共查询到20条相似文献,搜索用时 93 毫秒
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Sn-9Zn合金无铅钎料用助焊剂研究 总被引:10,自引:1,他引:9
通过测量润湿面积和润湿角,研究不同助焊剂对Sn-9Zn焊料润湿性的影响。结果表明:助焊剂对Sn-9Zn焊料润湿性影响很大,由乳酸、聚乙二醇和SnCl2所构成的助焊剂与Sn-9Zn焊料有很好适应性;同时扫描电镜和能谱分析也表明焊料与Cu基体界面的IMC为Cu5Zn8相,比Sn-37Pb焊料具有更高的剪切强度。 相似文献
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Sn-Zn-Bi-In-P新型无铅焊料性能研究 总被引:1,自引:1,他引:0
新型无铅焊料Sn-4.5Zn-2Bi-In-P、Sn-9Zn-2.5Bi-In-P具有优异的抗氧化、抗腐蚀性能,弥补了Sn-Zn系焊料润湿性能方面的不足,具有极大的实用性。测量了共晶Sn-9Zn、两种新型Sn-Zn系无铅焊料和传统的Sn-37Pb焊料的各项物理性能:密度、熔点、线膨胀系数、电阻率及对铜基体的润湿角。实验结果表明,新型Sn-Zn系无铅焊料的密度约为传统Sn-37Pb焊料的3/4;熔点(依次为194℃,191.9℃)接近Sn-37Pb焊料,熔程仅为8℃;在25~100℃,新型Sn-Zn焊料线膨胀系数依次为20.8×10–6/℃、16.9×10–6/℃,优于Sn-37Pb焊料(21.2×10–6/℃);新型Sn-Zn焊料的电阻率依次为1.73×10–6Ω·m、1.79×10–6Ω·m,优于Sn-37Pb焊料(1.96×10–6Ω·m);新型Sn-Zn焊料对Cu基体的润湿角接近30°,满足实用化的最低要求。 相似文献
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Effects of Trace Amounts of Rare Earth Additions on Microstructure and Properties of Sn-Bi-Based Solder Alloy 总被引:3,自引:0,他引:3
Wenxing Dong Yaowu Shi Zhidong Xia Yongping Lei Fu Guo 《Journal of Electronic Materials》2008,37(7):982-991
The effect of trace amounts of rare earth additions on the microstructure and properties were studied for the Sn-58Bi and
Sn-58Bi-Ag solder alloys. At the same time, the intermetallic compounds (IMCs) in the solder alloys and intermetallic layer
(IML) thickness at the solder/Cu substrate interface were investigated, both as-reflowed and after high-temperature aging.
The results indicate that adding trace amounts of rare earth (RE) elements has little influence on the melting temperature
and microhardness of the solders investigated, but adding RE elements improves the wettability and shear strength of the Sn-58Bi
and Sn-58Bi-Ag solder alloys. In addition, it was found that the addition of RE elements not only refines the microstructure
and size of the IMC particles, but also decreases the IML thickness and shear strength of the Sn-58Bi solder joint after high-temperature
aging. Adding trace amounts of RE elements is superior to adding trace amounts of Ag for improving the properties of the Sn-58Bi
solder. The reason may be related to the modification of the microstructure of the solder alloys due to the addition of trace
amounts of RE elements. 相似文献
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稀土改性的Sn-58Bi低温无铅钎料 总被引:1,自引:0,他引:1
研究了微量稀土对Sn-58Bi低温钎料的改性作用.试验添加质量分数为0.1 ?组混合稀土的无铅材料,并对比Sn-58Bi和Sn-58Bi0.5Ag合金.观察了钎料显微组织的变化并做了定量分析,采用DSC测试了钎料的熔化温度,同时测量了钎料的润湿性能、接头强度与硬度.结果表明,微量稀土添加细化了Sn-58Bi钎料合金的显微组织,对钎料的熔化温度几乎没有影响,能显著改善Sn-58Bi钎料的润湿性能和接头剪切强度,而且改善的程度优于添加微量Ag对Sn-58Bi钎料的作用. 相似文献
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In the current research, trace rare earth (RE) element Y was incorporated into a promising lead-free solder, Sn3.8Ag0.7Cu,
in an effort to improve the comprehensive properties of Sn3.8Ag0.7Cu solder. The range of Y content in Sn3.8Ag0.7Cu solder
alloys varied from 0 wt.% to 1.0 wt.%. As an illustration of the advantage of Y doping, the melting temperature, wettability,
mechanical properties, and microstructures of Sn3.8Ag0.7CuY solder were studied. Trace Y additions had little influence on
the melting behavior, but the solder showed better wettability and mechanical properties, as well as finer microstructures,
than found in Y-free Sn3.8Ag0.7Cu solder. The Sn3.8Ag0.7Cu0.15Y solder alloy exhibited the best comprehensive properties compared
to other solders with different Y content. Furthermore, interfacial and microstructural studies were conducted on Sn3.8Ag0.7Cu0.15Y
