全文获取类型
收费全文 | 22711篇 |
免费 | 2437篇 |
国内免费 | 1053篇 |
专业分类
电工技术 | 7692篇 |
综合类 | 2043篇 |
化学工业 | 918篇 |
金属工艺 | 681篇 |
机械仪表 | 1373篇 |
建筑科学 | 325篇 |
矿业工程 | 534篇 |
能源动力 | 488篇 |
轻工业 | 444篇 |
水利工程 | 146篇 |
石油天然气 | 217篇 |
武器工业 | 207篇 |
无线电 | 7007篇 |
一般工业技术 | 949篇 |
冶金工业 | 372篇 |
原子能技术 | 252篇 |
自动化技术 | 2553篇 |
出版年
2024年 | 46篇 |
2023年 | 298篇 |
2022年 | 377篇 |
2021年 | 540篇 |
2020年 | 556篇 |
2019年 | 441篇 |
2018年 | 388篇 |
2017年 | 618篇 |
2016年 | 759篇 |
2015年 | 838篇 |
2014年 | 1429篇 |
2013年 | 1156篇 |
2012年 | 1698篇 |
2011年 | 1849篇 |
2010年 | 1405篇 |
2009年 | 1407篇 |
2008年 | 1456篇 |
2007年 | 1731篇 |
2006年 | 1552篇 |
2005年 | 1261篇 |
2004年 | 1138篇 |
2003年 | 962篇 |
2002年 | 759篇 |
2001年 | 671篇 |
2000年 | 560篇 |
1999年 | 410篇 |
1998年 | 286篇 |
1997年 | 278篇 |
1996年 | 270篇 |
1995年 | 212篇 |
1994年 | 207篇 |
1993年 | 138篇 |
1992年 | 124篇 |
1991年 | 90篇 |
1990年 | 65篇 |
1989年 | 67篇 |
1988年 | 65篇 |
1987年 | 23篇 |
1986年 | 14篇 |
1985年 | 14篇 |
1984年 | 16篇 |
1983年 | 7篇 |
1982年 | 4篇 |
1981年 | 3篇 |
1980年 | 2篇 |
1979年 | 2篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1956年 | 1篇 |
1951年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
1.
K. Naveen Kumar L. Vijayalakshmi Hyeongyu Bae Kang Taek Lee Pyung Hwang Jungwook Choi 《Ceramics International》2021,47(4):4563-4571
Yb3+/Er3+codoped La10W22O81 (LWO) nanophosphor rods have been successfully synthesized by a facile hydrothermal assisted solid state reaction method, and their upconversion photoluminescence properties were systematically studied. X-ray diffraction patterns revealed that the nanophosphors have an orthorhombic structure with space group Pbcn (60). A microflowers-like morphology with irregular hexagonal nanorods was observed using field emission scanning electron microscopy for the Yb3+(2 mol%)/Er3+(2 mol%):LWO nanophosphor. The shape and size of the nanophosphor and the elements along with their ionic states in the material were confirmed by TEM and XPS studies, respectively. A green upconversion emission was observed in the Er3+: LWO nanophosphors under 980 nm laser excitation. A significant improvement in upconversion emission has been observed in the Er3+: LWO nanophosphors by increasing the Er3+ ion concentration. A decrease in the upconversion emission occurred due to concentration quenching when the doping concentration of Er3+ ions was greater than 2 mol%. An optimized Er3+(2 mol%): LWO nanophosphor exhibited a strong near infrared emission at 1.53 μm by 980 nm excitation. The green upconversion emission of Er3+(2 mol%): LWO was remarkably enhanced by co-doping with Yb3+ ions under 980 nm excitation because of energy transfer from Yb3+ to Er3+. The naked eye observed this upconversion emission when co-doping with 2 mol% Yb3+. In order to obtain the high upconversion green emission, the optimized sensitizer concentration of Yb3+ ions was found to be 2 mol%. The upconversion emission trends were studied as a function of stimulating laser power for an optimized sample. Moreover, the NIR emission intensity has also been enhanced by co-doping with Yb3+ ions due to energy transfer from Yb3+ to Er3+. The energy transfer dynamics were systematically elucidated by energy level scheme. Colorimetric coordinates were determined for Er3+ and Yb3+/Er3+: LWO nanophosphors. The energy transfer mechanism was well explained and substantiated by several fluorescence dynamics of upconversion emission spectra and CIE coordinates. The results demonstrated that the co-doped Yb3+(2 mol%)/Er3+(2 mol%): LWO nanophosphor material is found to be a suitable candidate for the novel upconversion photonic devices. 相似文献
2.
