Glycoconjugated polymer 6. Synthesis of poly[styrene-<Emphasis Type="Italic">block</Emphasis>-(styrene-<Emphasis Type="Italic">graft</Emphasis>-amylose)] via potato phosphorylase-catalyzed polymerization

Summary The potato phosphorylase-catalyzed polymerization of α-D-glucose-1-phosphate (G-1-P) onto poly[styrene-block-(4-vinylbenzyl maltohexaoside)] (1) was performed at the molar ratios of [G-l-P]₀ and [maltohexaose]₀ of 35, 80, and 250. The product was found to be soluble in dimethyl sulfoxide, which was a good solvent for amylose, and showed the complex-formation with iodine, indicating that the product was assignable to poly[styrene-block-(styrene-graft-amylose)] (2). The quantitative analysis of the liberated phosphoric acid gave the average degree of polymerization o f the glucose unit (n) as 27, 5 1, and 180 for 2-I, 2-II, and 2-III, respectively. Received: 29 November 2002/Accepted: 22 December 2002 Correspondence to Toyoji Kakuchi     

MULTICARRIER DS—CDMA WITH ADAPTIVE MODULATION AND POWER ALLOCATION

Adaptive modulation and power allocation is introduced into the multicarrier DSCDMA system to improve the system performance and bandwidth efficiency.First,the system design appropriate for adaptive modulation and power allocation is given,then the algorithm of adaptive modulation and power allocation is applied.Simulation results demonstrate great performance improvement compared with the fixed modulated one.     

Exchange-correlation errors at harmonic and anharmonic orders: the case of bulk Cu

As an aid towards improving the treatment of exchange and correlation effects in electronic structure calculations, it is desirable to have a clear picture of the errors introduced by currently popular approximate exchange-correlation functionals. We have performed ab initio density functional theory and density functional perturbation theory calculations to investigate the thermal properties of bulk Cu, using both the local density approximation (LDA) and the generalized gradient approximation (GGA). Thermal effects are treated within the quasiharmonic approximation. We find that the LDA and GGA errors for anharmonic quantities are an order of magnitude smaller than for harmonic quantities; we argue that this might be a general feature. We also obtain much closer agreement with experiment than earlier, more approximate calculations.     

高斜效率高功率850nm氧化限制型垂直腔面发射激光器

报道了MOCVD生长的高性能850nm氧化限制型垂直腔面发射激光器.研制出的氧化直径为9μm的激光器25℃时的斜效率和阈值电流分别为0.82mW/mA和2.59mA,激光器在23mA时输出16mW最大光功率.氧化直径为5μm的激光器25℃时的最小阈值电流为570μA,其最大饱和光功率为5.5mW.     

Electronic properties of magnetically doped nanotubes

Effect of doping of carbon nanotubes by magnetic transition metal atoms has been considered in this paper. In the case of semiconducting tubes, it was found that the system has zero magnetization, whereas in metallic tubes the valence electrons of the tube screen the magnetization of the dopants: the coupling to the tube is usually antiferromagnetic (except for Cr).     

24万t/a尿素装置技术改造总结

针对新化化肥有限公司尿素装置存在的问题进行了技术改造,从尿素合成塔、中压分解吸收、低压分解吸收、闪蒸等方面分析了产生问题的原因,提出了改进措施和实施方案。对改造前后工艺指标、产品质量和经济效益进行了对比和分析。改造结果表明.生产能力提高25％,5个月可收回全部投资。     

一种计算机实时控制系统的分析及其DCS实现

简述了计算机实时控制及分布式控制系统(DCS)的一般特点．并以某型水下机器人的控制系统为例，详细介绍了一种小型实时DCS系统的具体实现。     

水力脉动冲击钻井工具初步研究与试验

掘力脉动冲击钻井是将水力脉冲、机械冲击振动结合为一体提高钻井速度的一种方法，介绍了辽河油田研制的脉动冲击钻井工具的结构、工作原理及现场试验情况。在潜山混合花岗岩、砂岩，硬脆性泥岩等不同地层的现场试验表明：水力脉动工具工作平稳，未出现蹩跳钻现象，也没有出现脱、落、断、掉等问题，主体安全性、可靠性较好；在潜山混舍花岗岩、砂岩、硬脆性泥岩地层机械钻速提高幅度较大，但在部分泥岩地层效果不佳。试验中发现密封圈耐温性差、脉冲腔易磨损等问题，并据此提出了水力脉动冲击工具的下一步研究方向。     

厚膜永磁阵列微致动器的磁路研究

研究了厚膜永磁阵列微致动器中的磁场分布，并研究了永磁阵列单元几何尺寸对微致动器电磁力的影响。结果表明，厚膜永磁阵列单元高宽比和磁体单元间隔对微致动器电磁力影响较大磁徕单元高宽比为0．7是一个比较合适的尺寸。     

介质波导阵列的横向传播特性分析

根据已提出的有关二维周期介质严格分析理论，针对介质波导阵列进行了大量的数值计算。对介质波导阵列中波的横向传播作了详细分析。首先，在给定纵向波矢量(k)的情况下，分析了在不同工作频率时的横向波矢量间布里渊区色散特性，对空间谐波的相互作用情况也进行了研究。其次，在给定工作频率的情况下，分析了不同纵向波矢量和不同调制系数时的横向波矢量间布里渊区色散特性。由于空间谐波的相互作用随纵向波数或调制系数的增大而增强，导致阻带能明显地表现出来，从而使介质波导阵列的横向传播特性能较为全面地得到分析。