Thermokinetics of Liquid-Liquid Reaction of Dy（NO3 ）3 with Histidine

The thermokinetics of liquid-liquid reaction of dysprosium nitrate with histidine were studied using a microcalorimeter. On the basis of experimental and calculated results, threethermodynamic parameters (the activation enthalpy, the activation entropy and the activation free enegy),the rate constant, three kinetic parameters (the activation energy, the pre-exponential constant and the reaction order) wereobtained. On the basis of thermodynamics and kinetics, the for marion reaction of the complex was discussed.     

英力士淤浆工艺聚乙烯装置低压系统凝胶原因分析及对策

在英力士淤浆环管工艺生产钛系双峰聚乙烯产品期间,低压溶剂回收系统产生黄色凝胶物质,极难清理且影响装置的长周期生产。通过与国内同类装置工艺运行条件比对、样品元素分析,改变了生产期间催化剂配置流程,调整了低压溶剂回收温度,进而消除了凝胶产生。     

小型风光互补高频逆变器的设计方法

在世界环境污染日趋严重的情况下,清洁能源作为一种无污染的能源已经引起人们的注意.设计了一种风光互补逆变器,从它的特性和原理入手,用Matlab/Simulink作了仿真.该设计具有原理简单以及成本少的优点.     

工业平缝机挑线机构的优化综合

本文采用最优化方法，对工业缝纫机的连杆挑线机构进行了优化综合。分析结果表明，新机构的大多数参数均有所改善，结构更趋紧凑，振动得以减缓，实用性能明显改善。     

RE（NO3）3与Glu间配合行为的相平衡研究

测定了ＲＥ（ＮＯ３）３－Ｇｌｕ－Ｈ２Ｏ（ＲＥ＝Ｌａ、Ｇｄ、Ｅｒ）三元体系在２５℃时的溶解度和饱和溶液的折光率，绘制了相应的溶解度图与他和溶液的折光率曲线。各体系的溶解度曲线与折光率曲线均由两支组成，分别与ＲＥ（ＮＯ３）３·ｎＨ２Ｏ（ＲＥ＝Ｌａ、Ｇｏｌ、ｎ＝６；ＲＥ＝Ｅｒ，ｎ＝５）和Ｇｌｕ相对应。实验结果表明，在这些体系中不存在ＲＥ（ＮＯ３）３与Ｇｌｕ的配合物。     

Measurements of Enthalpy Change of Reaction of Formation, Molar Heat Capacity and Constant-Volume Combustion Energy of Solid Complex Yb（Et2dtc）3（phen）

A ternary solid complex Yb(Et2dtc)3(phen) was obtained from the reaction of hydrous ytterbium chloride with sodium diethyldithiocarbamate (NaEt2dtc), and 1, 10-phenanthroline (o-phen·H2O) in absolute ethanol.The bonding characteristics of the complex were characterized by IR.The result shows Yb3 bands with two sulfur atoms in the Na(Et2dtc)3 and two nitrogen atoms in the o-phen.The enthalpy change of liquid-phase reaction of formation of the complex ΔrHθm (l), was determined as being (-24.838±0.114) kJ·mol-1 at 298.15 K, by an RD-496 Ⅲ type heat conduction microcalormeter.The enthalpy change of the solid-phase reaction of formation of the complex ΔrHθm (s), was calculated as being (108.015±0.479) kJ·mol-1 on the basis of an appropriate thermochemistry cycle.The thermodynamics of liquid-phase reaction of formation of the complex was investigated by changing the temperature during the liquid-phase reaction.Fundamental parameters, the activation enthalpy, ΔHθ≠, the activation entropy, ΔSθ≠, the activation free energy, ΔGθ≠, the apparent reaction rate constant k, the apparent activation energy E, the pre-exponential constant A, and the reaction order n, were obtained by a combination of the reaction thermodynamic and kinetic equations with the data from the thermokinetic experiments.At the same time, the molar heat capacity of the complex cm, p, was determined to be (86.34±1.74) J·mol-1·K-1 by the same microcalormeter.The constant-volume combustion energy of the complex, ΔcU, was determined to be (-17954.08±8.11) kJ·mol-1 by an RBC-Ⅱ type rotating-bomb calorimeter at 298.15 K.Its standard enthalpy of combustion, ΔcHθm, and standard enthalpy of formation, ΔfHθm, were calculated to be (-17973.29±8.11) kJ·mol-1 and (-770.36±9.02) kJ·mol-1, respectively.     

Thermochemical Properties of Solid Complexes of Rare Earth Nitrates with Methionine

ＴｈｅｒｍｏｃｈｅｍｉｃａｌＰｒｏｐｅｒｔｉｅｓｏｆＳｏｌｉｄＣｏｍｐｌｅｘｅｓｏｆＲａｒｅＥａｒｔｈＮｉｔｒａｔｅｓｗｉｔｈＭｅｔｈｉｏｎｉｎｅＧａｏＳｈｅｎｇｌｉ（高胜利），ＹａｎｇＸｕｗｕ（杨旭武），ＲｅｎＤｅｈｏｕ（任德厚）ＳｈｉＱｉｚ...     

Cu(TO)2Cl2的制备和热力学研究（英）

根据制备过程,提出了配合物Cu(TO)2Cl2在混合溶液中的晶体生长的动力学模型。通过这个动力学模型,测定了一系列的动力学参数Ea=45.37kJ·mol-1,ln(A/s-1)=14.65,Δ≠Gm=82.11kJ·mol-1,Δ≠Hm=42.85kJ·mol-1,Δ≠Sm=131.58J·mol-1·K-1。另外,用RD496-Ⅲ型微量热计测定了该化合物在298.15K时的比热容,并计算了[Cu(TO)2]2 (aq)和Cu(TO)2Cl2(s)的标准生成焓。     

鄂尔多斯盆地神木地区上古生界煤储层特征及含气潜力

通过对鄂尔多斯盆地神木地区上古生界含煤岩系中煤储层的纵横向分布、宏观煤岩类型、微观煤岩组分、孔隙结构与渗透性、镜质体反射率和吸附性能等方面特征的研究,认为:煤层总厚呈东西厚、南北薄的分布特点,煤层厚度满足煤层气开发的要求;多为半亮煤,仅东部边缘地带以半暗煤为主,表现为低含水、中等灰分含量和高挥发分含量的烟煤;煤岩显微组分中,镜质组含量最高,其次为惰质组;孔隙类型以微孔、过渡孔为主.研究区从北向南,煤级逐渐升高,整体表现为低—中煤级;煤的吸附能力较强,煤层气具有饱和、过饱和特征,煤层含气潜力大.最后指出,本区具有煤层气勘探开发的储层条件,含气潜力较大.      

GdCl3

采用半微量相平衡方法研究了GdCl