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11.
12.
Yuling Ma Litao Tong Juan Li Jawad Ashraf Shanshan Wang Bo Zhao Liya Liu Christophe Blecker Sumei Zhou 《International Journal of Food Science & Technology》2021,56(4):1562-1573
In this study, the accumulation of GABA and its inherent factors across different varieties of mung bean (Vigna radiata L.) in response to heat and relative humidity (HRH) were investigated. Results showed the average GABA content in mung bean varieties was increased 7.52 times following HRH treatment, and the black mung bean variety (A8) exhibited the highest GABA accumulation capability (1.76–84.57 mg per 100 g DW). From the perspective of GABA shunt metabolites, the free glutamic acid content of mung beans significantly decreased (P < 0.05) after HRH treatment and presented a significant correlation (P < 0.05) with GABA content. In polyamine degradation pathway, although the average levels of spermine and spermidine of mung bean varieties significantly decreased (P < 0.05) after HRH treatment, no significant correlation with GABA content was identified. Hence, the GABA accumulation was predominantly attributed to GABA shunt. Besides, free amino acids including glutamic acid, serine, ornithine, arginine and glycine in mung beans showed a significant positive correlation (P < 0.05) with GABA content and increment following HRH treatment, which suggested that mung beans enriched in these free amino acids might accumulate higher amounts of GABA after HRH treatment and be useful for industrial applications. 相似文献
13.
John McGrady Shinichi Yamashita Atsushi Kimura Sho Kano Huilong Yang Zhengang Duan 《Journal of Nuclear Science and Technology》2020,57(4):463-471
ABSTRACTTypical metal oxide corrosion products of structural materials have been irradiated with γ-rays in ultra-pure water to investigate the effect of radiation on the surface oxide and the nature of adsorbed water. Analysis techniques including thermal gravimetric analysis, differential thermal analysis, diffuse reflectance infrared Fourier transform spectroscopy, and X-ray photoelectron spectroscopy before and after γ-irradiation were employed to investigate surface structural effects and adsorbed water behaviour. The production of H2 in the oxide nanoparticle mixtures was investigated by gas chromatography to probe the mechanism of radiolysis in the water/oxide mixtures and the relationship with surface water. The nature of water at the surface of the oxides was affected by γ-radiation and the relationship was dependent on the particle composition. The rate of H2 production was shown to be oxide dependent, and higher rates of H2 formation were attributed to the decomposition of surface adsorbed water. Changes to the surface chemistry and H2 production rates were found to be highly dependent on the surface chemistry of the metal oxide nanoparticle and no bulk structural changes were observed. 相似文献
14.
以整体型α-Al2O3为载体,晶种胶作导向剂,通过凝胶预陈化路线合成了多级孔道FAU整体材料。对合成的样品进行了FT-IR、XRD、SEM和N2吸附脱附表征。根据实验结果确定了晶种胶、凝胶预处理及预陈化步骤的作用,同时提出了不同路线生成氧化铝复合物可能的合成机理。结果发现:负载的FAU沸石的粒径、形状及数量可通过改变晶化凝胶的组成,并且α-Al2O3载体的结构没有明显改变。具有简单、可重现且易将三重孔道结构融于成型的整体材料中的特点,通过晶种胶预处理的凝胶预陈化路线可加强载体内表面与沸石间的界面作用,形成纯相FAU晶体沉积在α-Al2O3载体骨架表面的形貌。另外,该方法可为其他的多级孔道沸石的合成提供思路。 相似文献
15.
Junfeng Zhang Meng Zhang Shuyao Chen Zeling Zhou Kaiwen Zheng Yunxing Bai Yisheng Tan Yizhuo Han 《加拿大化工杂志》2020,98(7):1525-1533
Low-temperature methanation of CO in the continuous stirred tank reactor (CSTR) over Zr doped Ni/Al2O3 catalyst calcined at different temperatures (673, 723, and 823 K) was investigated. XRD, TPR, XPS, ICP, SEM, and S-TPR techniques were employed to characterize the fresh and spent catalysts. Based on the characterization results, it was found that low-temperature (673 K) calcination could effectively prohibit the formation of NiAl2O4 spinel, thereby resulting in more reducible NiO particles, which were the essential precursor of methanation active sites over the catalyst surface. Thus, the highest CO conversion of 93.6% was achieved over the 25N3ZA-673 catalyst. In addition, the deactivation rate of 25N3ZA-673 was relatively slow in comparison to 25N3ZA-823 due to the presence of more reducible NiO. The formed nickel carbonyl species (Ni[CO]x), which quickly decomposed at a higher reaction temperature, was closely related to the catalyst deactivation. Therefore, 25N3ZA-673 possessed much better stability at 593 K than that at 553 K. 相似文献
16.
Ammaru Ismaila Huanhao Chen Yan Shao Shaojun Xu Yilai Jiao Xueli Chen Xin Gao Xiaolei Fan 《中国化学工程学报》2020,28(9):2328-2336
Excess crude glycerol derived as a by-product from biodiesel industry prompts the need to valorise glycerol to value-added chemicals. In this context, catalytic steam reforming of glycerol (SRG) was proposed as a promising and sustainable alternative for producing renewable hydrogen (H2). Herein, the development of nickel (Ni) supported on ceria-modified mesoporous γ-alumina (γ-Al2O3) catalysts and their applications in catalytic SRG (at 550–750 °C, atmospheric pressure and weight hourly space velocity, WHSV, of 44,122 ml·g−1·h−1 (STP)) is presented. Properties of the developed catalysts were characterised using many techniques. The findings show that ceria modification improved Ni dispersion on γ-Al2O3 catalyst support with highly active small Ni particles, which led to a remarkable catalytic performance with the total glycerol conversion (ca. 99%), glycerol conversion into gaseous products (ca. 77%) and H2 yield (ca. 62%). The formation rate for H2 production (14.4 × 10−5 mol·s−1·g−1, TOF (H2) = 3412 s−1) was significantly improved with the Ni@12Ce-Al2O3 catalyst, representing nearly a 2-fold increase compared with that of the conventional Ni@Al2O3 catalyst. In addition, the developed catalyst also exhibited comparatively high stability (for 12 h) and coke resistance ability. 相似文献
17.
