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研究了反式-1,4-聚异戊二烯(TPI)硫化胶及其与BR,SBR,NR共混硫化胶的性能。结果表明,通过控制硫黄用量即交联密度,可使TPI硫化胶具有优异的力学和动态力学性能;TPI与BR,SBR,NR共混,工艺性能良好,当TPI/BR,TPI/SBR和TPI/NR共混比小于50/50时,共混硫化胶的力学和动态力学性能优于BR,SBR和NR硫化胶,特别是拉伸疲劳寿命大大延长,这正是高性能轮胎所需要的 相似文献
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研究了稀土顺丁橡胶(Ln-BR)与天然橡胶(NR)以不同比例共混后生胶、混炼胶和硫化胶的性能,并与相同条件下的镍系顺丁橡胶(Ni-BR)/NR共混胶的性能进行了对比,结果表明,共混胶随Ln-BR用量的增大,ML^100℃1+4降低,工艺行为良好,硫化胶力学性能、磨耗、湿滑指数和生热值下降,并且Ln-BR/NR硫化胶的抗湿滑性和动态疲劳性均优于Ni-BR/NR硫化胶。 相似文献
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研究了共混比及硫化体系对氯化丁基橡胶(CIIR)/天然橡胶(NR)共混物性能的影响,探讨了老化温度及防老剂对氧化锌/促进剂TMTD/促进剂DM硫化体系硫化的CIIR/NR共捐物耐热氧老化性能的影响。试验结果表明,氧化锌/促进剂TMTD/促进剂DM(5.0/1.5/1.0)硫化体系硫化的CIIR/NR共混物的拉伸强度和扯断伸长率与按共混比计算的平均值差别较小,尤其是拉伸强度与计算值完全一致。当共混物中CIIR用量超过50份时,共混物的耐热氧老化性能明显改善。不同防老剂对CIIR/NR(50/50)共混物热氧老化的防护效能大小顺序为RD及4010>4010NA>MB>D。防老剂RD先加入到NR中后再与CIIR共混.其防护效能更佳。 相似文献
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稀土BR/SBR共混胶的性能 总被引:1,自引:0,他引:1
研究了4种共混比的LnBR/SBR共混生胶、混炼胶及硫化胶的性能,并与NiBR/SBR共混胶进行了对比。结果表明,共混生胶的ML均低于LnBR及SBR;当LnBR/SBR共混混炼胶的ML、剪切应力、出口膨胀及硫化速度均低于NiBR/SBR共混胶,挤出物外观优于后者;共混硫化胶的拉伸强度、热空气老化、拉伸疲劳、湿滑、耐磨等性能均明显优于后者,生热和透气率高于后者。 相似文献
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PVC/ENR/XNBR(NBR)动态硫化共混物 总被引:1,自引:0,他引:1
能干不氧化天然橡胶(ENR)、聚氯乙烯(PVC)和羧基丁腈橡胶(XNBR)之间的自硫化反应,实现了PVC/ENR/XNBR三元共混物的动态友化,由此得到了具有热塑性弹性体的一些典型特征的PVC/ENR/XNBR动态自硫化共混物。该人混物与自硫化反应不明显的PVC/ENR/NBR共混物进行了比较,发现动态自硫化反应显著提高了共混物的综合性能。结果表明,当橡塑比为70/30时,前者的拉伸强度为11.8 相似文献
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PVC/SBR热塑性弹性体的研制 总被引:1,自引:0,他引:1
以ABS、氯丁橡胶(CR)、马来酸酐(MA)接枝SBR(SBR-MA)作增容剂对PVC/SBR的共混比、增容剂、增塑剂用量做了优化选择。同时对动态硫化PVC/SBR的硫化体系、硫化工艺条件进行了探讨,并比较了动态硫化对共混体性能的影响。结果表明:PVC/SBR为80/20,增容剂ABS/SBR-MA为5/5时,选用半有效硫化体系,165℃下动态硫化6min,共混物综合性能最佳 相似文献
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研究了橡胶型乙烯醋酸乙烯酯共聚物(EVM)/NBR共混比、硫黄和叔丁基酚醛树脂(2402树脂)硫化体系对共混物性能的影响,并对比了动态硫化和静态硫化共混物在性能上的差异。试验结果表明,EVM/NBR共混比显著影响共混物的力学性能,而采用NBR预先动态硫化的方法后,共混物胶料的挤出口型膨胀率明显减小,老化性能得到改善,同时减弱了硫黄和2402树脂等硫化体系对EVM硫化的影响,使多种硫化体系可以共存于共混物中。DSC分析表明EVM/NBR动态硫化共混物只有一个玻璃化温度,且介于EVM和NBR之间,说明EVM和NBR具有良好的相容性。 相似文献
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研究了铁系乙烯基丁二烯橡胶(FVBR)与天然橡胶(NR)以50/50(质量比)共混硫化胶的物理机械性能和黏弹特性,并与溶聚丁苯橡胶(SSBR)与NR共混胶进行了对比。结果表明,FVBR与NR有良好的相容性,共混胶只存在1个玻璃化转变温度。FVBR/NR的混炼行为良好,但必需添加操作油,否则难以获得理想的硫化胶性能。FVBR/NR与SSBR/NR相似,不仅具有良好的拉伸和撕裂性能,而且具有高抗湿滑性;其生热和滚动阻力以及热老化性能优于后者,但耐磨性略逊于SSBR/NR。 相似文献
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针对以溶聚丁苯橡胶(SSBR)/顺丁橡胶(BR)并用胶为主体材料的绿色轮胎胎面胶,研究在不同硫化时间下未填充白炭黑的SSBR/BR并用胶(简称未填充白炭黑体系胶料)及填充白炭黑的SSBR/BR并用胶(简称填充白炭黑体系胶料)形成的交联网络结构与性能变化。结果表明:对于未填充白炭黑体系胶料,随着硫化时间的延长,硫化胶的交联密度略有降低,硬度、定伸应力、拉伸强度和回弹值等变化不大,撕裂强度提高,拉断伸长率和耐伸张疲劳性能降低;对于填充白炭黑体系胶料,随着硫化时间的延长,硫化胶的填料网络结构化程度逐渐提高,交联密度略有增大,键能较低的多硫键减少,键能较高的单硫和双硫键增多,硫化胶的拉伸强度、回弹值、耐伸张疲劳性能和耐磨性能基本不变,生热和滚动阻力降低;未填充及填充白炭黑体系硫化胶的耐老化性能均随硫化时间的延长而逐渐提高,这表明以SSBR/BR并用胶为主体材料的胎面胶即使在高温下硫化较长时间,仍具有较好的性能。 相似文献
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炭黑在天然橡胶/溶聚丁苯橡胶硫化胶中的分散及其对性能的影响 总被引:1,自引:0,他引:1
考察了溶聚丁苯橡胶(SSBR)用量、炭黑的种类及用量对天然橡胶(NR)/SSBR硫化胶动态力学性能和力学性能的影响.结果表明,炭黑与SSBR的结合作用比与NR弱;随SSBR用量的增加,炭黑在NR/SSBR共混硫化胶中的分散性提高,Payne效应减弱,频率敏感性增强;随SSBR用量的增加,NR/SSBR共混硫化胶的拉伸强度和撕裂强度减小,扯断伸长率变化不大;而定伸应力则呈先减小后增大的趋势;随不同种类的炭黑在NR/SSBR硫化胶中分散性的提高,定伸应力呈上升趋势,损耗因子和压缩生热呈减小趋势. 相似文献
