The application of polyimide/silicon nitride dual passivation to AlxGa1−xN/GaN high electron mobility transistors

PECVD silicon nitride passivation is quite frequently done at the end of AlGaN/GaN HEMT fabrication before substrate back-side lapping. However, the PECVD silicon nitride process is likely to produce pinholes in the passivation film. A very thick PECVD silicon nitride film may produce mechanical stress on the underlying device. Polyimide passivation has also been known to be effective for AlGaN/GaN HEMT and it can also serve as a stress buffer. However, polyimide can take up water while PECVD silicon nitride is a good diffusion barrier for water, etc. Thus it is expected that a dual PECVD silicon nitride/polyimide passivation will be a better choice than just a single layer of PECVD silicon nitride or polyimide. In this paper, we will demonstrate the application of a dual PECVD silicon nitride/polyimide passivation to AlGaN/GaN HEMT process.     

多晶硅太阳电池PECVD氮化硅钝化工艺的研究

介绍等离子体化学气相淀积(PECVD)制备减反射钝化膜。将PECVD设备运用于太阳电池生产线上,发现通过PECVD设备可以对多晶硅太阳电池有很好的钝化效果。分析PECVD对多晶硅太阳电池钝化机理。     

Stability of sulfur-passivated facets of InGaAs-AlGaAs laser diodes

The facets of GaAs-AlGaAs ridge waveguide (RW) laser diodes were passivated using (NH/sub 4/)/sub 2/S/sub x/. The effectiveness of this procedure was checked by electroluminescence power-voltage-current (P-V-I) measurements that provide information on the changes in the density of surface states. Using this nondestructive method, the degradation of the passivation under ambient atmosphere has been studied. Capping with silicon nitride is found to stabilize the sulfur passivation and avoid degradation.     

Low-temperature gate dielectrics formed by plasma anodisation ofsilicon nitride

Silicon nitrides, deposited on silicon by PECVD using an SiH₄ /NH₃ plasma at 300°C, were anodised in an oxygen plasma at 500°C. The resulting dielectric appears to have lower fixed charge, leakage current and interface trap density than the original PECVD nitride, and to have the potential of use as a gate dielectric for MIS devices in VLSI circuits     

Passivation of GaAs FET's with PECVD silicon nitride films ofdifferent stress states

The passivation of GaAs MESFETs with plasma-enhanced chemical-vapor-deposited (PECVD) silicon nitride films of both compressive and tensile stress is reported. Elastic stresses included in GaAs following nitride passivation can produce piezoelectric charge density, which results in a shift of MESFET characteristics. The shift of MESFET parameters due to passivation was found to be dependent on gate orientation. The experiments show that nitride of tensile stress is preferable for MESFETS with [011-bar] oriented gates. The shifts in V_TH,I_DSS, and G_M of the devices before and after nitride passivation are less than 5% if the nitride of appropriate stress states are used for passivation. The breakdown voltage of the MESFETs after nitride deposition was also studied. It is found that the process with higher hydrogen incorporation tends to reduce the surface oxide and increase the breakdown voltage after nitride deposition. In addition, the passivation of double-channel HEMTs is reported for the first time     

Damage-free passivation of InAlAs/InGaAs HFETs by use of ECR-deposited SiN

Silicon nitride deposited by electron-cyclotron resonance has been used to fully passivate InAlAs/InGaAs HFETs. The passivation process did not increase the gate leakage current, and passivated 1 mu m HFETs had a breakdown voltage of 15 V. These results illustrate the potential of ECR nitride for passivation of InP-based semiconductor devices.<>     

Effects of SiN passivation and high-electric field on AlGaN-GaN HFET degradation

The authors report on the effects of silicon nitride (SiN) surface passivation and high-electric field stress (hot electron stress) on the degradation of undoped AlGaN-GaN power HFETs. Stressed devices demonstrated a decrease in the drain current and maximum transconductance and an increase in the parasitic drain series resistance, gate leakage, and subthreshold current. The unpassivated devices showed more significant degradation than SiN passivated devices. Gate lag phenomenon was observed from unpassivated devices and removed by SiN passivation. However, SiN passivated devices also showed gate lag phenomena after high-electric field stress, which suggests possible changes in surface trap profiles occurred during high-electric field stress test.     

