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新型酸性镀铜添加剂及光亮剂简介 总被引:1,自引:0,他引:1
0前言 全光亮酸性镀铜层韧性和镀液光亮整平性良好,沉积速度较快,在塑料电镀金属铜-镍-铬装饰性电镀、印刷板孔金属化电镀以及电镀中占有重要的位置.要达到良好的效果和充分发挥其长处,关键在于光亮剂.国内外在开展酸性镀铜光亮剂的研究方面,重在研究硫脲衍生物,并探讨了其他染料以及含羟基的杂环化合物和聚醚化合物等光亮剂和整平剂,取得了明显的效果. 相似文献
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钢铁酸性直接镀铜工艺具有节能、环保双重优点.采用250 mL赫尔槽和加热急冷等方法,研究了组合添加荆GB-93在钢铁酸性直接镀铜中对镀层光亮范围、孔隙率、阴极电流效率、镀液深镀能力和镀层与基体结合力的影响.结果表明,通过加入GB-93添加剂,可在钢铁基体上直接电镀出光亮、结合力好的酸性铜层,可用于管件、盲孔件、铸铁件,也可用于滚镀或继续加厚其他镀层.酸性直接镀铜工艺解决了钢铁在碱性无氰镀铜中因钝化而导致结合力不良的问题,亦解决了钢铁管状件在电镀酸铜时内孔易出现铜粉的难题,可以代替剧毒的氰化铜预镀工艺.试验获得最佳工艺条件:20 g/L CuSO4·5H2O,40 g/L H2SO4,15mL/LGB-93A主剂 ,15 mL/L GB-93B助光剂,阴极电流电流密度0.8 A/dm2,温度30℃,电镀时间3 min.在上述工艺条件下,可以得到较高的阴极电流效率和良好的结合力. 相似文献
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稀土添加剂在光亮酸性镀铜中的应用 总被引:5,自引:2,他引:3
稀土元素由于具有独特的原子结构,其优异性能在金属表面处理领域中已得到越来越广泛的应用。 光亮硫酸盐镀铜,由于具有低成本、全光亮的优点,所以在装饰性电镀中被广泛应用,但是它存在着几个较大的缺点,就是孔隙率较大,在空气中极易变色,影响着产品总体镀层的耐蚀性能,为了克服这些缺点,往往采用增厚镀铜层的办法,这样既费时,又费料,特别是在电镀自动线上,由于工艺程序设计固定,往往在进入下一道工序之前,镀铜层产生变色,影响镀层的质量。添加稀土添加剂进行光亮酸性镀铜,能降低镀铜层的孔隙率,提高镀层的抗变色能力和耐蚀性,特别是对镀件总体复合镀层抗蚀能力的提高有十分明显的效果,具有十分重要的现实意义。1 实验 镀铜基础液取自某滚镀厂生产自动线10 m~3光亮酸性镀铜液,其原料都是工业级,工艺按常规工艺配方配制,自行配制光亮剂,稀土添加剂(自制),由稀土材料与相应的辅助材料混合配制而成。 相似文献
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锌合金压铸件缎面装饰电镀 总被引:1,自引:0,他引:1
介绍了锌合金压铸件缎面装饰电镀的予镀、加厚镀层工艺体系的选择和控制以及整个电镀工艺过程.提出了采用柠檬酸盐预镀镍,用HEDP镀铜锡合金进行加厚,其镀层无孔隙,从而为下步酸性镀亮镍、铬时,防止锌基体被腐蚀,并使之顺利地获得镀覆,提供了可靠的保证。 相似文献
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2—四氢噻唑硫酮系酸性光亮镀铜添加剂,它已广泛用于电镀工业,它能使镀层具有良好的整平性,延展性与光亮度,且有电流密度大,无公害等特点。本文介绍2—四氢噻唑硫酮的快速化学测定法。 相似文献
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A method is proposed for estimating the parameters of a mixture of exponential and Weibull distributions for which the accuracy of preliminary estimates obtained by graphical analysis is refined in accordance with the criterion of maximum likelihood. The efficiency of the proposed method is supported by the results of statistical modeling. 相似文献
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Liebert A Wabnitz H Grosenick D Möller M Macdonald R Rinneberg H 《Applied optics》2003,42(28):5785-5792
A novel method for the determination of the optical properties of tissue from time-domain measurements is presented. The data analysis is based on the evaluation of the first moment and the second centralized moment, i.e., the mean time of flight and the variance of the measured distribution of times of flight (DTOF) of photons injected by short (picosecond) laser pulses. Analytical expressions are derived for calculation of absorption and of reduced scattering coefficients from these moments by application of diffusion theory for infinite and semi-infinite homogeneous media. The proposed method was tested on experimental data obtained with phantoms, and results for absorption and reduced scattering coefficients obtained by the proposed method are compared with those obtained by fitting of the same data with analytical solutions of the diffusion equation. Furthermore, the accuracy of the moment analysis was investigated for a range of integration limits of the DTOF. The moment analysis may serve as a comparatively fast method for evaluating optical properties with sufficient accuracy and can be used, e.g., for on-line monitoring of optical properties of biological tissue. 相似文献
