聚酰亚胺胶粘剂的现状与研究进展

聚酰亚胺胶粘剂是一种重要的结构胶粘剂,本文综述了近年来聚酰亚胺胶粘剂的研究进展。     

耐高温聚酰亚胺胶粘剂的研究进展

综述了近年来国内外耐高温聚酰亚胺胶粘剂的研究发展状况,对热塑性和热固性聚酰亚胺胶粘剂的化学结构与性能特点进行了分析和总结,并对耐高温聚酰亚胺胶粘剂的未来发展趋势进行了展望.     

一种耐高温聚酰亚胺胶粘剂的合成

以醚胺(ODA)、砜胺(DDS)和醚酐(ODPA)、酮酐(BTDA)为原料,采用冷却法和加热法分别合成了一种耐高温聚酰亚胺胶粘剂。通过搭接试验和聚酰亚胺膜结构表征,比较了两种不同合成方法所得聚酰亚胺胶粘剂的性能差异。通过试验选择了亚胺胶的搭接工艺和固化工艺,从而使聚酰亚胺胶粘剂的粘接性能达到最佳。     

石英纤维增强聚酰亚胺蜂窝的研究

研究聚酰亚胺胶粘剂的结构与性能,蜂窝复合材料的高低温压缩性能。结果表明:聚酰亚胺胶粘剂具有较高的高低温拉伸搭接剪切强度,室温和200℃的搭接剪切强度分别为24.64MPa和18.36MPa,满足蜂窝芯材的粘接性能;石英纤维增强的聚酰亚胺蜂窝复合材料400℃压缩强度和压缩模量分别为1.72MPa和27.22MPa。     

可熔性聚酰亚胺胶粘剂的真空性能研究

本文介绍了可熔性聚酰亚胺胶粘剂与其他二种胶粘剂的结构及使用特点，并运用四极质谱计对它们进行真；空放气性能和放气成分的分析，通过分析比较可以看出可熔性聚酰亚胺不仅具有优良的耐高温特,而且还具有良好的真空性能，因此，它完全可能作为真空中使用的耐高温胶粘剂材料。     

2000 年中国聚酰亚胺的研究与应用文摘(续)

聚酰亚胺 /环氧树脂共混胶粘剂的热性能分析 /赵石林 (南京化工大学材料工程学院、秦传香 (苏州大学材料工程学院 ) /粘接 ,2 0 0 0 ,2 1(4) ,7～ 9。利用热重法研究了聚酰亚胺 /环氧树脂共混胶粘剂的耐热性。聚酰亚胺及其ＬＢ膜光电导性研究进展 /徐志康、朱宝库、徐又一 (浙江大学高分子科学与材料研究所 ) /高分子材料科学与工程 ,2 0 0 0 ,16 (3) ,6～ 9。对聚酰亚胺及其ＬＢ膜光电导性研究作了总结 ,讨论了分子链结构、取向、掺杂等因素对其光电子性的影响和电荷转移络合物光电导机理。聚酰亚胺纳米发泡薄膜的开发 /涂炽焕 /化工新型材…     

胶粘剂在粘接接头内热分解动力学的计算

为了研究粘接接头内胶粘剂的耐热性能,采用X射线能谱分析确定了不同条件下粘接接头内胶粘剂的元素组成及其变化行为,利用X射线能谱计算了胶粘剂的热失重率,进而计算出聚酰亚胺薄膜粘接接头内胶粘剂的热分解动力学,并与空气环境下胶粘剂热分解活化能进行了比较.计算结果表明,粘接接头内胶粘剂的热分解速率低于空气环境下胶粘剂热分解速率,这种分析测试方法为原位表征粘接接头内胶粘剂耐热性能提供了一种新的分析方法.     

铝离子增强聚酰亚胺胶粘剂

聚酰亚胺胶粘剂能用来粘结钛、耐热复合材料及薄膜,但在482～572°F粘结是失败的。以前提高高温强度的解决办法,是在胶粘剂中加入80％(重量)的铝粉,但这种办法大大增加了重量而使粘结面发脆。现在,美国国家航空航天局兰利研究中心的研究工作者,已经找到了仅仅加入2.5％     