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采用以天然橡胶(NR)、NR/顺丁橡胶(BR)和NR/BR/溶聚丁苯橡胶(SSBR)为基体的轮胎胎面胶配方,研究低滞后炭黑DZ13对3种硫化胶物理性能和疲劳破坏行为的影响。结果表明:低滞后炭黑DZ13部分替代炭黑N234后,NR,NR/BR和NR/BR/SSBR硫化胶的物理性能变化规律相似,即定伸应力略有增大、拉断伸长率和撕裂强度减小;耐磨性能、耐压缩疲劳性能和耐割口增长性能的变化依赖于基体橡胶;其中NR/BR硫化胶的屈挠疲劳次数提高,但疲劳破坏界面的微观形貌更加粗糙。 相似文献
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This article explored the possibility of using silica from fly‐ash particles as reinforcement in natural rubber/styrene–butadiene rubber (NR/SBR) vulcanizates. For a given silica content, the NR : SBR blend ratio of 1 : 1 (or 50 : 50 phr) exhibited the optimum mechanical properties for fly‐ash filled NR/SBR blend system. When using untreated silica from fly‐ash, the cure time and mechanical properties of the NR/SBR vulcanizates decreased with increasing silica content. The improvement of the mechanical properties was achieved by addition of Si69, the recommended dosage being 2.0 wt % of silica content. The optimum tensile strength of the silica filled NR/SBR vulcanizates was peaked at 10–20 phr silica contents. Most mechanical properties increased with thermal ageing. The addition of silica from fly‐ash in the NR/SBR vulcanizates was found to improve the elastic behavior, including compression set and resilience, as compared with that of commercial precipitated silica. Taking mechanical properties into account, the recommended dosage for the silica (FASi) content was 20 phr. For more effective reinforcement, the silica from fly‐ash particles had to be chemically treated with 2.0 wt % Si69. It was convincing that silica from fly‐ash particles could be used to replace commercial silica as reinforcement in NR/SBR vulcanizates for cost‐saving and environment benefits. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007 相似文献
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N. Hinchiranan W. Lertweerasirikun W. Poonsawad G. L. Rempel P. Prasassarakich 《应用聚合物科学杂志》2009,113(3):1566-1575
Hydrogenated natural rubber (HNR) prepared from natural rubber (NR) is a new sustainable elastomer with excellent thermal properties. This study reports on the effect of vulcanization system and blend ratio on the thermal and oxidative resistance of HNR/NR vulcanizates. The various HNR/NR ratios vulcanized by peroxide and sulfur donor system exhibited the highest retention of tensile strength after thermal aging due to the formation of zinc‐dimethyldithiocarbamate (ZDMDC) which is an efficient antioxidant. The results from thermogravimetric analysis (TGA) indicated that the saturated structure of HNR had higher decomposition temperature and activation energy to enhance the thermal stability of HNR/NR vulcanizates. The initial and maximum decomposition temperatures of NR and HNR phases in vulcanizates were not affected by rubber blend ratio. This suggests that the decomposition pattern of HNR has no influence on another constituent. The increase in HNR content in the blends could retard the ozonolysis resulting in the surface cracking attacked by ozone. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献
