花簇状ZnS:Mn微球的制备及荧光性能研究

采用CTAB辅助溶剂热法合成出花簇状结构的ZnS:Mn微球,并研究了反应温度,时间,溶剂,CTAB用量对样品形貌的影响.结果表明在170℃时加入0.8g CTAB溶剂热反应12h,所获得样品形貌规整,尺寸较均一;此外在反应体系中加入油酸获得尺寸更小的花簇状ZnS:Mn.并对花簇状结构的生长机制进行了阐述.     

溶胶凝胶法制备的Mn,Li共掺ZnO粉晶性能研究

利用溶胶-凝胶法合成了名义组分Zn0.993-xMn0.007LixO(x=0,0.005,0.02)粉晶,分别采用SEM,EDX,XPS,XRD,UV-VIS和VSM对样品的形貌、成分、晶体结构、光学特性和磁性进行了研究。结果表明:Li的引入明显提高了Zn0.993Mn0.007O的室温磁化强度。当x=0.005时,Li以间隙原子的形式进入ZnO晶格,结晶性能下降,磁化强度的提高归因于ZnO晶格间隙电子掺杂和缺陷,使Mn2+-Mn2+间接铁磁性交换耦合增强;当x=0.02时,Li以替代原子形式进入ZnO晶格,相对于x=0.005其结晶性能提高,磁化强度的提高归因于ZnO中空穴载流子的增加,空穴载流子来自于Li+的受主作用。     

Shape memory effect in Fe-Mn-Ni-Si-C alloys with low Mn contents

An attempt was made to develop a new Fe-Mn-Si-based shape memory alloy from a Fe-17Mn-6Si-0.3C (mass%) shape memory alloy, which was previously reported to show a superior shape memory effect without any costly training treatment, by lowering its Mn content. The shape memory effect and the phase transformation behavior were investigated for the as-solution treated Fe-(17-2x)Mn-6Si-0.3C-xNi (x = 0, 1, 2, 3, 4) polycrystalline alloys. The shape recovery strain exceeded 2% in the alloys with x = 0-2, which is sufficient for an industrially applicable shape memory effect; however, it suddenly decreased in the alloys between x = 2 and 3 although the significant shape recovery strain still exceeded 1%. In the alloys with x = 3 and 4, X-ray diffraction analysis and transmission electron microscope observation revealed the existence of α′ martensite, which forms at the intersection of the ? martensite plates and suppresses the crystallographic reversibility of the γ austenite to ? martensitic transformation.     

30Cr3Si2Mn2NiNb钢中未溶相的热力学计算及分析

采用Thermo-Calc热力学软件模拟了30Cr3Si2Mn2NiNb钢奥氏体化时平衡相的演化规律以及非平衡态相的演化规律,研究了合金元素C,Mo,Nb和V对实验钢中未溶相的影响.通过SEM,XRD对30Cr3Si2Mn2NiNb钢淬火态组织进行实验观察及分析.结果表明:常规奥氏体化处理后,钢中未溶相主要有富Nb的M...     

核壳结构CdS：Mn/ZnS纳米晶的制备与光学性能研究

以3-巯基丙酸为稳定剂,采用共沉淀法在水相中合成了CdS∶Mn掺杂纳米晶,然后进一步将ZnS包覆于CdS∶Mn纳米晶表面,制备了CdS∶Mn/ZnS核壳结构纳米晶。利用X射线衍射（XRD）,透射电子显微镜（TEM）和紫外-可见吸收光谱（UV-Vis）对纳米晶的结构、形貌和光学性质进行了表征,发现制备的纳米晶具有优秀的单分散性,确认合成了CdS∶Mn/ZnS核壳结构纳米晶。通过荧光光谱（PL）研究了纳米晶的发光性质和光稳定性,结果表明包覆壳层后纳米晶的发光强度显著提高,最高可达8倍,且Mn2＋离子的发光峰峰位置随着ZnS壳层数的增加而红移。此外,核壳纳米晶的光稳定性大大提高。     

Flow stress and dynamic recrystallization behavior of Al-9Mg-1.1Li-0.5Mn alloy during hot compression process