solder alloys, and notable changes in microstructure were found compared to the Y-free alloy. The thickness of an intermetallic
compound layer (IML) was decreased during soldering, and the growth of the IML was suppressed during aging. At the same time,
the growth of intermetallic compounds (IMCs) inside the solder was reduced. In particular, some bigger IMC plates were replaced
by fine, granular IMCs. 相似文献
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M. J. Rizvi Y. C. Chan C. Bailey H. Lu M. N. Islam B. Y. Wu 《Journal of Electronic Materials》2005,34(8):1115-1122
The wettability of newly developed Sn-2.8Ag-0.5Cu-1.0Bi lead-free solder on Cu and Ni substrates was assessed through the
wetting balance tests. The wettability assessment parameters such as contact angle (ϑc) and maximum wetting force (Fw) were documented for three solder bath temperatures with three commercial fluxes, namely, no-clean (NC), nonactivated (R),
and water-soluble organic acid flux (WS). It was found that the lead-free Sn-2.8Ag-0.5Cu-1.0Bi solder exhibited less wetting
force, i.e., poorer wettability, than the conventional Sn-37Pb solder for all flux types and solder bath temperatures. The
wettability of Sn-2.8Ag-0.5Cu-1.0Bi lead-free solder on Cu substrate was much higher than that on Ni substrate. Nonwetting
for Sn-2.8Ag-0.5Cu-1.0Bi and Sn-Pb solders on Ni substrate occurred when R-type flux was used. A model was built and simulations
were performed for the wetting balance test. The simulation results were found very close to the experimental results. It
was also observed that larger values of immersion depth resulted in a decrease of the wetting force and corresponding meniscus
height, whereas the increase in substrate perimeter enhanced the wettability. The wetting reactions between the solder and
Cu/Ni substrates were also investigated, and it was found that Cu atoms diffused into the solder through the intermetallic
compounds (IMCs) much faster than did the Ni atoms. Rapid formation of IMCs inhibited the wettability of Sn-2.8Ag-0.5Cu-1.0Bi
solder compared to the Sn-Pb solder. 相似文献
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In the present work, lead-free solder balls were manufactured by a uniform droplet spray (UDS) method. The solder used to
produce solder balls was based on the Sn-3.8Ag-0.7Cu alloy. Different amounts of cerium-based mixed rare-earth (RE) elements
were added into the Sn-3.8Ag-0.7Cu solder alloy in order to examine the effects of small amounts of RE additions on the physical
properties, microstructure, and surface smoothness of the solder balls. Results show that a small amount of RE addition has
no obvious effect on the melting temperature, but it decreases the nucleation undercooling degree. Moreover, a small amount
of RE addition (<0.25 wt.%) can improve the surface smoothness of the solder balls. However, when the RE was added up to 0.5 wt.%,
the surface smoothness of the solder balls was deteriorated. From observations of the microstructure of the solder balls,
it is obvious that the RE addition affects solidification behavior, and as a result, the surface smoothness of the solder
balls. 相似文献
