Double nanocrystalline engineering for effective enhanced photoluminescence of Tb3+ in glass ceramic

Despite possessing good feature for optical thermometry, the rare (RE) ions-based temperature sensing (TS) has innate shortcoming of thermally coupled levels (TCLs) energy gap overlap, which reduces the sensitivity. In this work, a dual-luminous centers TS based on Tb³⁺ doped Cs₄PbBr₆ quantum dots (QDs) glass ceramic is fabricated. By locating in low phonon energy crystal field environment of Cs₂ZnSi₅O₁₂ nanocrystalline (NS) and Cs₄PbBr₆ QDs, the emission intensity of Tb³⁺ can be enhanced by 14 times. The large exciton binding energy (420 meV) indicates that the prepared QDs glass ceramic has a good thermal stability and the PL intensity of Cs₄PbBr₆ QDs and Tb³⁺ can be well-maintained above 70% and 89% after 8 thermal cycles between 323K and 373K. Furthermore, the obtained maximum absolute sensitivity (S_a) and relative sensitivity (S_r) is as high as 0.2541 K^-1 and 2.68% K^?1, respectively. It is expected that the finding of this work can offer a help in exploring novel QDs/RE ions-based TS and further optimize their practical applications.     

Numerical study on premixed hydrogen/air combustion characteristics and heat transfer enhancement of micro-combustor embedded with pin fins

Aimed at improving the energy output performance of the Microthermal Photovoltaic (MTPV) system, it is necessary to optimize the structure of the micro combustor. In this paper, micro combustor with in-line pin fins arrays (MCIPF) and micro combustor with both end-line pin fins arrays (MCEPF) were presented to realize the efficient combustion and heat transfer enhancement, and the influence of inlet velocity, equivalent ratio, and materials on thermal performance was investigated. The results showed that pin fins embedding is beneficial to improving combustion, and the combustion efficiency of MCIPF and MCEPF reaches 98.5% and 98.7%, which is significantly higher than that of the conventional cylindrical combustor (MCC). However, with the increase of inlet velocity from 8 m/s to 14 m/s, MCIPF exhibits the highest external wall temperature with a range of (1302–1386 K), while MCEPF maintains the best temperature uniformity. As the inlet velocity increases to 10 m/s, the external wall temperature and temperature uniformity reach the optimum. Besides, under the conditions of different equivalence ratios, both external wall temperature and heat flux increases first and then decreases, meanwhile the temperature uniformity of MCEPF is significantly improved compared with that of MCIPF, they all exhibit the highest external wall temperature with an equivalence ratio of 1.1, and the thermal performance is greatly enhanced. By comparing the heat transfer performance of combustors with different materials based on MCEPF, it is interesting to find that the application of high thermal conductivity materials can not only increase the external wall temperature, but also improve the temperature uniformity. Therefore, materials with high thermal conductivity such as Aluminum, Red Copper and Silicon Carbide should be selected for application in micro combustors and their components. The current work provides a new design method for the enhanced heat transfer of the micro combustor.     

Temperature distribution within a ceiling jet propagating in an inclined flat-ceilinged tunnel with natural ventilation

In this study, we conducted detailed measurements of the temperature distribution within a steady fire-driven ceiling jet, formed in a tunnel with a rectangular cross-section. We then compared the measured temperature distributions with those for an unconfined smooth-ceiling jet flow, and estimated the relative errors between them. The results showed that the temperature distribution in a horizontal tunnel exhibits a greater bulge than that of a ceiling jet under an unconfined ceiling and varied from a bulging shape to an exponential shape as the tunnel inclination increased. We propose a new correlation for representing the temperature distribution, which takes the tunnel inclination into account, and which consists of an exponential function and a cubic function with a coordinated transformation.     

重整装置首次开工关键因素探讨

阐述了做好重整装置首次开工的几个关键因素：做好预处理开工工作，确保重整进料合格；做好重整催化剂的处理工作；把好重整进油后480℃温度关；遵守操作规程，平稳操作。     

LNG energy transfer uncertainty–sensitivity to composition and temperature changes

Determining and reducing the measurement uncertainty of LNG energy transfer in custody transfer operations is considered extremely important and challenging for industry. The European Metrology Research Programme (EMRP) for Liquefied Natural Gas (LNG) has been focused on reducing the uncertainty in the evaluation of LNG energy transfers by improving existing measurement methods, validating new measurement methods and development of new traceable calibration systems. Part of this project was to produce realistic measurement uncertainty budgets and to determine the sensitivity of the overall LNG energy transfer uncertainty to changes in the composition and temperature of different LNG cargoes.This paper provides details on the development of an uncertainty budget and the results from the sensitivity study. It was found that the uncertainty in the LNG energy transfer ranged from 0.56% to 0.77% when using the uncertainty budget for 461 LNG cargoes. The variation was mainly due to the difference in the LNG composition and its associated uncertainty.     