Microalloying is thought to improve the performance of Al–Mg alloys commonly used in transport applications. The effect of Y addition (0–0.4%) on the microstructure, mechanical properties, and corrosion resistance of Al–9.2Mg–0.7Mn alloy is investigated for potential use in engineering applications. The generation of the β-Al3Mg2 phase along the grain boundaries is suppressed in the as-cast alloy due to the formation of the AlMgY ternary phase. The average intergranular corrosion mass loss of the alloy with 0.1% Y addition decreases about 53.1% almost at no expense of mechanical performance in the as-rolled alloy after annealing. Moreover, the alloy with 0.1% Y addition shows the corrosion mass loss about 30.2% lower than the Y-free alloy in the sensitized state. The enhanced corrosion resistance of the alloy can be ascribed to the reduced β-Al3Mg2 precipitation along the grain boundaries associated with Y addition. 相似文献
18.
Junyuan Bai Xueyong Pang Xiangying Meng Hongbo Xie Hucheng Pan Yuping Ren Min Jiang Gaowu Qin 《材料科学技术学报》2020,(1):167-175
The crystal structure of the single-unit-cell thickness γ " phase,as a key strengthening phase in Mg-REZn(Ag) series alloys,has been extensively studied,and several structural models have been proposed in the past two decades.However,these reported models,and even the lattice constants at the same proposed structure,are scattered severely,which has led to considerable confusion and not available for further mechanical property simulation and prediction of Mg alloys containing this phase.In this study,by using first-principles calculations,the crystal structure of y" phase is clarified,resolving the discrepancies among different experiments,and its intrinsic mechanical properties have also been studied for the first time.It is verified that the γ " phase contains quasi-five atomic layers,instead of the previously reported tri-layer,and surprisingly,its crystal structure has many variants,which would change with the alloy composition.Besides,with the help of the simulated selected area electron diffraction(SAED) patterns,it is found that the atoms in the central layer remain partially ordered distribution,and this ordered extent primarily depends on the atomic ratio of RE:Zn(Ag) and the solute content in an alloy.That is,the ordered extent increases with decreasing the atomic ratio of RE:Zn(Ag) and/or increasing solute content of alloy,and vice versa.Ag and Zn dissolved in the γ" phase would produce almost opposed mechanical anisotropy for the γ " phase under the identical crystal structure,and the addition of Ag shows more efficient on increasing the shear modulus of γ" phase. 相似文献
19.
Marwa M. Ibrahim 《中国化学工程学报》2021,40(12):225-236
To preserve the environment for civilization, we should remove the pollutants like toxic dyes by friendly and cost efficacious method. In this study, the effect of surfactants or mixed surfactants on physicochemical, optical and adsorption properties of ternary mixed oxide CeO2-ZrO2-Al2O3 (CZA) are investigated. The ternary mixed oxide CZA was prepared by surfactants or mixed surfactants assisted ultrasonic co-precipitation method. The physicochemical and optical properties are estimated by different techniques like XRD, TEM, EDX, FTIR, SBET and UV–Vis/DR. The CZAT and CZAC have hybrid shapes and high surface area. The adsorption properties of ternary mixed oxides adsorbents were characterized by sono-removing anionic dyes such as Congo red (CR) and Remazol red RB-133 (RR). The different factors like contact time, different dye concentrations and temperatures also studied. The kinetics and isotherms applications showed that, the adsorption process was followed pseudo second order kinetics and the Freundlich isotherm model. Also, the adsorption is spontaneous and endothermic process through the thermodynamic study. Finally, the results showed that the ternary mixed oxide nano-adsorbent (CeO2-ZrO2-Al2O3) is promising and functional materials for anionic dye sweep from wastewater. 相似文献
20.
Hadi Munarko Azis Boing Sitanggang Feri Kusnandar Slamet Budijanto 《International Journal of Food Science & Technology》2021,56(9):4540-4548
Germination of brown rice can be completed by full soaking and partial soaking methods. This study aimed to analyse the influence of germination methods on the bioactive accumulations in germinated brown rice (GBR). Germination was conducted in four treatments: (i) membrane reactor with full (RFS) and (ii) partial soaking method soaking (RAG), (iii) manual soaking for complete germination (MFS) and (iv) partial manual soaking in combination with atmospheric germination (MAG). The results showed that soaking BR in membrane reactor accelerated the shoots' growth and increased GABA (γ-aminobutyric acid) content compared with the manual soaking method. The RAG treatment achieved higher GABA content (up to 125 mg/100 g), total phenolic and flavonoid content, and antioxidant activity than other germination methods. The main finding of this research indicates that membrane reactor effectively enhances the growth of sprouts. The combination of partial soaking in membrane reactor and atmospheric germination (RAG) is a suited method to increase GABA accumulation in GBR. 相似文献