固化剂对聚酰亚胺挠性覆铜板剥离强度的影响

采用双氰胺(DICY)、间苯二胺(m-PDA)、长链柔性二胺(DAMI)固化双酚A型环氧树脂(E-51),制备了三种环氧胶粘剂,分别考察了三种固化剂对挠性覆铜板剥离强度的影响。根据差示扫描量热仪(DSC)曲线,通过t-β外推法得到了各固化剂固化环氧胶粘剂的固化工艺。采用扫描电子显微镜(SEM)考察其不同的破坏形式。结果表明,采用双氰胺固化的环氧胶粘剂粘接的挠性覆铜板,剥离后聚酰亚胺薄膜、铜箔表面都留有大量的胶粘剂,此破坏形式属于内聚破坏。同时双氰胺固化的环氧胶粘剂剥离强度最高,粘接强度达到0.74 N/mm,符合日本JPAC行业标准。     

聚酰亚胺薄膜材料的制备和应用探究

聚酰亚胺被称为"解决问题的能手",主要由于这类材料是目前工业化的高分子材料中耐热性最好的品种,并具有一系列优越的综合性能,比如可以应用于薄膜材料、涂料、复合材料、胶粘剂、泡沫塑料、纤维、分离膜等的制作,并且在液晶取向及、光刻胶等高新技术领域也得到十分广泛的发展。本研究将根据聚酰亚胺薄膜材料的制作工艺及应用探究做出简要分析。     

Survey of Industrial,Agricultural, and Medical Applications of Radiometric Gauging and Process Control

Photon and particle radiations (gamma rays, x rays, brems-strahlung, electrons and other charged particles, and neutrons) from radioactive isotopes, x-ray tubes, and accelerators are now widely used in gauging, production control, and other monitoring and metrology devices where avoidance of mechanical contact is desirable. The general principles of radiation gauges, which rely on detection of radiation transmitted by the sample, or on detection of scattered or other secondary radiations produced in the sample, are discussed. Examples of such devices currently used or at least shown to be feasible in industrial, transportation, building, mining, agricultural, medical, and other metrology situations are presented, drawing from a total of 146 selected technical and review paper reference sources here cited.     

改性聚硫氨酯密封材料的制备及性能

制备了兼具聚氨酯、聚硫橡胶结构特征和性能优势的新型绿色高性能高分子密封材料——改性聚硫氨酯,并考察了其制备机理、流平性、弹性恢复率、拉伸模量、浸水和浸油后定伸粘接性、冷拉—热压后粘接性、质量损失率、抗燃性及耐老化性能。结果表明,聚硫氨酯强度高,变形、弹性恢复和耐老化性优良,模量和质量损失低,定伸60%、100%、150...     

微波消解-ICP-AES/ICP-MS测定大米中微量元素

采用微波消解技术,电感耦合等离子体光谱(ICP-AES)和电感耦合等离子体质谱(ICP-MS)测定了分别产自辽宁、四川、湖南三地的大米中21种元素B、Ba、Ca、Cd、Cu、Fe、K、Mg、Mn、Na、P、S、Sr、Zn、Co、Ni、Cr、Mo、Pb、Li、Cs。所有元素标准曲线回归方程线形系数均大于0.999,各元素相对标准偏差(RSD)均小于5.31%(测定次数n=4),加标回收率为96.6%～110.6%,方法检出限:ICP-AES为0.0048～0.33μg·mL-1,ICP-MS为0.022～0.192ng·mL-1。用国家一级标准物质大米(GBW10010)验证了方法的准确性,测定值与推荐值相符,实验表明,P、S、K、Mg、Ca、Na、Zn、Mn、Fe、Cu在大米中含量较高。此方法简便、快速,适用于大米等粮食作物中微量元素的测定。     

Low-Temperature Properties of Silver

Pure silver is used extensively in the preparation of high-temperature superconductor wires, tapes, films, and other configurations in which the silver not only shields the superconducting material from the surrounding materials, but also provides a degree of flexibility and strain relief, as well as stabilization and low-resistance electrical contact. Silver is relatively expensive, but at this stage of superconductor development, its unique combination of properties seems to offer the only reasonable means of achieving usable lengths of conductor. In this role, the low-temperature physical (electrical, thermal, magnetic, optical) and mechanical properties of the silver all become important. Here we present a collection of properties data extracted from the cryogenic literature and, to the extent possible, selected for reliability.     

