Anodic oxidation of mecoprop herbicide at lead dioxide

The electrochemical oxidation of an aqueous solution containing mecoprop (2-(2-methyl-4-chlorophenoxy)propionic acid) has been studied at PbO₂ anodes by cyclic voltammetry and bulk electrolysis. The influence of current density, hydrodynamic conditions, temperature and pH on the degradation rate and current efficiency is reported. The results obtained show that the use of PbO₂ leads to total mineralization of mecoprop due to the production of oxidant hydroxyl radical electrogenerated from water discharge. The current efficiency for the electro-oxidation of mecoprop is enhanced by low current density, high recycle flow-rates and high temperature. In contrast, the pH effect was not significant. It has also been observed that mecoprop decay kinetics follows a pseudo-first-order reaction and the rate constant increases with rising current density.     

Si相的析出状态对Al—Si合金性能的影响

控制Si相的析出状态,会对Al-Si(1wt％)合金的性能产生不同的影响。本文阐述通过不同的热处理工艺改变了Al-Si(1wt％)合金的机械、物理性能,获得了高形变强化率、高塑性变形能力、高拉伸强度的工艺,还讨论了具有上述高拉伸强度的微细丝在半导体器件应用中所具有的优越性。     

硅梁式引线肖特基混频四管堆

介绍了硅梁式引线肖特基混频四管堆的研制。通过计算,获得各项设计参数,讨论了所采用的一些新工艺,管堆总电容C_t≤0.5pF,串联电阻R_s≤4Ω,管堆一致性和可靠性好。将管堆用于S波段双平衡混频器HSP25,性能优良。在这个研制的基础上,可以制作出其它多种形式的梁式引线器件。     

滚子丝杠副的原理研究

本文对滚子丝杠副的运动原理及啮合原理进行分析 ,并推导了参数计算公式及由啮合原理求出了滚子的空间螺旋面方程     

引线框架用铜合金QFe2.5的退火性能

分析对比了QFe2．5合金的红锭和黑锭在不同温度退火后的高、低倍金相组织与力学性能。结果表明：由于第二相分布较均匀，退火后红锭试样的性能变化比较平缓，高温下晶粒较小，轧制时开裂较少；由于Fe的不均匀分布，有较大的铸造应力，高温扩散退火时基体晶粒粗大及晶界上的显微孔洞等因素的综合作用，使黑锭在高温轧制时容易开裂。     

日用陶瓷铅溶出量与儿童多动症关系的探讨

根据目前日用陶瓷铅溶出量状况和铅中毒儿童多动症的研究结果，论证了日用陶瓷铅溶出量与儿童多动症存在相互关系，介绍了日用陶瓷铅溶出量与铅中毒检测方法，对铅中毒儿童多动症的预防和治疗提出了建议。     

Morphologic study of electrochemically formed lead dioxide

Various electrochemical methods with different conditions were used to prepare lead dioxide (PbO₂). The observation revealed that the morphology of deposited PbO₂ could be controlled by simply changing deposition parameters. Under the condition of oxygen evolution, which dominates the electrode process, uniformly distributed high porous structured PbO₂ was formed. The results indicated that large current density or high potential polarization should be one of the most important and necessary factors for forming high surface area PbO₂ deposit. Only β-PbO₂ was identified by X-ray diffraction measurement for the deposit prepared by present methods and solution. One potential application of this method is to prepare nanoscaled PbO₂ parallel lines.     

Effect of competitive interference on the biosorption of lead(II) by Chlorella vulgaris

Batch experiments were carried out to asses the effect of Cu(II) and Zn(II) on the biosorption of lead(II) ions by non-living Chlorella vulgaris. The uptake of Pb(II) was examined for single, binary and ternary solutions at different initial concentrations and different pH values. The experimental results showed that the uptake increased with increasing pH from 3.0 to an optimum value of 5.0. The biosorption of Pb(II) was found to be adversely affected by the presence of Cu(II) ions, while Zn(II) ions seemed to have negligible effect on the process. The equilibrium data were fitted to four isotherm models: Langmuir, Freundlich, Sips and Dubinin–Radushkevich; the Sips isotherm gave the best fit for the data. Modeling of the controlling mechanisms indicated that both intrinsic kinetics and mass transfer played major roles in controlling the process. A new dimensionless parameter, Ψ, was defined to asses the relative contributions of the two mechanisms to the biosorption of lead(II). Mass transfer seemed to be the dominant mechanism at low initial lead(II) concentrations, while intrinsic kinetics dominates at high concentrations.     

低熔封接微晶玻璃无铅化的最新研究进展及其发展趋势

低熔封接微晶玻璃是一种先进的焊接材料，由于其具有低的熔化温度和封接温度，优良的机械强度和化学稳定性，而在很多领域中得到广泛的应用，实现了玻璃、陶瓷、金属、半导体间的相互封接。综述了无铅低熔封接微晶玻璃的研究现状，展望了无铅低熔封接微晶玻璃今后的研究发展方向。