The substitution of coal blending with sawdust had been widely investigated for metallurgical coke production. In this paper, the physiochemical structures of the semicoke derived from sawdust/coals blends co-coking were characterized by several analytical techniques including FTIR-ATR, XPS, NMR, OM, and SEM. Meanwhile, the influence of the sawdust on the physicochemical properties of the sawdust/coals blends were also investigated. Results indicated that partial substitution of coal blending with sawdust benefited from the formation of colloid and optical anisotropy due to the positive synergetic effect, whereas high proportion of sawdust (>10 wt%) inhibited the agglomeration of semi-coke. On the other hand, the semicoke consisted primarily of aromatic carbons replaced by the oxygen linked to carbons and aliphatic carbons when the coal blending was replaced by high proportion of sawdust, causing a less polyaromatic graphite-like structure formation in the semicoke. 相似文献
3.
4.
SeyedHosein Payandeh Daniel Rentsch Zbigniew Łodziana Ryo Asakura Laurent Bigler Radovan Černý Corsin Battaglia Arndt Remhof 《Advanced functional materials》2021,31(18):2010046
Hydroborate-based solid electrolytes have recently been successfully employed in high voltage, room temperature all-solid-state sodium batteries. The transfer to analogous lithium systems has failed up to now due to the lower conductivity of the corresponding lithium compounds and their high cost. Here LiB11H14 nido-hydroborate as a cost-effective building block and its high-purity synthesis is introduced. The crystal structures of anhydrous LiB11H14 as well as of LiB11H14-based mixed-anion solid electrolytes are solved and high ionic conductivities of 1.1 × 10−4 S cm−1 for Li2(B11H14)(CB11H12) and 1.1 × 10−3 S cm−1 for Li3(B11H14)(CB9H10)2 are obtained, respectively. LiB11H14 exhibits an oxidative stability limit of 2.6 V versus Li+/Li and the proposed decomposition products are discussed based on density functional theory calculations. Strategies are discussed to improve the stability of these compounds by modifying the chemical structure of the nido-hydroborate cage. Galvanostatic cycling in symmetric cells with two lithium metal electrodes shows a small overpotential increase from 22.5 to 30 mV after 620 h (up to 0.5 mAh cm−2), demonstrating that the electrolyte is compatible with metallic anodes. Finally, the Li2(B11H14)(CB11H12) electrolyte is employed in a proof-of-concept half cell with a TiS2 cathode with a capacity retention of 82% after 150 cycles at C/5. 相似文献
5.
扶梯制动系统是扶梯在出现紧急状况下确保乘客安全的重要设施。制动系统中的安全制动是在工作制动器无法在规定的时间内制停扶梯的一个措施,往往是在一些特别危险的场合下被触发,因此对于此制动器的控制显得尤为重要。本文提出了一种新型的自动扶梯制动器电磁铁驱动电路的设计,该设计用纯电子线路替代了传统的电气与电子组合形式,直接由自动扶梯单片机控制单元进行控制。 相似文献
6.
The 3D structure electromagnetic computation presents several difficulties related to the volume mesh. In fact, the entire volume space must be taken into account even the smallest details. In this article, we propose a formulation based on the reciprocity theorem combined with the generalized equivalent circuit method to model a planar 3D structure with both coaxial and planar excitation. The major advantage of this formulation is the fact to reduce the computational volume into 2D ones in the discontinuity plane. In addition, we focused on the calculation of the discontinuity between the excitation source and the planar structure to determine the exact behavior of the electric coaxial excitation model. The obtained current density, electric field distributions, and the input impedance are presented and discussed in the following sections. An approximately good agreement of input impedance with those obtained by the simulator and measurement is shown. 相似文献
7.
8.
现有文献针对计及转子变流器(RSC)控制的双馈感应风电机组(DFIG)定子短路电流解析表达,将定子磁链当作一阶直流衰减分量或忽略功率外环控制。基于DFIG电压、磁链和RSC控制方程,得到定子电流关于定子电压和定子功率的传递函数,提出定子电流的精确解析表达式。基于RSC内、外环PI参数关系,推导直流分量衰减时间常数和角频率关于PI参数的表达式。分析了RSC内外环PI参数对定子电流直流衰减分量的影响。仿真结果验证了解析表达式的准确性,为PI参数选取和保护装置测量、整定提供依据。 相似文献
9.
10.
简要介绍了本安先导电路的判定及继电器隔离方式的本安先导电路原理,运用3种方法分析了矿井低压电网漏电故障,最后在此基础上,从组合开关对电压保护、短路保护和过载保护三个方面,详细探讨了基于组合开关的矿井低压电网保护,相信可以通过多方面的综合分析研究出更可靠、保护更加全面和智能的组合开关,从而为中国井下煤矿的安全机械化开采提供更有保障的服务。 相似文献