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Kannika Sahakaro Rabin N. Datta Johan Baaij Jacques W. M. Noordermeer 《应用聚合物科学杂志》2007,103(4):2555-2563
The NR/BR blend compound formulations for tire sidewall applications contain a set of stabilizers added to prevent degradation mainly due to oxygen, ozone, and heat. 6PPD is the most effective and widely used antiozonant in tire compounds, but is a highly staining material causing a surface discoloration of the tire sidewall. Incorporation of 30 phr EPDM into blends of NR/BR improves the ozone resistance to the required level, without the need of 6PPD. The first two parts of this series have described a reactive processing technique applied to enhance the covulcanization and blend homogeneity, together with their characterization. In the present article, the properties of the NR/BR/EPDM blends prepared by both reactive and straight mixing are tested in comparison with those of equivalent conventional NR/BR compounds. The reactive NR/BR/EPDM blend vulcanizates show excellent tensile strength, elongation at break, tear strength, fatigue‐to‐failure, and ozone resistance in both static and dynamic conditions. The properties are equivalent or even superior to those of the conventional NR/BR tire sidewall compounds. The simple straight mixed NR/BR/EPDM blend vulcanizates distinctively possess inferior mechanical properties compared to those of the reactive mix. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 2555–2563, 2007 相似文献
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Mechanochemically devulcanized ground rubber tire (GRT) was (re)vulcanized in compositions with virgin natural rubber (NR). The NR/GRT (re)vulcanizates with GRT content from 20 to 60 wt% have been prepared and studied. Reclaiming of GRT was successfully carried out by tetra methyl thiuram disulfide (TMTD) in presence of spindle oil at around ambient temperature. The cure characteristics and mechanical properties of the virgin NR/reclaim GRT blend were studied. The optimum cure time decreases but scorch time remain unaltered with increasing reclaim rubber content in the blend. Effect of carbon black was studied in NR/RR (80/20) blend. Ageing characteristics of different NR/RR blends were evaluated. Scanning electron microscopy (SEM) studies further indicate the coherency and homogeneity in the NR/RR vulcanizate. The dynamic mechanical properties and swelling behavior of NR/RR blend vulcanizates were examined. The elastic and storage modulus of the NR/RR vulcanizates become improve with increasing reclaim rubber content. Electrical properties of NR/RR vulcanizates were also studied. POLYM. ENG. SCI., 47:1091–1100, 2007. © 2007 Society of Plastics Engineers 相似文献
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研究了不同用量的沉淀法白炭黑填充质量比75/25的氯丁橡胶/天然橡胶共混物的物理机械性能、耐热老化性能和耐油性能,并用扫描电镜研究了共混物的结构。结果显示,白炭黑的加入改善了共混硫化物的拉伸强度、100%定伸应力和邵尔A硬度。压缩永久变形减小,黏度增大,从而导致在形变的过程中天然橡胶分散相占有率相对减少。相关性能也证明随着白炭黑用量的增加,硫化胶的耐热和耐油性能显著提高。 相似文献