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21.
Clara G. Soubelet María P. Albano 《International Journal of Applied Ceramic Technology》2020,17(3):1141-1154
Well-dispersed concentrated aqueous suspensions of Al2O3-doped Y-TZP (AY-TZP), AY-TZP with 5.4 vol% of CaO–P2O5–SiO2 (CaPSi) glass (AY-TZP5) and 10.5 vol% CaPSi glass (AY-TZP10), with ammonium polyacrylate (NH4PA) dispersant were prepared to produce slip cast compacts. The rheological properties of 35 and 40 vol% slips were studied. The densification, microstructure as well as hardness and fracture toughness were investigated as a function of CaPSi glass content at 1300°C-1500°C. The optimum NH4PA concentration of 35 vol% AY-TZP5 and AY-TZP10 slips at pH ~9 was found to be about 43% and 67% greater than that of AY-TZP slips; this behavior was related to the greater amounts of Ca2+ ions leached out from the CaPSi glass surface. The viscosity of stabilized 40 vol% slips with NH4PA attained a minimum value at 5.4 vol% CaPSi glass addition, and resulted in a more dense packing of cast samples. AY-TZP5 can be sintered at a lower temperature (1300°C) compared to that of AY-TZP. AY-TZP5 exhibited a fine microstructure of tetragonal ZrO2 (grain sizes below 0.3 µm), and ZrSiO4–Ca2P2O7 particles homogeneously distributed within the zirconia matrix. It presented similar fracture toughness and a slightly lower hardness compared to those of AY-TZP. 相似文献
22.
Guangyao Chen Baotong Li Hao Zhang Ziwei Qin Xionggang Lu Chonghe Li 《International Journal of Applied Ceramic Technology》2016,13(6):1173-1181
Various ZrO2/CaO samples were fabricated by cold isostatic pressing and sintered at 1750°C for 4 h. It was observed that the sample with 12% ZrO2 additive possessed the good hydration resistance and had the lowest apparent porosity of about 0.75%; its weight additive stored after 56 days was less than 0.6 wt%, and it contributed to the occurrence of CaZrO3 on the surface of CaO. The CaO crucible with 12 mol% ZrO2 additive did not react with titanium melt during melting TiNi alloy. This provides a support for searching a new refractory with the good hydration resistance for induction melting titanium alloys. 相似文献
23.
通过高温烧结法在不同钙铝比(C/A)的条件下合成了铝酸钙熟料。利用XRD对不同C/A下合成产物进行物相分析,对含量进行半定量分析,并计算其晶格常数。采用SEM观察不同C/A下合成产物的显微结构,并通过EDS佐证所得物相;最后研究了不同C/A下氧化铝的溶出性能。结果表明:当C/A<1.6时得到的产物为CaO·Al2O3和11.3CaO·7Al2O3(C11.3A7),且随着C/A的增大,C11.3A7的含量增高,氧化铝的溶出率提高;当C/A=1.6时得到的产物只有C11.3A7,溶出率达到最大;当C/A>1.6时由于3CaO·Al2O3的形成,溶出率有所降低。C11.3A7晶格中CaO的缺失,促进了溶出反应的进行。 相似文献
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基于化学链燃烧的原理,利用固定床反应器,以铁触媒为催化剂和载氧剂,CaO为吸附剂,研究了化学链燃烧法净化合成氨原料气的可行性。系统考察了还原阶段CaO、汽气比、温度、CaO与铁触媒质量比等因素对原料气脱碳效果的影响,以及氧化阶段温度对铁触媒氧化和CaCO3热分解效果的影响。结果表明,在还原阶段,铁触媒既是CO变换反应的催化剂又是过程的载氧剂,而吸附剂CaO的存在,不仅能快速吸附CO2,而且能有效促进CO的变换反应,同步脱除CO和CO2,且适宜的还原条件为:汽气比8.0左右、温度500~550℃、CaO与铁触媒质量比3:1。在氧化反应阶段,当操作温度为800℃时,还原态的铁触媒Fe3O4可迅速被氧化为Fe2O3,CaO可完全再生,铁触媒的氧化反应热能有效促进CaCO3的热分解。 相似文献
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In present work, the aim of producing biodiesel from waste cooking oil was pursued by doping the cerium element into the MCM‐41 framework as catalyst with various Si/Ce molar ratio (5, 10, 25, 50, and Ce = 0). The catalytic performance and stability improved by employing the ultrasound irradiation in active phase loading step of catalyst preparation. The physicochemical characteristics of synthesized samples were investigated using various techniques as follows: Brunauer‐Emmett‐Teller (BET), X‐ray powder diffraction (XRD), Fourier transfer infrared (FTIR), energy‐dispersive X‐ray