot in recent years. In this work, we report that Ag+/Nb5+ co-doped (Ag1/4Nb3/4)xTi1−xO2 (ANTOx) ceramics with colossal permittivity over a wide frequency and temperature range were successfully prepared by a traditional solid–state method. Notably, compositions of ANTO0.005 and ANTO0.01 respectively exhibit both low dielectric loss (0.040 and 0.050 at 1 kHz), high dielectric permittivity (9.2 × 103 and 1.6 × 104 at 1 kHz), and good thermal stability, which satisfy the requirements for the temperature range of application of X9R and X8R ceramic capacitors, respectively. The origin of the dielectric behavior was attributed to five dielectric relaxation phenomena, i.e., localized carriers' hopping, electron–pinned defect–dipoles, interfacial polarization, and oxygen vacancies ionization and diffusion, as suggested by dielectric temperature spectra and valence state analysis via XPS; wherein, electron-pinned defect–dipoles and internal barrier layer capacitance are believed to be the main causes for the giant dielectric permittivity in ANTOx ceramics. 相似文献
2.
3.
Chao Chen Qixin Zhong Zhengxing Chen 《International Journal of Food Science & Technology》2022,57(5):2747-2755
The purpose of this study was to increase the water solubility and potential bioavailability of quercetin by encapsulation in whey protein isolate (WPI) based on a green, efficient pH-driven method. According to the results, the water solubility of quercetin increased by 346.9: times after loading into WPI nanoparticles. When the initial quercetin concentration was 0.25 mg mL−1 and WPI was 2% w/v, the encapsulation efficiency reached 94.1%, the Z-average diameter was 36.63 nm, and the zeta potential was −36.4 mV at pH 7.0. The fluorescence spectroscopy assay suggested the molecular complexation of quercetin and WPI at pH 12.0. X-ray diffraction assay indicated the enclosure of amorphous quercetin in WPI. Correspondingly, the bioaccessibility increased from 2.76% to 31.23% and the Caco-2 cell monolayer uptake increased from 0% to 2.12% after nanoencapsulation. This work confirmed that the pH-driven method is an effective approach to prepare WPI–quercetin nanocapsules to improve physical and potentially biological properties of quercetin. 相似文献
4.
目的:解决当前饮料瓶盖检测系统功能单一、体积偏大、颜色识别率低的问题。方法:提出一种基于ARM处理器的小型饮料瓶盖颜色识别系统设计方案,通过仿真软件HyperLynx的LineSim工具设计四层PCB板,设置传输线参数并进行阻抗匹配仿真分析;利用编译软件Jupyter Notebook实现阈值设置、目标轮廓检测、目标框出等功能。结果:在强、弱光条件下,识别系统对红、绿、蓝3种颜色瓶盖的识别率达到92.7%。结论:与傅里叶描述子相比,该识别系统识别准确率和精度更高,同时系统也具有人脸识别功能,适用于各种智能应用场景。 相似文献
5.
Wang Chen Bao Chun-Hui Wu Wan-Yu Hsu Chia-Hsun Zhao Ming-Jie Zhang Xiao-Ying Lien Shui-Yang Zhu Wen-Zhang 《Journal of Materials Science》2022,57(26):12341-12355
Journal of Materials Science - Molybdenum oxide (MoOx) films had been grown by using plasma-enhanced atomic layer deposition (PEALD) with Mo(CO)6 precursor and O2 plasma reactant in a substrate... 相似文献
6.
针对现有的混凝土裂缝检测算法在各种复杂环境中检测精度不够、鲁棒性不强的问题,根据深度学习理论和U-net模型,提出一种全U型网络的裂缝检测算法。首先,依照原U-net模型路线构建网络;然后,在每个池化层后都进行一次上采样,恢复其在池化层之前的特征图规格,并将其与池化之前的卷积层进行融合,将融合之后的特征图作为新的融合层与原U-net网络上采样之后的网络层进行融合;最后,为了验证算法的有效性,在测试集中进行实验。结果表明,所提算法的平均精确率可达到83.48%,召回率为85.08%,F1为84.11%,相较于原U-net分别提升了1.48%,4.68%和3.29%,在复杂环境中也能提取完整裂缝,保证了裂缝检测的鲁棒性。 相似文献
7.