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Conventional methods for summation of direct measurement errors are considered. Conditions under which these methods provide consistent results are stated. It is proposed to utilize for characteristic of the total error, its interval estimator or the half-sum of the value obtained by adding up its arithmetic and geometric random errors.Translated from Izmeritel'naya Tekhnika, No. 4, pp. 10–12, April, 1995. 相似文献
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An approximate analytical expression is derived for the velocity of the front of the wave of change of boiling modes on a
rod and on a plate. The impact of the Thomson effect and of the heater orientation in the gravity field is included. Adequate
agreement is demonstrated between the derived relations and experimental data. 相似文献
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由于空压机进气侧轴承箱蜗壳温度探头密封效果不好,使空压机及其后续管道受到油污染。后将温度探头的O形圈密封改为骨架油封,杜绝了轴承箱漏油问题。文章简介空压机的结构和技术参数,详细介绍了骨架油封的制作和优点。 相似文献
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M. M. Gadenin 《Inorganic Materials》2013,49(15):1352-1356
It is shown that conditions of attainment of marginal states in the material of structural components are formulated on the basis of analysis of force and deformation criteria of formation and development of destruction. The parameters of these criteria are data on types of structural materials, standard and special characteristics of their mechanical properties, structural forms of considered elements of the equipment, and their operating stress loading. In this case, the construction of a system of state equations for describing interrelation of current damage, external actions, and responses to them is based on the concept of calculating variations in properties of materials at all stages of the design life cycle. 相似文献
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V. T. Kornienko 《Strength of Materials》1991,23(7):760-765
The article suggests a method of evaluating the microstructural inhomogeneity of deformation of metals by modeling. The method includes the measurement of deformations of metal according to meshes of a dividing grid with small base and the calculation of the distribution parameters of microdeformations in model representation. It is shown that the modeling method makes it possible objectively to evaluate the microinhomogeneity of deformation of metals independently of the chosen mesh size of the dividing grid. New structural characteristics are introduced: the base and wave of variation expressing the degree of crumbling or amalgamation of metal grains by inhomogeneity of deformation.Translated from Problemy Prochnosti, No. 7, pp. 40–44, July, 1991. 相似文献
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水三相点是开尔文热力学温度的唯一基准点,也是ITS-90国际温标重要的定义固定点。因此,水三相点不确定度分析对整个温标的建立、温度量值传递起着至关重要的作用。近3年来,中国计量科学研究院研制出一系列高质量的水三相点容器,加强了水三相点的研究,为不确定度的分析提供了更为可靠的实验依据。同时,不确定度的分析也是客观评价新研制容器性能的一个重要指标。因此,根据实验结果对新研制容器所复现的水三相点进行了不确定度评定。评定结果表明,其扩展不确定度为0.16mK(k=2.69,P=0.99)。 相似文献