spectroscopy (EDX), transmission electron microscopy (TEM), and field emission scanning electron microscope (FESEM). The XRD patterns along with the results of FTIR and BET analysis revealed the MCM‐41 framework destruction while increasing the Ce content. The FESEM images of the nanocatalysts illustrated a well distribution and uniform morphology for the Ca/CeM (Si/Ce = 25). The particle size and size distribution of the Ca/CeM (Si/Ce = 25) were subsequently determined by TEM and FESEM images. The activity of fabricated nanocatalysts was evaluated by measuring the free acid methyl ester (FAME) content of produced biodiesel. The tests were carried out at constant operational conditions: T = 60°C, catalyst loading = 5 wt%, methanol/oil molar ratio = 9, and 6‐hour reaction time. A superior activity was observed for Ca/CeM (Si/Ce = 25) among other nanocatalysts with 96.8% conversion of triglycerides to biodiesel. The mentioned sample was utilized in five reaction cycles, and at the end of the fifth cycle, the conversion reached to 91.5% which demonstrated its significant stability. 相似文献
29.
L. J. Konwar D. Deka 《Energy Sources, Part A: Recovery, Utilization, and Environmental Effects》2018,40(6):601-607
In the wake of increasing environmental constraints, this work is aimed at developing a catalyst purely prepared from waste biomass source as the raw material. The catalyst is investigated for its applicability in transesterification of vegetable oil with the objectives: (i) to use waste shells of mollusk as raw material for the preparation of activated carbon and CaO; (ii) to use it as heterogeneous catalyst in the transesterification of waste cooking oil; (iii) to optimize the different parameters affecting the transesterification reaction; and (iv) to study its reusability. Under optimized conditions it was observed that a conversion >90% was possible and the catalyst could be reused five times with a slight loss in activity. This study indicates that the biomass source could also be used as a potential raw material in the synthesis of environmentally benign catalysts. 相似文献
30.
Fei Gao Jiali Huang Hongman Sun Jun Hu Meihong Wang Jiawei Mi Chunfei Wu 《能源学会志》2019,92(5):1591-1598
CaO is a promising material as an alternative CO2 capture material which can be used at high temperature. However, CaO sinters to form large particles under long-term high temperature conditions, resulting in a rapid decrease of its surface area and the capacity of CO2 capture. Incorporating CaO into inert materials is a promising strategy to enhance the performance of CO2 capture. This work investigated a novel composite material called mesocellular siliceous foam (MCF)-supported CaO to enhance the stability and capacity of CaO-based materials for CO2 capture. The crystal structure, surface morphology and porosity property of the developed composite materials were investigated. Thermogravimetric measurements were carried out to study the cyclic CO2 capture performance of the MCF-supported CaO composites. The results showed that a part of CaO reacted with the silica wall, and the formation of Ca2SiO4 within the MCF framework limited the presence of CaO in the mesopores, thus inhibited the sintering of CaO. The sample of MCF-3CaO exhibited a better performance of CO2 capture and long-term stability, compared with the materials prepared with lower CaO loading. This work contributes to the development of high temperature CO2 capture adsorbents, which can be applied for decarbonizing major industrials e.g. power plant. 相似文献