Shannon Lee Scott L. Carnahan Georgiy Akopov Philip Yox Lin-Lin Wang Aaron J. Rossini Kui Wu Kirill Kovnir 《Advanced functional materials》2021,31(16):2010293
Noncentrosymmetric (NCS) tetrel pnictides have recently generated interest as nonlinear optical (NLO) materials due to their second harmonic generation (SHG) activity and large laser damage threshold (LDT). Herein nonmetal-rich silicon phosphides RuSi4P4 and IrSi3P3 are synthesized and characterized. Their crystal structures are reinvestigated using single crystal X-ray diffraction and 29Si and 31P magic angle spinning NMR. In agreement with previous report RuSi4P4 crystallizes in NCS space group P1, while IrSi3P3 is found to crystallize in NCS space group Cm, in contrast with the previously reported space group C2. A combination of DFT calculations and diffuse reflectance measurements reveals RuSi4P4 and IrSi3P3 to be wide bandgap (Eg) semiconductors, Eg = 1.9 and 1.8 eV, respectively. RuSi4P4 and IrSi3P3 outperform the current state-of-the-art infrared SHG material, AgGaS2, both in SHG activity and laser inducer damage threshold. Due to the combination of high thermal stabilities (up to 1373 K), wide bandgaps (≈2 eV), NCS crystal structures, strong SHG responses, and large LDT values, RuSi4P4 and IrSi3P3 are promising candidates for longer wavelength NLO materials. 相似文献
8.
Jia Dai Xiang Cheng Xiaofeng Li Zhisheng Wang Yufeng Wang Jing Zheng Jun Liu Jiawei Chen Changjin Wu Jinyao Tang 《Advanced functional materials》2021,31(48):2106204
Synthetic active matters are perfect model systems for non-equilibrium thermodynamics and of great potential for novel biomedical and environmental applications. However, most applications are limited by the complicated and low-yield preparation, while a scalable synthesis for highly functional microswimmers is highly desired. In this paper, an all-solution synthesis method is developed where the gold-loaded titania-silica nanotree can be produced as a multi-functional self-propulsion microswimmer. By applying light, heat, and electric field, the Janus nanotree demonstrated multi-mode self-propulsion, including photochemical self-electrophoresis by UV and visible light radiation, thermophoresis by near-infrared light radiation, and induced-charge electrophoresis under AC electric field. Due to the scalable synthesis, the Janus nanotree is further demonstrated as a high-efficiency, low-cost, active adsorbent for water decontamination, where the toxic mercury ions can be reclaimed with enhanced efficiency. 相似文献
9.
Shuang Chen Chao Yu Zhanfang Cao Xiaoping Huang Shuai Wang Hong Zhong 《International Journal of Hydrogen Energy》2021,46(10):7037-7046
The development of efficient and stable oxygen evolution reaction (OER) catalysts is an ongoing challenge. In order to solve the problem of low oxygen evolution efficiency of the current OER catalysts, a novel material was synthesized by the incorporation of NiFeCr-LDH and MoS2, and its structural and electrochemical properties were also investigated. The introduction of MoS2 improves the electrochemical performance of NiFeCr-LDH. The polarization curve shows that the potential of composite material is only 1.50 V at a current density of 10 mA cm?2, which is far superior to commercial precious metal catalysts. In addition, the stability experiment shows that the composite material has excellent stability, and the current density has little change after 500 cycles. Furthermore, we found that some metal ions, such as Ni, Cr and Mo, exist in the form of high valence on the surface of NiFeCr-LDH@MoS2, which is also conducive to the occurrence of oxygen evolution reaction. 相似文献
10.
Yunqi Li Jing Li Yang-Gang Wang Xiran Chen Mingtao Liu Zhong Zheng Xihong Peng 《International Journal of Hydrogen Energy》2021,46(24):13273-13282
In this work, density functional theory (DFT) calculations were used to investigate the mechanism of carbon corrosion on nitrogen-doped carbon support. Free energy diagrams were generated based on three proposed reaction pathways to evaluate corrosion mechanisms. The most energetically preferred mechanism on nitrogen-doped carbon was determined. The results show that the step of water dissociation to form #OH was the rate-determining step for gra-G-1N (graphene doped with graphitic N) and pyrr-G-1N (graphene doped with pyrrolic N). As for graphene doped with pyridinic N, the step of C#OC#O formation was critical. It was found that the control of nitrogen concentration was necessary for precisely designing optimized carbon materials. Abundance of nitrogen moieties aggravated the carbon corrosion. When the high potential was applied, specific types of graphitic N and pyridinic N were found to be favorable carbon modifications to improve carbon corrosion resistance. Moreover, the solvent effect was also investigated. The results provide theoretical insights and design guidelines to improve corrosion resistance in carbon support through material modification by inhibiting the adsorption of surface oxides (OH, O, and OOH). 相似文献