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The effects of sulfur on the wettability of Sn-0.7Cu on Cu and on the corrosion behavior of Sn-0.7Cu in 3.5 wt% NaCl solution were investigated. The results reveal that sulfur considerably improves the wettability of Sn-0.7Cu and the optimal sulfur content is 0.08 wt%. SnS and SnSO4 phases form on the surface of the sulfur containing Sn-0.7Cu solder alloy after soldering characterized by XPS and XRD analysis. The addition of sulfur decreases the dross formation of the solder melt and the formation of SnO2 is inhibited. The potentiodynamic polarization tests show that the corrosion resistance of Sn-0.7Cu solder alloy is obviously enhanced by sulfur element. Analyses by SEM and XRD indicate that sulfur promotes the formation of the corrosion product, Sn3O(OH)2Cl2, on the surface of sulfur containing Sn-0.7Cu solder and it keeps the solder alloy from further corrosion. 相似文献
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Wei Min Xiao Yao Wu Shi Yong Ping Lei Zhi Dong Xia Fu Guo 《Journal of Electronic Materials》2008,37(11):1751-1755
The effects of rare-earth (RE) element additions on the tensile deformation mechanism of the Sn-3.8Ag-0.7Cu solder alloy have
been investigated. The results show that adding RE elements can remarkably improve the tensile strength and elongation of
the Sn-3.8Ag-0.7Cu alloy. The increase in the mechanical properties are attributed to the constraints of microcrack growth
and grain boundary sliding in the eutectic phase as well as the relaxation of stress concentration in the β-Sn phase due to
the addition of the RE elements. It is considered that the RE elements strengthen the eutectic phase and increase the deformation
resistance of this alloy. 相似文献
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The comparison study of Sn-10Bi and Sn-3.0Ag-0.5Cu solder alloys and joints was conducted. The results showed that the liquidus of Sn-10Bi solder alloy was lower than that of Sn-Ag-Cu slightly. The interfacial IMCs layer growth of Sn-10Bi/Cu was slower than that of Sn-Ag-Cu/Cu during liquid/solid reaction. The higher strength and lower creep strain rate of Sn-10Bi comparing with that of Sn-Ag-Cu were contributed by the solid solution strengthening effect of Bi atom in β-Sn phase. The ultimate bending load of Sn-10Bi joint was higher than that of Sn-Ag-Cu joint as the high strength of Sn-10Bi solder alloy. Moreover, the thinner and more flat IMCs layer also ensured the stable maximum bending displacement of Sn-10Bi joint at a loading speed of 1 mm/s compared with that of Sn-Ag-Cu joint. 相似文献
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Microstructure, solderability, and growth of intermetallic compounds of Sn-Ag-Cu-RE lead-free solder alloys 总被引:4,自引:0,他引:4
C. M. T. Law C. M. L. Wu D. Q. Yu L. Wang J. K. L. Lai 《Journal of Electronic Materials》2006,35(1):89-93
The near-eutectic Sn-3.5 wt.% Ag-0.7 wt.% Cu (Sn-3.5Ag-0.7Cu) alloy was doped with rare earth (RE) elements of primarily Ce
and La of 0.05–0.25 wt.% to form Sn-3.5Ag-0.7Cu-xRE solder alloys. The aim of this research was to investigate the effect
of the addition of RE elements on the microstructure and solderability of this alloy. Sn-3.5Ag-0.7Cu-xRE solders were soldered
on copper coupons. The thickness of the intermetallic layer (IML) formed between the solder and Cu substrate just after soldering,
as well as after thermal aging at 170°C up to 1000 h, was investigated. It was found that, due to the addition of the RE elements,
the size of the Sn grains was reduced. In particular, the addition of 0.1wt.%RE to the Sn-3.5Ag-0.7Cu solder improved the
wetting behavior. Besides, the IML growth during thermal aging was inhibited. 相似文献