Compositional design,structure stability,and microwave dielectric properties in Ca3MgBGe3O12 (B = Zr,Sn) garnet ceramics with tetravalent cations on B-site

Two garnet-structured Ca₃MgBGe₃O₁₂ (B = Zr, Sn) ceramics with tetravalent cations at B-site were prepared by conventional solid state reaction. The crystal structure, microstructure evolution, and microwave dielectric performance were investigated using X-ray powder diffraction, Rietveld refinement, scanning electron microscopy, Raman spectroscopy, and infrared spectroscopy techniques. Dense Ca₃MgZrGe₃O₁₂ and Ca₃MgSnGe₃O₁₂ ceramics were obtained at sintering temperatures of 1420 and 1400 °C, respectively. The dielectric constant, unloaded quality factor, and temperature coefficient of resonance frequency of Ca₃MgZrGe₃O₁₂ were 10.80 ± 0.2; 79,600 ± 1000 GHz (f = 12.61 GHz); and ?66.8 ± 1 ppm/°C, respectively, and the corresponding values for Ca₃MgSnGe₃O₁₂ were 9.68 ± 0.2; 83,400 ± 1000 GHz (f = 14.19 GHz); and ?57.9 ± 1 ppm/°C, respectively. The dielectric performances of the two ceramics were compared by analyzing the ionic polarizability, packing fraction, and bond valence. The intrinsic dielectric properties were predicted by fitting the infrared reflectivity spectra.     

Static pentane extraction as a potential alternative to Soxhlet extraction for polypropylene olive oil overall migration limit measurements

Static pentane extraction of olive oil from polypropylene was evaluated as a safer, higher throughput alternative to pentane Soxhlet extraction for the recovery of olive oil from polypropylene for overall migration limit determinations. Static, ambient temperature, pentane extraction achieved quantitative recovery of olive oil from polypropylene plaques prepared by using the OM‐5 overall migration limit protocol. In addition to validation data for static extractions, a modified esterification procedure is presented as a means to accommodate the larger sample sets that are enabled with static extraction.     

Reference governors and maximal output admissible sets for linear periodic systems

ABSTRACT

In this paper, we consider the problem of constraint management in Linear Periodic (LP) systems using Reference Governors (RG). First, we introduce the periodic-invariant maximal output admissible sets for LP systems. We extend the earlier results in the literature to Lyapunov stable LP systems with output constraints, which arise in RG applications. We show that, while the invariant sets for these systems may not be finitely determined, a finitely-determined inner approximation, which is periodically invariant, can be obtained by constraint tightening. We then analyze the geometric and algebraic relationship between these sets and show that these sets are related via simple transformations, implying that it suffices to compute only one of them for real-time applications. This greatly reduces the memory burden of RG (or other similar constraint management strategies), at the expense of an increase in processing requirements. We present a thorough analysis of this trade-off. In the second part of this paper, we present two RG formulations, and discuss their properties and algorithms for their computation. Numerical simulations demonstrate the efficacy of the approach.     

基于滑模的运载器主动段俯仰通道姿控系统设计

与传统比例-积分-微分（PID）控制方法相比，滑模控制（SMC）方法可以比较容易地将不确定性纳入控制器设计中，从而增强系统的鲁棒性。探索了SMC技术在运载器主动段姿态控制中的工程应用，首先通过分析基于趋近律的SMC系统，提出了降低不连续切换项系数的需求，然后研究了基于干扰上界的SMC方法。三通道小偏差仿真结果验证了两种方法的控制效果，表明第2种控制器的鲁棒性更好，稳态误差小，同时发动机喷管摆角需求较小。     

The control of paracetamol particle size and surface morphology through crystallisation in a spray dryer

The parameters governing the crystallisation of paracetamol using various conventional techniques has been extensively studied, however the factors influencing the drug crystallisation using spray drying is not as well understood. The aim of this work was to investigate the crystallisation of an active pharmaceutical ingredient through evaporative crystallisation using a spray dryer to study the physicochemical properties of the drug and to use semi-empirical equations to gain insight into the morphology and particle size of the dried powder. Paracetamol solutions were spray dried at various inlet temperatures ranging from 60 °C to 120 °C and also from a series of inlet feed solvent compositions ranging from 50/50% v/v ethanol/water to 100% ethanol and solid-state characterisation was done. The size and morphology of the dried materials were altered with a change in spray drying parameters, with an increase in inlet temperature leading to an increase in particle Sauter mean diameter (from 3.0 to 4.4 µm) and a decrease in the particle size with an increase in ethanol concentration in the feed (from 4.6 to 4.4 µm) as a result of changes in particle density and atomised droplet size. The morphology of the dried particles consisted of agglomerates of individual crystallites bound together into larger semi-spherical agglomerates with a higher tendency for particles having crystalline ridges to form at higher ethanol concentrations of the feed.     