The flow stress behavior of spray-formed Al-9Mg-1.1Li-0.5Mn alloy was studied using thermal simulation tests on a Gleeble-3500 machine over deformation temperature range of 300-450 °C and strain rate of 0.01-10 s^?1. The microstructural evolution of the alloy during the hot compression process was characterized by transmission electron microscopy (TEM) and electron back scatter diffractometry (EBSD). The results show that the flow stress behavior and microstructural evolution are sensitive to deformation parameters. The peak stress level, steady flow stress, dislocation density and amount of substructures of the alloy increase with decreasing deformation temperature and increasing strain rate. Conversely, the high angle grain boundary area increases, the grain boundary is in serrated shape and the dynamic recrystallization in the alloy occurs. The microstructure of the alloy is fibrous-like and the main softening mechanism is dynamic recovery during steady deformation state. The flow stress behavior can be represented by the Zener-Hollomon parameter Z in the hyperbolic sine equation with the hot deformation activation energy of 184.2538 kJ/mol. The constitutive equation and the hot processing map were established. The hot processing map exhibits that the optimum processing conditions for Al-9Mg-1.1Li-0.5Mn alloy are in deformation temperature range from 380 to 450 °C and strain rate range from 0.01 to 0.1 s^?1.     

Effect of enhanced interfacial reaction on the microstructure,phase transformation and mechanical property of Ni–Mn–Ga particles/Mg composites

This study investigated the microstructure, phase transformation and mechanical property of Ni–Mn–Ga particles/Mg composites with a strong interfacial reaction between the particles and the matrix. The strong interfacial reaction was related to the large surface area and energy per unit volume of the flaky shape Ni–Mn–Ga particles that favors the reaction between the particles and matrix. The martensitic transformation behavior was largely weakened due to the interfacial reactions and thus the reduced volume fraction of Ni–Mn–Ga particles. The composites exhibited a much improved compressive strength and ductility in comparison with that of the Ni–Mn–Ga alloy. The compressive plasticity of the composites was decreased when the Ni–Mn–Ga particle content exceeded 40 wt%. In comparison with the Mg-composites with large size Ni–Mn–Ga particles, the composites with small size particles would have a much stronger interfacial reactions, which was detrimental to the phase transformation and mechanical ductility of the composites. The investigation results in this article could provide a reference for the design and preparation of the particles reinforced metal matrix functional composites.     

16Mn钢长轴裂纹缺陷成因分析

某16Mn钢长轴零件经超声波探伤发现存在缺陷,采用化学成分分析、低倍检验、金相检验、断口分析等方法对缺陷的类型和成因进行了分析。结果表明:该零件原材料中存在的非金属夹杂形成了裂纹源,在加工压力的作用下进一步扩展,最终形成了裂纹缺陷。     

不同pH的碱性环境中16Mn钢及热影响区应力腐蚀行为

利用电化学技术和U形弯试样浸泡实验研究了16Mn钢及其模拟热影响区(HAZ)在不同pH的碱性硫化物和Cl-介质中的应力腐蚀开裂(SCC)行为与机理.结果表明:16Mn钢原始组织、粗晶组织(空冷组织)和硬化组织(淬火组织)在pH为11.8的碱性硫化物环境中均近似呈钝化状态,维钝电流密度依次降低;随着pH的降低,原始组织和粗晶组织的阳极过程逐渐由钝化态转变为活化态;HAZ中硬化组织、粗晶组织和原始组织在碱性硫化物环境下的SCC敏感性依次降低,其中硬化组织具有明显的SCC特征;随着pH的降低,SCC裂纹有从沿晶裂纹转变为穿晶和沿晶混合裂纹的趋势,并且裂纹的宽度增加.     

TiO2/Mn2O3复合纳米纤维的制备及光吸收性能研究

以聚乙烯吡咯烷酮(PVP)为络合剂,与钛酸四正丁酯 Ti(C4H9O)4]和醋酸锰(Mn(CH3COO)2·4H2O)反应制得前驱体溶液,用静电纺丝法制备PVP/TiO2/Mn2O3纳米复合纤维,在马弗炉中经过煅烧处理过程,获得了TiO2/Mn2O3纳米纤维.采用扫描电镜(SEM)、热分析仪(TG-DTA)、X射线衍射...