十字形碳化硅纤维的制备与微波电磁特性(英文)

通过先驱体法制备出十字形SiC纤维, 纤维外接圆直径为34μm左右, 纤维叶片长度为12μm左右, 宽度为8μm左右。使用同轴环方法测试了十字形SiC纤维的复介电常数和复磁导率, 测试表明纤维是介电损耗材料, 纤维的介电常数实部（ε′）、虚部（ε″）和介电损耗角正切值（tanδ=ε″/ε′）分别为2. 77~7. 93、1. 38~6. 41和0. 49~0. 81, 磁导率实部（μ′）和虚部（μ″）分别为0. 96~1. 12和-0. 05~0. 08。在2~18GHz频率范围内, 纤维/石蜡复合材料的反射率衰减大于10dB的频率为9. 12~18GHz, 最大衰减为28. 47dB, 对应频率为12GHz。反射率衰减大于10dB的频宽为8. 88GHz。     

内包金属富勒烯C_(66)-C_(84)团簇的结构特征

从富勒烯笼五六元环的分布情况评述了内包单金属、双金属、三金属以及三金属氮化物(M_3N)和碳化物(M_2C_2)富勒烯C_(66)～C_(84)团簇的结构特征.富勒烯满足五元环最大分离规则,内包不同类型的金属团簇不仅改变了笼的稳定性顺序,也使C_(66)、C_(68)、C_(70)、C_(72)、C_(74)、C_(78)和C_(84)的部分异构体违背五元环最大分离规则 .     

洋葱状富勒烯的研究进展

详细介绍和分析了洋葱状富勒烯(OLFS)的各种制备、纯化和改性方法,概述了其性能和应用的最新研究进展.OLFS特有的力、电、光、磁、吸附、催化等物理及化学性能,使其在工程、电子信息、能源、生物医学、化学化工、国防等领域有着广阔的应用前景.为此,应进一步围绕OLFS类新型纳米碳材料的制备、表面修饰、功能化、实际应用等各个环节的物理与化学问题进行探索,为该类功能材料的实际应用提供参考依据.     

文摘

匹兹堡能源技术中心净煤技术演示计划现状Energy Technol,1989,16(Eng)文中描述了此中心的几个煤洁净利用计划及相关技术和最新进展。其中的四个计划是有关燃烧技术的翻新改进,包括先进的熔渣燃烧器、吸附剂加入锅炉或加入出口产物、     

用PLC改造小型DCS系统取得成功

ＰＬＣ技术日益成熟，用其来改造一些早期的小型ＤＣＳ系统具有很高的性能价格比，是控制领域内一种新的尝试，具有普及意义。文章介绍了系统的总体结构、工作方式、功能及实施结果。     

新型碳素资源化学简介

<正> 占碳素资源很大比例的重质原油、煤等化石燃料,必须进行化学转变以便于运输和利用.为此,有必要建立新的化学体系作为理论基础,以便将由多种高分子量碳氢化合物组成的,含有硫、氮、无机灰分的固体,更有效地转     

质量流量计的振动管频率计算

质量流量计的振动频率计算是其研制生产中的一个关键性问题。本文以双U型管式质量流量计为例,从理论上详细推导了振动管频率的计算公式,并给出了样机的实验结果,理论计算频率与实测频率之间的误差为-4.5%。     

纳米金属微粒催化制备的洋葱状富勒烯的结构表征

采用金属Cu，Al做粒／石墨混合材料．用直流电弧放电方法制备了洋葱状富勒烯。对两种产物进行了XRD、SEM、HRTEM和Raman结构表征。结果表明：两种纳米金属微粒均可催化得到洋葱状富勒烯；所得产物中有单纯洋葱状富勒烯和内包纳米金属微粒洋葱状富勒烯，且石墨化程度都很高；纳米金属微粒尺寸大小不同决定洋葱状富勒烯的直径分布不均匀，从而造成其拉曼谱峰相对于石墨特征峰1582cm^-1发生了频移；用汽-液-固(VLS)生长模型描述了洋葱状富勒烯生长机理，解释了汽态碳原子通过在液态催化剂中扩散和析出，逐渐长大成形的现象。     

Preparation and self-assembly of chitosan/carbon microsphere composite

Carbon-based films were synthesized by self-assembly of chitosan-encapsulated carbon microsphere (CMS@CS) composite. First, carbon microspheres (CMSs) prepared by chemical vapor deposition were modified by HNO3 and H2O2. Second, oxidized CMSs were modified by chitosan (CS). Finally, CMS@CS was self-assembled by vertical deposition, in which suspension concentration and deposition temperature on the quality of self-assembling film were investigated. Field emission scanning electron microscopy, atomic force microscopy, X-ray diffraction, thermogravimetry, and Fourier transformation infrared spectrometry were employed to characterize the morphology and structure of the samples. The results show that CMSs modified by CS had uniform particle size and good dispersion, CMS@CS was self-assembled into a dense film, the film thickened with increasing suspension concentration at fixed temperature, and more ordered film was obtained at 1 wt% of suspension concentration and 50 ℃. The ultraviolet-visible absorption spectra show that the absorbance of CMS@CS film grew steadily with increasing suspension concentration and that the CMSs with oxygen-containing groups have a good assembling performance to form composite films with CS.     

Pt/洋葱状富勒烯复合纳米颗粒的结构表征

Onion-like Fullerenes[1](OLFs),a new carbon allotrope together with C60 and carbon nanotubes (CNTs),are closed-cage carbon molecules with the special structure of concentric spherical shells.Because of several unique properties,it has many potential applications in electronic,magnetic,tribological,photoluminescenic,conductive and wave absorbing areas[2].