New empirical correlation for estimation of vaporization enthalpy of algerian saharan blend petroleum fractions

A Real-coded Genetic Algorithm has been used to develop a new correlation to estimate the enthalpy of vaporization for pure compounds and petroleum fractions as a function of the normal boiling point and specific gravity. In developing the correlation 80% of the data was used and the remaining are used for validation. The results of the proposed correlations are compared to others in literature. The comparison indicates that the proposed model is simple to use and more accurate than the most common correlations for predicting the enthalpy of vaporization of pure compounds and petroleum fractions.     

Examining the role of regional culture and geographical distances on the representation of unfamiliar foods in a continental-size country

This study provides an experimental-exploratory investigation about the role of regional culture and Euclidean distances on the consumers’ representation of edible insects in Brazil, a country with an extensive geographical surface. Seven hundred and eighty participants were recruited on the streets of eight cities from different Brazilian states: Manaus in Amazonas; Porto Velho in Rondônia; Macapá in Amapá; Cuiabá in Mato Grosso; Aracaju in Sergipe; Rio de Janeiro in Rio de Janeiro; Campinas in São Paulo; and Santa Maria in Rio Grande do Sul. These participating cities were considered from their cultural identity differences and geographical distances. Through a continual restricted word association task, participants were instructed to promptly verbalize the first five terms that came to their minds when stimulated with the expression “food made with edible insects”. Following, they had to score the valence of each term they produced. The dictionaries produced in each city were compared and classified into groups using the Ellegård’s index. Each group presented distinct ways of expression and attitude with respect to the inductive expression. Basically, Brazil was divided into two main groups according to their representation of edible insects: one consisted by the cities situated near the shore of the Atlantic Ocean, which present a cultural formation influenced by the European immigrants; and the other comprised the cities from the continental region that have strong cultural influence from the Amerindians. Thus, the cultural formation was more decisive to explain the similar representations among the cities than their geographical proximity. Given that, to effectively introduce a novel food in a country with varied regional culture, the marketing strategy should be focused on the values and beliefs of their culture subgroups instead of a single strategy for the whole country.     

铝合金三角形波纹夹芯板对平头弹抗冲击特性数值模拟研究

为研究铝合金三角形波纹夹芯板对平头弹体的抗冲击性能及损伤特性，利用有限元软件ABAQUS/Explicit建立弹体冲击靶板的数值模拟模型，并结合实验验证了模型及其参数的有效性。基于数值计算结果，分析了三角形波纹夹芯板几何结构对其防护性能、失效模式和能量吸收的影响规律及机理，并与等面密度单层板进行对比分析，研究结果表明，靶体几何结构对其抗冲击性能存在影响，三角形波纹夹芯板抗冲击性能低于单层板抗冲击性能。此外，增加芯体拓扑结构夹角能显著提高三角形波纹夹芯板的抗冲击性能，并且靶板几何形状会对其失效模式及耗能特性存在影响。     

A priori risk-informed approach to ensure the compliance with discharge limits for liquid radioactive effluent to be discharged from APR 1400

ABSTRACT

In order to develop a methodology to guarantee the conformance to operational discharge limits for liquid effluent from a NPP at an early stage of design, a risk-informed approach was proposed and its applicability was verified for APR 1400. Existing methodology to calculate risk-based detection limit for a single radionuclide was improved by incorporating a new model to derive more realistic pathway dose factors. A new simple expression was also proposed to adjust risk-based detection limits for multiple radionuclides mixture if necessary. In addition, a new procedure to warrant the compliance with discharge limits by controlling detection limits of only a few principal radionuclides was established in accordance with risk-informed concept. Through case studies for APR 1400 to be commissioned at a hypothetical site, it was shown that calculated pathway dose factors are more realistic for majority of radionuclides. It also turns out that neither present detection limits nor unadjusted risk-based detection limits can be justified when the radionuclide composition is unknown, however further adjustment of detection limits or increasing additional dilution factor resolves the problem. Finally, ten principal radionuclides were identified and shown to be enough for liquid effluent control at APR 1400 from a risk-informed point of view.