采用AlN/SiNx钝化的高性能AlGaN/GaN HEMTs

两种不同的钝化层结构被应用到势垒层厚度为12 nm的AlGa/GaN 高电子迁移率场效应晶体管中。首先采用等离子增强原子层沉积(PEALD)技术生长5 nm的AlN薄膜,然后再覆盖50 nm的等离子增强化学气相淀积(PECVD)生长的SiNx。相比于传统的SiNx钝化,AlN钝化层的插入更有效地抑制了电流崩塌效应,同时获得了小的亚阈值斜率(SS)。AlN钝化层的插入增大了器件的射频跨导从而获得了较高的截止频率。另外,通过变温直流特性测试发现,AlN/SiNx钝化的器件在高温时饱和电流和最大跨导的衰退相对于仅采用SiNx钝化的器件都要小,表明AlN钝化层的插入改善了器件的高温稳定性。     

Stable gallium arsenide MIS capacitors and MIS field effecttransistors by (NH4)2Sx treatment andhydrogenation using plasma deposited silicon nitride gate insulator

The beneficial effects of sulfur passivation of gallium arsenide (GaAs) surface by (NH₄)₂S_x chemical treatment and by hydrogenation of the insulator-GaAs interface using the plasma-enhanced chemical vapor-deposited (PECVD) silicon nitride gate dielectric film as the source of hydrogen are illustrated by fabricating Al/PECVD silicon nitride/n-GaAs MIS capacitors and metal insulator semiconductor field effect transistors (MISFET). Post metallization annealing (PMA) at temperatures in the range 450-550°C is shown to be the key process for achieving midgap interface state density below 10 ¹¹/cm²/eV and maximum incremental transconductance, which is about 75% of the theoretical maximum limit. MIS capacitors are fabricated on (NH₄)₂S_x treated GaAs substrate using gate dielectrics such as PECVD SiO ₂ and silicon oxynitride to demonstrate that the PMA is less effective with these dielectrics because of their lower hydrogen content. The small signal AC transconductance, g_ms measurements on MISFETs fabricated using silicon nitride, have shown that the low-frequency degradation of g_ms is almost absent in the devices fabricated on (NH₄)₂S_x-treated GaAs substrates and subjected to PMA. The drain current stability in these devices is demonstrated to be excellent, with an initial drift of only 2% of the starting value. The dual role of silicon nitride layer, namely, protection against loss of sulfur and an excellent source of hydrogen for additional surface passivation along with sulfur is demonstrated by comparing the transconductance of MISFETs fabricated on GaAs substrates annealed without the nitride cap after the (NH₄)₂S _x treatment     

Optimization of saturation current density of PECVD SiN coated phosphorus diffused emitters using neural network modeling

Emitter surface passivation by low temperature plasma enhanced chemical vapor deposition (PECVD) silicon nitride is investigated and optimized in this paper. We have found that the saturation current density of a 90±10 μ/sq phosphorus diffused emitter with N_s ≈3 x 10¹⁹ and X_j ≈0.3 μm can be lowered by a factor of eight by appropriate PECVD silicon nitride deposition and photoassisted anneal. PECVD silicon nitride deposition alone reduces the emitter saturation density (J_oe) by about a factor of two to three, and a subsequent photoanneal at temperatures ≥350°C reduces J_oe by another factor of three. In spite of the larger flat band shift for direct PECVD silicon nitride coating, the silicon nitride induced surface passivation is found to be about a factor of two inferior to the thermal oxide plus PECVD silicon nitride passivation due to higher interface state density at the SiN/SiO₂ interface compared to SiO₂/Si interface. A combination of statistical experimental design and neural network modeling is used to show quantitatively that lower radio frequency power, higher substrate temperature, and higher reactor pressure during the PECVD deposition can reduce the J_oe of the silicon nitride coated emitter.     

Hydrogen desorption and diffusion in PECVD silicon nitride. Application to passivation of CMOS active pixel sensors

Presented either as a source or as a barrier to hydrogen, plasma deposited silicon nitride can impact microelectronic device performances. The objective of this paper is to clarify the hydrogen behavior in silicon nitride in order to optimize film characteristics for each microelectronic application. A design of experiments methodology was used to statistically discriminate films properties which govern hydrogen diffusion and desorption from PECVD silicon nitride. Finally, we confirm, thanks to trials on CMOS active pixel sensor devices and dark current measurements, the role of the SiN passivation layer on Si remaining defect and we propose an optimized passivation stack.     

Elimination of low frequency gain in InAlAs/InGaAs metal-semiconductor-metal photodetectors by silicon nitride passivation

We report the reduction of low frequency gain and surface recombination in InAlAs/InGaAs metal-semiconductor-metal (MSM) photodetectors, by surface passivation with plasma-enhanced chemical vapor deposition (PECVD) of silicon nitride. A corresponding improvement in device speed, measured in the frequency-domain, is demonstrated. Large (100 μm)² devices exhibit neartransit-time-limited bandwidth (>10 GHz) following passivation, and device characteristics have been stable over a period of several months. We propose a physical model for electron trapping at the free surface, to explain the low frequency gain in nonpassivated devices and its subsequent elimination.     

