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采用射频反应磁控溅射方法制备了氧化锡/多壁碳纳米管(SnO2/MWCNTs)薄膜材料,并在此基础上研制NO2气敏传感器。采用X射线衍射仪(XRD)、X光电子能谱仪(XPS)、扫描电子显微镜(SEM)来研究WO3/MWCNTs材料的表面形貌、表面化学状态、表面化学元素等材料特性,研究结果表明MWCNTs已经掺杂进SnO2材料,合成的SnO2/MWCNTs气敏传感器表现出对低浓度(甚至低于10ppb)的NO2气体有较高的灵敏度和较好的反应-恢复特性,并解释了该传感器的工作机理是基于pn结(P型MWCNTs和N型SnO2)作用的结果。 相似文献
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聚噻吩/WO_3复合纳米材料的制备及气敏性能 总被引:1,自引:1,他引:0
采用水合肼法制备WO3粉体,再以无水FeCl3作氧化剂,通过原位化学氧化聚合制备了不同聚噻吩(PTh)掺杂量的PTh/WO3复合纳米材料。并研究了用其制备的气敏元件的气敏性能。结果表明:气敏元件对H2S和NOx有较高的灵敏度和较好的选择性。用质量分数w(PTh)为5%的PTh/WO3复合纳米材料制备的气敏元件,在加热电压为2.25V时,对体积分数φ(NOx)为5×10–6的灵敏度可达77.14;用w(PTh)为20%的PTh/WO3复合纳米材料所制之气敏元件,在加热电压为2.43V时,对φ(H2S)为20×10–6的灵敏度达63.27。 相似文献
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WO3的气敏特性研究 总被引:7,自引:2,他引:5
通过实验,结合气敏元件分析方法,对WO3气敏元件的气敏特性、响应与恢复时间、电阻特性、初期驰豫特性进行了系统分析。为进一步开发研制WO3气敏元件提供了可靠的数据。 相似文献
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WO3/Ag composite film photoanodes were synthesized by hydrothermal combined electrodeposition method. Characterization of samples was conducted by scanning electron microscope (SEM) and X-ray diffraction (XRD), which showed that WO3/Ag composite films had been synthesized. Diffuse reflectance spectra show WO3/Ag composite film has more strong absorption than WO3 film under simulated visible light irradiation. Electrochemical impedance spectroscopy shows WO3/Ag composite film photoanode enhances charge transfer efficiency compared with WO3 film. WO3/Ag composite film photoanodes show higher photocurrent and photoelectric catalytic activity than WO3 film, and the WO3/Ag composite film obtained by depositing Ag nanoparticles at 50 s (WO3/Ag-50) shows the highest photocurrent and photoelectric photoelectric catalytic activity. Meanwhile, the photoelectric catalytic activity of the composite film is higher than their direct photocatalytic and electric catalytic activity. The higher photocurrent and photoelectric catalytic activity of the WO3/Ag composite film photoanodes are attributed to the surface plasmon resonance effect of Ag nanoparticles and Schottky junction effect at the WO3/Ag interface. 相似文献
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WO3/Au composite film electrode was prepared by hydrothermal combined electrodeposition method. The samples were characterized by scanning electron microscope (SEM), energy dispersive spectrometer (EDS) and X-ray diffraction (XRD), and the results showed that WO3/Au composite film was synthesized. Electrochemical and spectral measurements were carried out to obtain the electrochromic response time, reversibility, coloration efficiency (CE) and transmittance of the WO3/Au composite film. The photoelectrochemical properties of the samples were characterized by measuring photocurrent and photocatalytic degradation efficiency. The results show that compared with pure WO3 nanoblocks, WO3/Au composite film improves the electrochromic property, photocurrent and photoelectric catalysis activity. Among them, WO3/Au composite film prepared by depositing Au nanoparticles in 80 s showed the highest electrochromic property, photocurrent and photoelectric catalysis activity. Meanwhile, compared with direct photocatalysis (DP) and electrocatalysis (EC), the photoelectrocatalysis (PEC) activity of the composite film is the highest. 相似文献
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研究了采用薄层WO3作为叠层有机发光器件电荷产生层时的性能并对其厚度进行了优化,器件的电荷产生层由Li掺杂的电子注入层和高透明的WO3组成.研究表明,薄层WO3具有很高的透明度,并能有效地产生和注入空穴.叠层器件性能与单发光单元器件相比较,其亮度及效率均有大幅提高,叠层器件的最大电流效率达到了4.2 cd/A,在相同的电流密度下,叠层器件的效率约为传统器件的2倍;同时,电荷产生层的性能与WO3薄膜厚度密切相关,WO3薄膜厚度为3 nm时,器件的效率在整个电流范围内都保持稳定.采用薄层WO3作为电荷产生层为制备高效叠层有机发光器件提供了一条有效的途径. 相似文献
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采用射频磁控溅射技术,以WO3陶瓷靶为原料,在透明导电氧化铟锡(ITO)玻璃上沉积了非晶相WO3薄膜,研究了溅射功率对薄膜结构及光学性质的影响,并研究了WO3薄膜的电致变色特性。利用扫描电子显微镜(SEM)、X射线衍射技术(XRD)表征了薄膜的表面形貌和内部结构;利用UV-Vis分光光度计表征了薄膜在变色前后的光学透过性质,利用电化学测试工作站研究了WO3薄膜的电致变色性质,并从原理上分析了WO3薄膜的变色机理。研究结果表明,不同功率下获得的WO3薄膜均为非晶结构,在可见光范围内有较高的透过率。透明的WO3薄膜在负向电压下逐渐转变成深蓝色,且在撤去电压后其颜色不变,当施加正向电压时,薄膜又转换为透明态,表现出良好的电致变色特性。所制备WO3薄膜在550nm处褪色态的透过率为83%,着色态的透过率为29%,使得该薄膜在智能窗方面具有广阔的应用前景。 相似文献
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Because of its high activity and selectivity toward the reduction of hydrogen peroxide and oxygen, Prussian blue (PB) is usually considered as an “artificial enzyme peroxidase” and has been extensively used in the construction of electrochemical biosensors. In this study, we report on the construction of amperometric biosensors via grafting PB nanoparticles on the polymeric matrix of multiwalled carbon nanotubes (MWCNTs) and poly(4‐vinylpyridine) (PVP). The MWCNT/PVP/PB composite films were synthesized by casting films of MWCNTs wrapped with PVP on gold electrodes followed by electrochemical deposition of PB on the MWCNT/PVP matrix. The electrode modified with the MWCNT/PVP/PB composite film shows prominent electrocatalytic activity toward the reduction of hydrogen peroxide, which can be explained by the remarkable synergistic effect of the MWCNTs and PB. Therefore, fast amperometric response of this sensor to hydrogen peroxide was observed with a detection sensitivity of 1.3 μA μM –1 of H2O2 per square centimeter area and a detection limit of 25 nM . These results are much better than those reported for PB‐based amperometric sensors. In addition, a glucose biosensor fabricated by casting an additional glucose oxidase (GOD) containing Nafion film above the MWCNT/PVP/PB composite film shows promise for the sensitive and fast detection of glucose. The observed high stability, high sensitivity, and high reproducibility of the MWCNT/PVP/PB composite films make them promising for the reliable and durable detection of hydrogen peroxide and glucose. 相似文献