全文获取类型
收费全文 | 25567篇 |
免费 | 2552篇 |
国内免费 | 816篇 |
专业分类
电工技术 | 135篇 |
综合类 | 1164篇 |
化学工业 | 8184篇 |
金属工艺 | 676篇 |
机械仪表 | 242篇 |
建筑科学 | 710篇 |
矿业工程 | 222篇 |
能源动力 | 466篇 |
轻工业 | 12271篇 |
水利工程 | 172篇 |
石油天然气 | 804篇 |
武器工业 | 23篇 |
无线电 | 377篇 |
一般工业技术 | 1230篇 |
冶金工业 | 955篇 |
原子能技术 | 336篇 |
自动化技术 | 968篇 |
出版年
2024年 | 205篇 |
2023年 | 616篇 |
2022年 | 1485篇 |
2021年 | 1727篇 |
2020年 | 1160篇 |
2019年 | 1061篇 |
2018年 | 1044篇 |
2017年 | 1138篇 |
2016年 | 1222篇 |
2015年 | 1113篇 |
2014年 | 1492篇 |
2013年 | 1830篇 |
2012年 | 1806篇 |
2011年 | 1921篇 |
2010年 | 1312篇 |
2009年 | 1261篇 |
2008年 | 1089篇 |
2007年 | 1317篇 |
2006年 | 1092篇 |
2005年 | 778篇 |
2004年 | 678篇 |
2003年 | 597篇 |
2002年 | 492篇 |
2001年 | 394篇 |
2000年 | 330篇 |
1999年 | 253篇 |
1998年 | 196篇 |
1997年 | 181篇 |
1996年 | 160篇 |
1995年 | 145篇 |
1994年 | 136篇 |
1993年 | 118篇 |
1992年 | 111篇 |
1991年 | 72篇 |
1990年 | 74篇 |
1989年 | 50篇 |
1988年 | 47篇 |
1987年 | 37篇 |
1986年 | 35篇 |
1985年 | 24篇 |
1984年 | 22篇 |
1983年 | 14篇 |
1982年 | 8篇 |
1980年 | 22篇 |
1965年 | 5篇 |
1964年 | 8篇 |
1961年 | 5篇 |
1959年 | 7篇 |
1958年 | 5篇 |
1956年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 25 毫秒
1.
《International Journal of Hydrogen Energy》2022,47(10):6710-6720
Herein, molybdenum disulfide nanoflakes decorated copper phthalocyanine microrods (CuPc-MoS2) are synthesized via two step simple hydrothermal method. The as synthesized hybrid along with pure molybdenum disulfide (MoS2) nanoflower and pure copper phthalocyanine (CuPc) microrods are well characterized by various techniques that confirm phase, morphology, elemental compositions etc. Next, electrocatalytic oxygen reduction reaction towards fuel cell is investigated in alkaline medium and obtained results proclaim that our CuPc-MoS2 heterostructure outperforms the other two constituent materials. Efficient oxygen reduction is achieved following four electron pathway by CuPc-MoS2 whereas partial reduction is done through two electron process by CuPc and MoS2 separately. Long-time durability test reveals almost 97.6% retention after 8000s that eventually dictate us that CuPc-MoS2 heterostructure can be the efficient cathode electrocatalyst for future generation fuel cell. 相似文献
2.
3.
4.
《Ceramics International》2022,48(6):8297-8305
Pure and Sn/Fe co-doped (0.2 at.% Sn and 0.6 at.% Fe, 0.6 at.% Sn and 0.2 at.% Fe, 1.0 at.% Sn and 1.0 at.% Fe) TiO2 nanoparticles were synthesized via a sol-gel method and subsequently calcined at different temperatures. Furthermore, the particles were analyzed by TG-DSC, XRD, TEM, HRTEM, EDS, SAED and UV–Vis for investigating the influences of dopant and calcination temperature on the thermal effect, composition, morphology, energy band gap (Eg) and the degradation efficiency of methyl orange (MO) under various light irradiations respectively. Results indicated that Sn/Fe co-doping inhibited the crystallization transformation from anatase to rutile phase of TiO2 and decreased the Eg. The increased calcination temperature and Sn/Fe co-doped effect brought about the abnormal grain growth of TiO2 nanoparticles. 0.6 at.% Sn/0.2 at.% Fe and 1.0 at.% Sn/1.0 at.% Fe co-doped TiO2 nanoparticles presented better photocatalytic performance than pure and 0.2 at.% Sn/0.6 at.% Fe co-doped TiO2 nanoparticles under visible light irradiation mainly due to the decreased Eg. On the contrary, 0.2 at.% Sn and 0.6 at.% Fe co-doped TiO2 nanoparticles calcined at 650 °C showed the most excellent photocatalytic performance under UV light irradiation, which was about twice as large as that of pure TiO2 possibly due to the formed hybrid structure of anatase and rutile phase as well as the h+-mediated decomposition pathway. 相似文献
5.
6.
