面向钢轨监测的无线传感器网络网关设计与性能测试

针对我国铁路钢轨实时广域监测的重大需求,通过研究异构无线传感器网络（WSNs）通信技术,设计并实现了一种基于Zig Bee-3G通信的无线传感器网络网关.进行了通信电路设计和电磁兼容设计,并在WinCE操作系统平台上实现了Zig Bee网络与3G网络之间的互联,开发了网关远程维护管理模块.对网关设备分别进行了网络传输性能测试和电磁兼容测试,测试结果表明：此网关传输效率高、抗电磁干扰能力强,能够满足铁路轨道监测现场的应用要求.     

相容剂对PE-HD／PET共混合金性能的影响

以乙烯-丙烯酸丁酯-甲基丙烯酸缩水甘油酯三元共聚物（PTW）作为高密度聚乙烯（PE-HD）／聚对苯二甲酸乙二醇酯（PET）共混合金的反应性相容剂，采用熔融挤出法制备了以PE-HD为基体的PE～Hi）／PET、共混合金。通过力学性能和流变性能测试，扫描电镜（SEM）和动态力学分析（DMA）等手段，研究丁PTW对共混合金性能的影响。结果表明：PTW提高了体系的综合性能，当PE-HD／PET配比为90／10，PTW含量在5份时，其缺口冲击强度提高了近400％，拉伸强度和断裂伸长率分别提高了25％和50％，同时改善了共混合金的加工性能。SEM分析表明PTW的加入增大了共混合金的界面相互作用，促进了分散相粒子的细化，从而提高丁体系相容性，DMA测试表明，PTW的加入使PET的玻璃化转变温度向PE—HD的玻璃化转变温度靠近：     

稀土顺丁橡胶／SBR体系的力学性能

稀土顺丁橡胶与丁苯橡胶（ＳＢＲ）共混，可以改善ＳＢＲ的耐低温性能。当稀土顺丁橡胶／ＳＢＲ（质量比）这２０／８０时，－３０℃的ｔａｎδ仅小于ＳＢＲ，６０℃的ｔａｎδ最小。其共混胶的应力－应变性能、湿滑指数、磨耗及生热性能均优于镍系顺丁橡胶／ＳＢＲ共混体系。     

Preparation of silk fibroin and polyallylamine composites

Composite films made of silk fibroin (SF) and polyallylamine (PAA) are prepared that contain various compositional ratios. These materials are analyzed to elucidate the resulting physical properties and to assess their potential toward advanced applications as industrial materials. The composite films are obtained from a SF and PAA binary system by dry casting from aqueous solution. These composite films exhibit excellent processability such as film forming capabilities, and the elongation at break is increased in the wet state. The differential scanning calorimetry (DSC) curves of the composites suggest that a mutual interaction takes place between the SF and PAA. This interaction is believed to occur because the endothermic peak, corresponding to the individual polymer, shifts with increasing SF content. The random coil conformation of the SF is present, regardless of the PAA blending, as confirmed by FTIR and DSC measurements. Additionally, living cells from Antheraea pernyi and Bombyx mori insect tissues are shown to grow effectively on the composite films. Maximum growth levels occur when the cultivation flask is coated with the material in SF/PAA ratios of 75:25 to 25:75. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 1963–1970, 2002; DOI 10.1002/app.10491     

Compatibility of polysaccharide/maleic copolymer blends. IV. Thermal behavior of hydroxypropyl cellulose‐containing blends

The compatibility of the hydroxypropyl cellulose (HPC) with maleic acid–vinyl acetate copolymer in the solid state was studied by thermogravimetry, thermo‐optical analysis, differential scanning calorimetry (DSC), Fourier transform infrared spectroscopy (FTIR), and optical microscopy. It was established that physical interactions are prevalent in blends with a high content of HPC, whereas chemical interactions predominate in blends with a medium and low content of HPC. By increasing the temperature, the thermochemical reactions are favored. Thermal properties are dependent on the mixing ratio of the components. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 2585–2597, 2003     