Preparation and adsorbing performance of calcium titanate with template method

In this paper, using furfural residue as a template, porous calcium titanate (FPCT) was prepared by a sol-gel method and characterized by XRD, SEM, and nitrogen adsorption method. The conditions of preparation were investigated. The adsorption capabilities of FPCT for heavy metal ions were studied, and the adsorption mechanism was investigated. The results show that the calcium titanate was porous, and material is composed of crystals in nanoparticle size with a small amount of calcium sulfate impurities, while the sulfuric acid in furfural residue is fixed as the calcium sulfate in the material. The adsorbed quantity is affected by the pH value of medium and time. When the pH value of medium is 5, and oscillating adsorption lasts for 30?min, the adsorbed quantities of Cd, Pb, Zn, Cu, and Ni are 118.04, 197.96, 64.98, 56.85, and 47.91?mg/g, respectively. The adsorption conforms to the Langmuir adsorption isothermal model and pseudo-second-order kinetic equation, and is a spontaneous endothermic process driven by entropy. After adsorption, adsorbents can be regenerated with 1?mol/L nitrate solution. It is used for eliminating Cd, Pb, Zn, Cu, and Ni in wastewater and the results are satisfactory.     

白藜芦醇纳米载体的制备与表征

制备了负载1%白藜芦醇（Res）的三种脂质纳米载体,分别为固体脂质纳米粒（SLN）、纳米脂质载体（NLC）和纳米乳（NE）,通过进行离心、粒径、zeta电位、pH值、含量、包封率及对温度的稳定性等理化性质研究,结果表明,Res-SLN,粒径45±5nm,zeta电位-10.0±0.3mV,含量为9.57mg.mL-1,包封率为98.68%;Res-NLC,粒径185±3nm,zeta电位-10.8±0.5mV,含量为9.17mg.mL-1,包封率为99.36%;Res-NE,粒径7nm,zeta电位-4.8±0.4mV,含量为9.89mg.mL-1,包封率为97.97%。三种载体体系在4℃及25℃离心10000r/min,30min不分层。分别在室温、4℃、40℃下放置15d,Res-NLC表现出良好的稳定性。     

Thermophysical properties of some key solids: An update

In 1985, the CODATA Bulletin published a Report of its Task Group on Thermophysical Properties of Solids which analyzed available data on, and gave recommended values for, the heat capacity of Cu, Fe, W, and Al₂O₃, the thermal expansion of Cu, Si, W, and Al₂O₃, the electrical resistivity of Cu, Fe, Pt, and W, the thermal conductivity of Al, Cu, Fe, and W, and the absolute thermopower of Pb, Cu, Pt, and W. The analysts for the different properties were R. B. Castanet, S. J. Collocott, P. D. Desai, C. Y. Ho, J. G. Hust, R. B. Roberts, C. A. Swenson, and G. K. White. The present paper is an updated version of the earlier report and includes more recent data which change some of the recommended values. notably the heat capacity of Cu and W and the thermal expansion of Si and W.     

Survey of Experimental Data of Thermophysical Properties for Difluoromethane (HFC-32)

A survey of experimental data for HFC-32 was prepared at the Institute of Thermomechanics in connection with planned experiments. In tabular form, surveys of thermodynamic, transport, and other property measurements, including pvT behavior, second virial coefficient, vapor pressure, saturation densities, critical parameters, heat capacities, speed of sound, thermal conductivity, viscosity, surface tension, refractive index, dielectric constant, and dipole moment, are presented. Tables include author)s) name(s), reference, year of publication, ranges of measurements, number of points, stated uncertainty, sample purity, and experimental method.     

高强度高模量玻璃纤维特性与应用

与传统E玻璃纤维相比,高强度高模量玻璃纤维在拉伸强度、弹性模量、抗冲击性能、耐高温性能、耐腐蚀性能、电绝缘性和介电性能等方面都具有明显优势,可广泛地应用于航空航天、国防军事、风力发电、交通运输、体育休闲、压力容器、建筑工程、管道、环境处理、石油、机械等许多领域,成为本行业研究与开发的热点和重点.     

Microwave Processing of Materials and Applications in Manufacturing Industries: A Review

The main focused aim of developing new processing and manufacturing technologies are to reduce production or manufacturing costs, processing times, and to enhance manufactured product properties. The developed processing techniques should be widely acceptable for all types of materials including metal matrix composites, ceramics, alloys, and fiber reinforced plastics. Microwave materials processing is emerging as a novel processing technology which is applicable to a wide variety of materials system including processing of MMC, FRP, alloys, ceramics, metals, powder metallurgy, material joining, coatings, and claddings. In comparison to the conventional processes, microwave processing of materials offers better mechanical properties with reduced defects and economical advantages in terms of power and time savings. The present review work focuses mainly on global developments taking place in the field of microwave processing of materials and their relevant industrial applications.