《Journal of dairy science》2022,105(12):9463-9475
Phenyllactic acid (PLA) has been demonstrated to possess antibacterial activity and capacity to prolong food shelf life. However, studies on the performance of PLA in inhibiting Staphylococcus aureus and its effectiveness when applied to dairy products are largely lacking. Here, antibacterial activity (planktonic and biofilm states) of PLA against S. aureus CICC10145 (S. aureus_45) were investigated. The results showed that PLA inhibited growth of S. aureus_45 and formation of S. aureus_45 biofilm. Next, the antibacterial action target of PLA was uncovered from both physiological and phenotypic perspectives. The results showed that PLA decreased cell metabolic activity and cell viability, damaged cell membrane integrity, triggered leakage of intracellular contents (DNA, proteins, and ATP), and caused oxidative stress damage and morphological deformation of S. aureus_45. In practical application, the antibacterial activity of PLA against S. aureus_45 cells was further confirmed in skim milk and cheese as dairy food models, and the antibacterial effects can be adequately maintained during storage for 21 d, at least at 4°C. These findings suggested that PLA could be a potential candidate for controlling S. aureus outgrowth in dairy foods. 相似文献
7.
Anna Stasiowicz Natalia Rosiak Ewa Tykarska Maciej Kozak Jacek Jenczyk Piotr Szulc Joanna Kobus-Cisowska Kornelia Lewandowska Anita Paziska Wojciech Paziski Judyta Cielecka-Piontek 《International journal of molecular sciences》2021,22(8)
Piperine is an alkaloid that has extensive pharmacological activity and impacts other active substances bioavailability due to inhibition of CYP450 enzymes, stimulation of amino acid transporters and P-glycoprotein inhibition. Low solubility and the associated low bioavailability of piperine limit its potential. The combination of piperine with 2-hydroxypropyl-β-cyclodextrin (HP-β-CD) causes a significant increase in its solubility and, consequently, an increase in permeability through gastrointestinal tract membranes and the blood–brain barrier. X-ray powder diffraction (XRPD), differential scanning calorimetry (DSC), Fourier-transform infrared spectroscopy (FT-IR), nuclear magnetic resonance (NMR) were used to characterize interactions between piperine and HP-β-CD. The observed physicochemical changes should be combined with the process of piperine and CD system formation. Importantly, with an increase in solubility and permeability of piperine as a result of interaction with CD, it was proven to maintain its biological activity concerning the antioxidant potential (2,2-diphenyl-1-picryl-hydrazyl-hydrate assay), inhibition of enzymes essential for the inflammatory process and for neurodegenerative changes (hyaluronidase, acetylcholinesterase, butyrylcholinesterase). 相似文献
8.
Paola Leonor Quan Marina Sabat-Bresc Yanru Guo Margarita Martín Gabriel Gastaminza 《International journal of molecular sciences》2021,22(9)
Recent research on mast cell biology has turned its focus on MRGPRX2, a new member of the Mas-related G protein-coupled subfamily of receptors (Mrgprs), originally described in nociceptive neurons of the dorsal root ganglia. MRGPRX2, a member of this group, is present not only in neurons but also in mast cells (MCs), specifically, and potentially in other cells of the immune system, such as basophils and eosinophils. As emerging new functions for this receptor are studied, a variety of both natural and pharmacologic ligands are being uncovered, linked to the ability to induce receptor-mediated MC activation and degranulation. The diversity of these ligands, characterized in their human, mice, or rat homologues, seems to match that of the receptor’s interactions. Natural ligands include host defense peptides, basic molecules, and key neuropeptides such as substance P and vasointestinal peptide (known for their role in the transmission of pain and itch) as well as eosinophil granule-derived proteins. Exogenous ligands include MC secretagogues such as compound 48/80 and mastoparan, a component of bee wasp venom, and several peptidergic drugs, among which are members of the quinolone family, neuromuscular blocking agents, morphine, and vancomycin. These discoveries shed light on its capacity as a multifaceted participant in naturally occurring responses within immunity and neural stimulus perception, as in responses at the center of immune pathology. In host defense, the mice Mrgprb2 has been proven to aid mast cells in the detection of peptidic molecules from bacteria and in the release of peptides with antimicrobial activities and other immune mediators. There are several potential actions described for it in tissue homeostasis and repair. In the realm of pathologic response, there is evidence to suggest that this receptor is also involved in chronic inflammation. Furthermore, MRGPRX2 has been linked to the pathophysiology of non-IgE-mediated immediate hypersensitivity drug reactions. Different studies have shown its possible role in other allergic diseases as well, such as asthma, atopic dermatitis, contact dermatitis, and chronic spontaneous urticaria. In this review, we sought to cover its function in physiologic processes and responses, as well as in allergic and nonallergic immune disease. 相似文献
9.
Xuejie Li Yaqing Wen Jian Zhang Dongyun Ma Jie Zhang Yanxia An Xiaoyan Song Xiujuan Ren Weifeng Zhang 《International Journal of Food Science & Technology》2022,57(3):1544-1553
The effects of non-thermal plasma (NTP) on the physicochemical properties of wheat flour and the quality of fresh wet noodles ( FWN) were investigated. The results showed that NTP effectively decreased the total plate count (TPC), yeast and mould count (YMC) and Bacillus spp. in wheat flour. Wet gluten contents and the stability time reached the maximum when treated for 20 s. The viscosity of starch increased significantly after treatment due to the increased of damaged starch. The contents of secondary structure were altered to some extent, which was because that the ordered network structure of gluten protein broken. Furthermore, compared with the control, texture properties of FWN were enhanced significantly at 20 s, and the darkening rate of FWN was greatly inhibited due to the low polyphenol oxidase (PPO) activity. Consequently, the most suitable treatment was 500 W for 20 s, providing a basis for the application of NTP in flour products. 相似文献
10.