粘帚霉可湿性粉剂助剂的初步研究

可湿性粉剂是生物农药的重要剂型。通过平板培养法，测定菌落形成单位数（cfu值1，开展了可湿性粉剂多种常用助剂对高效生防真菌粉红粘帚霉67．1菌株孢子的生物学相容性研究。所试载体中，滑石粉等4种处理与对照没有显著性的差异，对粘帚霉孢子活力影响不明显；所试润湿分散剂中，木质素磺酸钙与对照没有显著性差异，对粘帚霉孢子活力影响不明显；所试紫外保护剂均对孢子活力无显著影响，但在紫外灯照射3min的条件下，只有腐植酸和糊精能有效保护孢子活力；常用稳定剂CMC—Na（羧甲基纤维素钠）对孢子活力无影响。上述多种与粘帚霉孢子具良好生物学相容性助剂的确定，为粘帚霉可湿性粉剂的研究提供重要依据。     

聚酰胺共混物的结构与性能

就近年来国内聚酰胺共混物的形态结构、相容性、流变行为、力学性质四方面的研究进展作一综述。     

Viscoelastic Behavior, Thermodynamic Compatibility, and Phase Equilibria in Block Copolymer-Based Pressure-Sensitive Adhesives

The viscoelastic behavior, thermodynamic compatibility, and phase equilibria in block copolymer-based pressure-sensitive adhesives were investigated. The block copolymers investigated were: (1) polystyrene-block-polybutadiene-block-polystyrene (SBS) copolymer (KRATON® D-1102, Shell Development Company) and (2) polystyrene-block-polyisoprene-block-polystyrene (SIS) copolymer (KRATON® D-1107, Shell Development Company). The tackifying resins investigated were: (1) WINGTACK® 86 (Goodyear Tire & Rubber Company) and (2) PICCOTAC® 95BHT (Hercules Inc.). Samples of various compositions were prepared by a solution-casting method with toluene as solvent. Measurements of dynamic storage modulus (G'), dynamic loss modulus (G'), and loss tangent (tan δ) were taken, using a Rheometrics Mechanical Spectrometer. It was found that: (1) both WINGTACK 86 and PICCOTAC 95BHT were equally effective in decreasing the plateau modulus (G^O_N), and increasing the glass transition temperature (T_g) of the polyisoprene midblock of KRATON 1107; and (2) WINGTACK 86 was very effective in decreasing the G^O_N and increasing the T_g of the polybutadiene midblock of KRATON 1102, whereas PICCOTAC 95BHT was not. The observed difference between WINGTACK 86 and PICCOTAC 95BHT in decreasing the G^O_N and increasing the T_g of the polybutadiene midblock of KRATON 1102, whereas PICCOTAC 95BHT was not. The observed difference between WINGTACK 86 and PICCOTAC 95BHT in decreasing the G^O_N and increasing the T_g of the polybutadiene midblock of KRATON 1102 (perhaps to SBS block copolymers in general) is explained by the values of the interaction parameter for WINGTACK 86 and KRATON 1102, and for PICCOTAC 95BHT and KRATON 1102. The interaction parameter was determined, using the piezoelectric quartz sorption method. Phase diagrams were constructed for the four block copolymer/tackifying resin systems investigated, using information obtained from both dynamic viscoelastic measurements and optical microscopy. It was found that when mixed with KRATON 1102, PICCOTAC 95BHT formed separate domains whereas WINGTACK 86 did not over the range of concentrations and temperatures investigated. This confirms the evidence obtained from two other independent experimental techniques, namely, dynamic viscoelastic measurements and the piezo-electric sorption method. We have concluded from the present study that PICCOTAC 95BHT is not as an effective tackifying resin as WINGTACK 86, when each is mixed with KRATON 1102. It is pointed out further that information on the order-disorder transition temperature T_r, which was determined from a rheological technique proposed by us, is valuable in determining optimal processing conditions for block copolymer-based pressure-sensitive adhesives.     

铸膜液结构对PVC/PMMA合金微滤膜性能的影响

通过高分子合金化,以L-S相转化法制备了PVC/PMMA非对称型合金微滤膜,考察了铸膜液结构对微滤膜结构与性能的影响.结果表明:随聚合物浓度、铸膜液温度升高合金膜水通量降低,平均孔径减小;增大PMMA含量,水通量上升,平均孔径增大;随添加剂量的增加,合金膜水通量上升,平均孔径减小.     

Marsh筒法量化评价水泥与减水剂流变学相容性的探讨

从流变学角度阐述了Marsh筒试验参数的物理意义,并提出用5min流动性能系数K1、λmin（λ〉5）流动性能系数K2、流动性能经时损失系数K3及流变学相容性指数α来定量评价水泥与减水剂相容性的优劣。