Time-temperature transparency in the cold chain

A study concerning time-temperature information sharing behavior in the one-step forward chilled and frozen food supply chains was conducted. We mailed 1774 questionnaires to food manufacturing companies in Taiwan with a response rate of 7.0%. We showed that obtaining raw materials time-temperature information from suppliers was more difficult than obtaining processed food product information from food manufacturers. The determinant factors considered were also different. For sharing time-temperature information on raw materials during distribution from suppliers to food manufacturers, the relative power of food manufacturers, business strategy, and raw material quality uncertainty were important. However, for sharing information on processed product during distribution from food manufacturers to buyers, only business strategy and processed product quality uncertainty were important. This implies that requesting information from suppliers requires more effort. In addition, when zooming in, we found that the time-temperature sharing strategies of companies differ in the subsectors. For instance, the chilled food sector has higher willingness to share time-temperature information than the frozen food sector.     

Performance analysis and temperature gradient of solid oxide fuel cell stacks operated with bio-oil sorption-enhanced steam reforming

A high temperature gradient within a solid oxide fuel cell (SOFC) stack is considered a major challenge in SOFC operations. This study investigates the effects of the key parameters on SOFC system efficiency and temperature gradient within a SOFC stack. A 40-cell SOFC stack integrated with a bio-oil sorption-enhanced steam reformer is simulated using MATLAB and DETCHEM. When the air-to-fuel ratio and steam-to-fuel ratio increase, the stack average temperature and temperature gradient decrease. However, a decrease in the stack temperature steadily reduces the system efficiency owing to the tradeoff between the stack performance and thermal balance between heat recovered and consumed by the system. With an increase in the bio-oil flow rate, the system efficiency decreases because of the lower resident time for the electrochemical reaction. This is not, however, beneficial to the maximum temperature gradient. To minimize the temperature gradient of the SOFC stack, a decrease in the bio-oil flow rate is the most effective way. The maximum temperature gradient can be reduced to 14.6 K cm⁻¹ with the stack and system efficiency of 76.58 and 65.18%, respectively, when the SOFC system is operated at an air-to-fuel ratio of 8, steam-to-fuel ratio of 6, and bio-oil flow rate of 0.0041 mol s⁻¹.     

Stress-controlled direct shear testing of geosynthetic clay liners II: Assessment of shear behavior

This paper is the second of a two-paper set on stress-controlled direct shear testing of geosynthetic clay liners (GCLs). Design of the apparatus, preliminary experiments, and shear deformation mechanisms in heat-treated and non-heat treated needle-punched (NP) GCLs were discussed in Part I. The objective of Part II (this paper) was to evaluate the effects of physical factors (i.e., peel strength and initial normal stress, σ_ni), environmental factors (i.e., temperature and hydration solution), and creep on the internal shear behavior of NP GCLs. In addition, failure conditions of GCLs in the stress-controlled direct shear tests were compared to displacement-controlled direct shear tests to verify results. An increase in internal shear strength developed from increased GCL peel strength or increased normal stress. Elevated temperatures were observed to decrease internal shear strength for both non-heat treated and heat-treated NP GCLs. Specimens hydrated with a calcium-rich synthetic mining solution experienced increased internal shear strength due to cation exchange in the bentonite, whereas specimens hydrated with a highly alkaline synthetic mining solution experienced decreased internal shear strength. Creep tests revealed an increase in time-to-failure with decrease in applied shear stress. Finally, stress states at failure from stress-controlled and displacement-controlled shear tests corresponded to a unique failure envelope, which validates the efficacy of using stress-controlled direct shear tests to assess internal shear behavior and shear strength of NP GCLs.     

Thermally-induced phase transformations in KNNS-BNKZ lead-free piezoceramics

Promising piezoelectric properties have been reported in potassium sodium niobate-based ceramics by introducing Bi_0.5(Na_0.82K_0.18)_0.5ZrO₃ (BNKZ) into K_0.48Na_0.52Nb_0.95Sb_0.05O₃ (KNNS) solid solutions in order to control the polymorphic phase transformation temperatures. In the present study, synchrotron x-ray powder diffraction (SXPD) was employed in combination with dielectric and ferroelectric measurements in order to clarify the influence of BNKZ on the phase transition temperatures of (1-x)KNNS-(x)BNKZ ceramics (with x = 0 to 0.05). The results, presented in terms of temperature-dependent SXPD patterns, dielectric permittivity and thermal depolarisation characteristics, confirmed that polymorphic phase transformation temperatures all shifted in a systematic manner with increasing BNKZ content. Broadening of the phase transition regions was also observed with increasing BNKZ content, leading to improvements in thermal stability of the ferroelectric properties. Microstructural examination of the KNNS-BNKZ ceramics revealed the presence of core-shell microstructures; this was correlated with the presence of weak shoulders on the diffraction peaks.     

柱状晶Cu-Al-Be形状记忆合金低温压缩性能研究

利用竖直下拉式热型连铸技术制备柱状晶Cu-Al-Be形状记忆合金,其马氏体相变结束温度(Mf)在-50℃以下,柱状晶生长方向为轴向。在温度低于Mf时,对普通多晶、平行于柱状晶方向和垂直于柱状晶方向的试样分别进行单向压缩试验,并进行金相组织观察与断口形貌分析。结果发现,柱状晶Cu-Al-Be合金杆件组织结构为类似于贝壳的仿生结构且断裂形式相似,垂直于柱状晶方向的试样塑性最好,断裂前吸收能量最高,综合性能最好。