基于STC单片机的GPS定位显示系统设计

全球定位系统（ GPS）能够全天候、全方位的为海陆空用户提供连续的、高精度的三维坐标、三维速度和时间等信息。本设计以STC12C5A60S2单片机为核心进行硬件电路设计,采用集成GPS信号接收模块ATK-NEO-6M接收GPS卫星信号,单片机接收该数据并进行数据处理,在德飞莱TFT2．4液晶显示屏上显示出相应信息。应用C语言进行软件设计,实现GPS信号的提取、显示及基本的控制操作等,给出了软件流程图。     

Engineering oxygen vacancy-rich Co3O4 nanowire as high-efficiency and durable bifunctional electrocatalyst for overall alkaline water splitting

A novel kind of vacancy-rich nanowire arrays were prepared by reducing rough Co₃O₄ nanowires with NaBH₄ solution on 3D nickel foam at room temperature for overall water splitting. Co₃O₄/NF treated by NaBH₄ for 10 min was highly active for oxygen evolution reaction (OER) and simultaneously efficient for hydrogen evolution reaction (HER) with the need of the overpotentials of 240 and 132 mV to drive 10 mA·cm^-2 in alkaline media, respectively. Furthermore, the electrocatalysts as both cathode and anode in a two-electrode system presented excellent durability for over 60 h at 10 mA·cm^-2, maintaining the cell voltage of merely 1.63 V. This work provides new methods and ideas for the preparation of transition metal oxide bifunctional electrocatalysts rich in oxygen vacancies.     

放电等离子烧结工艺对Ca3Co4O9陶瓷织构及电性能的影响

采用溶胶-凝胶与放电等离子烧结(SPS)相结合的方法制备了Ca3Co4O9陶瓷.通过X射线衍射、扫描电镜等表征手段,研究了放电等离子烧结工艺对Ca3Co4O9物相、显微结构和性能的影响.实验结果表明片状颗粒和放电等离子烧结工艺,特别是烧结温度的提高有利于Ca3Co4O9织构的形成.初步认为是片状颗粒在脉冲电流所产生的脉冲磁场作用下发生重排,使颗粒定向排列.本实验范围内,当烧结温度从700℃提高到900℃时,Ca3Co4O9晶粒取向度从0.75增大到0.87,700℃下的电阻率从6.24×10-5 Ωm降低到5.59×10-5 Ωm.此外,Ca3Co4O9块体表现出典型的半导体电学特征,电导率随着SPS烧结温度和测量温度的升高而增大,当SPS烧结温度为850℃时,P型Ca3Co4O9化合物在700℃有最大电导率.     

稀土、锶复合添加对AM60镁合金组织和性能的影响

稀土、锶复合添加对AM60镁合金组织、力学性能和抗热裂性能的影响的研究结果表明,往AM60镁合金中添加稀土后,稀土与合金中的异质形核核心Al9Mn11相或Al(8Fe,Mn)5相反应生成Al-RE-Mn三元相,减少了合金熔体中异质形核核心的数目,从而引起了合金晶粒粗化。往AM60镁合金中复合添加稀土和锶后,锶能够消除稀土引起的晶粒粗化作用,减少晶粒粗化对合金力学性能和抗热裂性能的不利影响,从而提高合金的高温屈服强度,并消除稀土对合金抗热裂性能的恶化作用。     

高频感应熔覆Ni60合金粉末涂层的研究

研究了用3种方法制备的Ni60合金粉末涂层的显微组织和腐蚀特性，其中用第1种冷涂法制备预涂层，再经高频感应熔覆的方法比用第2种氧—乙炔喷涂法制备预涂层，然后用高频感应熔覆的方法经济实用。这两种方法所制备的涂层性能接近，组织均匀细致，有丰富的增强耐磨性的硬质相，显微结构和抗腐蚀性明显优于第3种用氧—乙炔喷焊制备的涂层。总之，冷预涂加高频熔覆法优于氧—乙炔预涂加高频熔覆法，高频感应熔覆法优于氧—乙炔喷焊法。     

喷涂与激光重熔技术制备镍基纳米钴包碳化物复合涂层的研究

采用横流2．0kW CO2激光器，在45钢表面制备了表面较平整、较细密、基本消除了裂纹与孔隙并与基体呈冶金结合的镍基纳米WC／Co复合涂层。通过SEM，EDAX，XRD，AFM及Nano Indenter XP分析了熔覆层的显微组织、成分、物相及结合强度。结果表明，涂层的显微组织为涂层中镶嵌着大量与Ni基合金结合良好的WC／C。颗粒，其中在原子力显微镜下可见相当数量的粒度≤100μm的纳米颗粒。涂层的结合强度比传统热喷涂涂层提高了2．1倍。涂层中纳米WC／Co的纳米效应在激光熔覆中起着重要作用。     

高速冲压中硬质合金级进模磨损研究

通过高速冲裁试验和金相检测,对比了硬质合金级进模刃口磨损前后的表面形貌、微观结构和Co元素含量百分比的变化,并结合骨架理论和复合增强理论,从微观结构方面解释了Co元素丢失对硬质合金级进模磨损的影响。对于提高精密级进模的寿命和提高电子零件的生产效率具有重要的意义。     

Surface modification of spherical LiNi1/3Co 1/3 Mn1/3O2 with Al2O3 using heterogeneous nucleation process

To improve the cycle stability at high voltage and high charge/discharge rate, spherical LiNi1/3Co1/3Mn1/3O2 was coated with Al2O3 by using heterogeneous nucleation process, and the physical and electrochemical properties were studied. The SEM images show that there is a uniform coating on the modified spherical LiNi1/3Co1/3Mn1/3O2. The electrochemical tests indicate that the properties of LiNi1/3Co1/3Mn1/3O2 coated with 0.5% aluminum oxide are the best. The initial capacities are 150 and 173 mA.h/g at the rate of I C in the voltage range of 2.7-4.3 V and 2.7-4.6 V, respectively, and the discharge capacities maintain about 99% and 85% after 30 cycles, respectively. While those of the bare LiNi1/3Co1/3Mn1/3O2 are only 90% and 75%, respectively. The CV tests of LiNi1/3Co1/3Mn1/3O2 show that Al203-coating can restrain the oxide-reduction peak currents fading during the charge/discharge course.     

Sr对AM60B铸造镁合金晶粒细化的影响

研究了Sr对AM60B合金晶粒细化的影响.结果表明,微量Sr能提高AM60B合金的初生相析出温度,降低再辉温差;凝固过程中Sr位于晶粒生长前沿,抑制了晶粒的长大,从而有效地细化了晶粒,在本试验条件下,从约425μm降至约147μm.     

Synthesis and characterization of LiNi0.45Co0.10Mn0.45O2 cathode for lithium ion batteries

1INTRODUCTIONAdvanced rechargeable lithium ion batteriesare attractive for use in consumer electronic andelectric vehicle(EV)application because of a fa-vorable combination of voltage,energy density,cycling performance,and have been developed rap-idly worldwide during the past decade[1,2].LiCoO2has been widely used as a cathode material in com-mercial lithiumion battery because it is reasonableeasy to synthesize and shows a stable discharge ca-pacity[3].But due to its high cost and toxic…