New applications of low temperature PECVD silicon nitride films for microelectronic device fabrication

Silicon nitride has been widely used in microelectronic device fabrication processes for encapsulation, surface passivation and isolation. In this paper we report new applications of plasma-enhanced chemical vapor deposition (PECVD) silicon nitride films that can be deposited at a temperature lower than the soft bake temperature of normal photoresists. Lift-off of the silicon nitride film was carried out using standard positive photoresist. GaAs MESFETs and InP MISFETs with self-aligned gates were successfully fabricated using this lift-off process of low temperature PECVD silicon nitride.     

High performance BCB-bridged AlGaAs/InGaAs power HFETs

A novel low-k benzocyclobutene (BCB) bridged and passivated layer for AlGaAs/InGaAs doped-channel power field effect transistors (FETs) with high reliability and linearity has been developed and characterized. In this study, we applied a low-k BCB-bridged interlayer to replace the conventional air-bridged process and the SiN/sub x/ passivation technology of the 1 mm-wide power device fabrication. This novel and easy technique demonstrates a low power gain degradation under a high input power swing, and exhibits an improved adjacent channel power ratio (ACPR) than those of the air-bridged one, due to its lower gate leakage current. The power gain degradation ratio of BCB-bridged devices under a high input power operation (P/sub in/ = 5 /spl sim/ 10 dBm) is 0.51 dB/dBm, and this value is 0.65 dB/dBm of the conventional air-bridged device. Furthermore, this novel technology has been qualified by using the 85-85 industrial specification (temperature = 85 C, humidity = 85%) for 500 h. These results demonstrate a robust doped-channel HFET power device with a BCB passivation and bridged technology of future power device applications.     

Improvements in direct-current characteristics of Al/sub 0.45/Ga/sub 0.55/As-GaAs digital-graded superlattice-emitter HBTs with reduced turn-on voltage by wet oxidation

Heterojunction bipolar transistors (HBTs) having an Al/sub 0.45/Ga/sub 0.55/As-GaAs digital-graded superlattice (DGSL) emitter along with an InGaP sub-emitter are reported. The band diagram of the DGSL emitter is analyzed by using a transfer matrix method and the theoretical result is consistent with the experimental observation that the DGSL emitter smoothes out the potential spike at the emitter-base junction. Such passivated HBTs with a high Al-fraction passivation layer exhibit a small offset voltage of 50 mV, a turn-on voltage of 0.87 V, and a current gain of 385. The HBTs are examined by wet-oxidizing the exposed passivated region under various conditions. Experimental results reveal that the HBTs with an exposed high Al-fraction emitter are sensitive to the ambient air. However, with InGaP capped upon the high Al-fraction emitter, the HBTs exhibit better oxidation quality. The wet oxidation brings forth the most remarkable improvements for the InGaP-capped HBTs when the passivation layer is totally wet oxidized. Furthermore, some devices from the same chip have undergone nitrogen treatment for comparison.     

High efficiency polycrystalline silicon solar cells using lowtemperature PECVD process

Conventionally directionally solidified (DS) and silicon film (SF) polycrystalline silicon solar cells are fabricated using gettering and low temperature plasma enhanced chemical vapor deposition (PECVD) passivation. Thin layer (~10 nm) of PECVD SiO₂ is used to passivate the emitter of the solar cell, while direct hydrogen rf plasma and PECVD silicon nitride (Si₃N₄) are implemented to provide emitter and bulk passivation. It is found in this work that hydrogen rf plasma can significantly improve the solar cell blue and long wavelength responses when it is performed through a thin layer of PECVD Si₃N₄. High efficiency DS and SF polycrystalline silicon solar cells have been achieved using a simple solar cell process with uniform emitter, Al/POCl₃ gettering, hydrogen rf plasma/PECVD Si₃N₄ and PECVD SiO₂ passivation. On the other hand, a comprehensive experimental study of the characteristics of the PECVD Si₃N₄ layer and its role in improving the efficiency of polycrystalline silicon solar cells is carried out in this paper. For the polycrystalline silicon used in this investigation, it is found that the PECVD Si₃N₄ layer doesn't provide a sufficient cap for the out diffusion of hydrogen at temperatures higher than 500°C. Low temperature (⩽400°C) annealing of the PECVD Si₃N ₄ provides efficient hydrogen bulk passivation, while higher temperature annealing relaxes the deposition induced stress and improves mainly the short wavelength (blue) response of the solar cells     

Optimization of low temperature silicon nitride processes for improvement of device performance

This paper gives some insights in the applications where PECVD nitrides can be introduced to replace the LPCVD layers and how the process parameters need to be varied to obtain the desired properties. Film properties like stress, hydrogen content, wet etch rate and deposition rate are reported. The nitrides are optimized for specific applications and examples on the influence of nitride properties on device performance are given. It is important to investigate that the advantage of the high film integrity of nitride layers used in the past is not lost due to the strong demand for developing new process schemes with low thermal budget layers. We show that PECVD films are a valid alternative for LPCVD and that the majority of the film properties satisfy the criteria to use PECVD films as contact-etch-stop layers, silicidation blocking films and spacer materials.     

Modeling the growth of PECVD silicon nitride films for solar cellapplications using neural networks

Silicon nitride films grown by plasma-enhanced chemical vapor deposition (PECVD) are useful for a variety of applications, including anti-reflection coatings in solar cells, passivation layers, dielectric layers in metal/insulator structures, and diffusion masks, PECVD nitride films are known to contain hydrogen, and defect passivation by hydrogenation enhances efficiency in polycrystalline silicon solar cells. PECVD systems are controlled by many operating variables, including RF power, pressure, gas flow rate, reactant composition, and substrate temperature. The wide variety of processing conditions, as well as the complex nature of particle dynamics within a plasma, makes tailoring Si₃N₄ film properties very challenging, since it is difficult to determine the exact relationship between desired film properties and controllable deposition conditions. In this study, silicon nitride PECVD modeling using neural networks has been investigated. The deposition of Si₃N₄ was characterized via a central composite experimental design, and data from this experiment was used to train optimized feed-forward neural networks using the back-propagation algorithm. From these neural process models, the effect of deposition conditions on film properties has been studied. It was found that the process parameters critical to increasing hydrogenation and therefore enhancing carrier lifetime in polysilicon solar cells are temperature, silane, and ammonia flow rate. The deposition experiments were carried out in a Plasma Therm 700 series PECVD system     

Nonvolatile memory with a metal nanocrystal/nitride heterogeneous floating-gate

Heterogeneous floating-gates consisting of metal nanocrystals and silicon nitride (Si/sub 3/N/sub 4/) for nonvolatile memory applications have been fabricated and characterized. By combining the self-assembled Au nanocrystals and plasma-enhanced chemical vapor deposition (PECVD) nitride layer, the heterogeneous-stack devices can achieve enhanced retention, endurance, and low-voltage program/erase characteristics over single-layer nanocrystals or nitride floating-gate memories. The metal nanocrystals at the lower stack enable the direct tunneling mechanism during program/erase to achieve low-voltage operation and good endurance, while the nitride layer at the upper stack works as an additional charge trap layer to enlarge the memory window and significantly improve the retention time. The write/erase time of the heterogeneous stack is almost the same as that of the single-layer metal nanocrystals. In addition, we could further enhance the memory window by stacking more nanocrystal/nitride heterogeneous layers, as long as the effective oxide thickness from the control gate is still within reasonable ranges to control the short channel effects.     

Bulk and surface passivation of silicon solar cells accomplished by silicon nitride deposited on industrial scale by microwave PECVD

Bulk and surface passivation by silicon nitride has become an indispensable element in industrial production of multicrystalline silicon (mc‐Si) solar cells. Microwave PECVD is a very effective method for high‐throughput deposition of silicon nitride layers with the required properties for bulk and surface passivation. In this paper an analysis is presented of the relation between deposition parameters of microwave PECVD and material properties of silicon nitride. By tuning the process conditions (substrate temperature, gas flows, working pressure) we have been able to fabricate silicon nitride layers which fulfill almost ideally the four major requirements for mc‐Si solar cells: (1) good anti‐reflection coating (refractive index tunable between 2·0 and 2·3); (2) good surface passivation on p‐type FZ wafers (S_eff<30 cm/s); (3) good bulk passivation (improvement of IQE at 1000 nm by 30% after short thermal anneal); (4) long‐term stability (no observable degradation after several years of exposure to sunlight). By implementing this silicon nitride deposition in an inline production process of mc‐Si solar cells we have been able to produce cells with an efficiency of 16·5%. Finally, we established that the continuous deposition process could be maintained for at least 20 h without interruption for maintenance. On this timescale we did not observe any significant changes in layer properties or cell properties. This shows the robustness of microwave PECVD for industrial production. Copyright © 2005 John Wiley & Sons, Ltd.