Fluid sloshing thermo-mechanical characteristic in a cryogenic fuel storage tank under different gravity acceleration levels

Fluid sloshing usually causes serious safety issues on the dynamic stability and propellant thermal management during the powered-flight phase of launch vehicle. With the wide using of cryogenic propellants, the coupled thermo-mechanical performance during fluid sloshing becomes more prominent. In the present study, one numerical model is established to simulate fluid sloshing by using the VOF method coupled with the mesh motion treatment. The phase change occurring within the tank is considered. Both the experimental validation and mesh sensitivity analysis are made. It shows that present numerical model is acceptable. Based on the developed numerical model, the effect of different super gravity accelerations on fluid sloshing hydrodynamic characteristic is numerically researched. The fluid pressure variation, the sloshing force and sloshing moment, the interface dynamic response and the interface shape variation are investigated, respectively. It shows that the gravity acceleration has caused obvious influences on fluid sloshing characteristic. When the gravity acceleration is higher than 4g₀, fluid sloshing becomes more obvious and must be paid enough attention. With some valuable conclusions obtained, the present work is of great significance for in-depth understanding of fluid sloshing mechanism.     

Behavior of phase transformation of Baotou mixed rare earth concentrate during oxidation roasting

Based on the new process named “Combination Method” for metallurgy and separation of Baotou mixed rare earth concentrate (BMREC), the aim of this paper is to clearly elucidate the phase change behavior of BMREC without additives during oxidative roasting at 450–800 °C. The results indicate that the bastnaesite in BMREC is decomposed at 450–550 °C, the weight loss is about 10.3 wt%, and the activation energy (E) is 144 kJ/mol. The bastnaesite in BMREC is decomposed into rare earth fluoride, rare earth oxides (La₂O₃, Ce₇O₁₂, Pr₆O₁₁ and Nd₂O₃), and CO₂, particularly, with the increase of roasting temperature, bastnaesite in BMREC is more completely decomposed into LaF₃, which causes a decrease in leaching rate of La during the HCl leaching process. Additionally, the maximum cerium oxidation efficiency reaches about 60 wt% when the roasting temperature is equal to or above 500 °C, and the oxidation reaction rate of cerium increases with the increasing roasting temperature.     

Influence of temperature on acoustic emission source location accuracy in underground structure

An acoustic emission (AE) experiment was carried out to explore the AE location accuracy influenced by temperature. A hollow hemispherical specimen was used to simulate common underground structures. In the process of heating with the flame, the pulse signal of constant frequency was stimulated as an AE source. Then AE signals received by each sensor were collected and used for comparing localization accuracy at different temperatures. Results show that location errors of AE keep the same phenomenon in the early and middle heating stages. In the later stage of heating, location errors of AE increase sharply due to the appearance of cracks. This provides some beneficial suggestions on decreasing location errors of structural cracks caused by temperature and improves the ability of underground structure disaster prevention and control.     

Three distinct optical-switching states in phase-change materials containing impurities:From physical origin to material design

Ge2Sb2Tes is the most widely utilized chalcogenide phase-change material for non-volatile photonic applications,which undergoes amorphous-cubic and cubic-hexagonal phase transition under external excitations.However,the cubic-hexagonal optical contrast is negligible,only the amorphous-cubic phase transition of Ge2Sb2Te5 is available.This limits the optical switching states of traditional active dis-plays and absorbers to two.We find that increasing structural disorder difference of cubic-hexagonal can increase optical contrast close to the level of amorphous-cubic.Therefore,an amorphous-cubic-hexagonal phase transition with high optical contrast is realized.Using this phase transition,we have developed display and absorber with three distinct switching states,improving the switching perfor-mance by 50％.Through the combination of first-principle calculations and experiments,we reveal that the key to increasing structural disorder difference of amorphous,cubic and hexagonal phases is to intro-duce small interstitial impurities(like N)in Ge2Sb2Tes,rather than large substitutional impurities(like Ag)previously thought.This is explained by the formation energy and lattice distortion.Based on the impurity atomic radius,interstitial site radius and formation energy,C and B are also potential suit-able impurities.In addition,introducing interstitial impurities into phase-change materials with van der Waals gaps in stable phase such as GeSb4Te7,GeSb2Te4,Ge3Sb2Te6,Sb2Te3 will produce high optical con-trast amorphous-metastable-stable phase transition.This research not only reveals the important role of interstitial impurities in increasing the optical contrast between metastable-stable phases,but also proposes varieties of candidate matrices and impurities.This provides new phase-change materials and design methods for non-volatile optical devices with multi-switching states.     

High-Throughput Screening for Phase-Change Memory Materials

Phase change memory (PCM) is an emerging non-volatile data storage technology concerned by the semiconductor industry. To improve the performances, previous efforts have mainly focused on partially replacing or doping elements in the flagship Ge-Sb-Te (GST) alloy based on experimental “trial-and-error” methods. Here, the current largest scale PCM materials searching is reported, starting with 124 515 candidate materials, using a rational high-throughput screening strategy consisting of criteria related to PCM characteristics. In the results, there are 158 candidates screened for PCM materials, of which ≈68% are not employed. By further analyses, including cohesive energy, bond angle analyses, and Born effective charge, there are 52 materials with properties similar to the GST system, including Ge₂Bi₂Te₅, GeAs₄Te₇, GeAs₂Te₄, so on and other candidates that have not been reported, such as TlBiTe₂, TlSbTe₂, CdPb₃Se₄, etc. Compared with GST, materials with close cohesive energy include AgBiTe₂, TlSbTe₂, As₂Te₃, TlBiTe₂, etc., indicating possible low power consumption. Through further melt-quenching molecular dynamic calculation and structural/electronic analyses, Ge₂Bi₂Te₅, CdPb₃Se₄, MnBi₂Te₄, and TlBiTe₂ are found suitable for optical/electrical PCM applications, which further verifies the effectiveness of this strategy. The present study will accelerate the exploration and development of advanced PCM materials for current and future big-data applications.     

Genome-Wide Analyses of the Temperature-Responsive Genetic Loci of the Pectinolytic Plant Pathogenic Pectobacterium atrosepticum

Temperature is one of the critical factors affecting gene expression in bacteria. Despite the general interest in the link between bacterial phenotypes and environmental temperature, little is known about temperature-dependent gene expression in plant pathogenic Pectobacterium atrosepticum, a causative agent of potato blackleg and tuber soft rot worldwide. In this study, twenty-nine P. atrosepticum SCRI1043 thermoregulated genes were identified using Tn5-based transposon mutagenesis coupled with an inducible promotorless gusA gene as a reporter. From the pool of 29 genes, 14 were up-regulated at 18 °C, whereas 15 other genes were up-regulated at 28 °C. Among the thermoregulated loci, genes involved in primary bacterial metabolism, membrane-related proteins, fitness-corresponding factors, and several hypothetical proteins were found. The Tn5 mutants were tested for their pathogenicity in planta and for features that are likely to remain important for the pathogen to succeed in the (plant) environment. Five Tn5 mutants expressed visible phenotypes differentiating these mutants from the phenotype of the SCRI1043 wild-type strain. The gene disruptions in the Tn5 transposon mutants caused alterations in bacterial generation time, ability to form a biofilm, production of lipopolysaccharides, and virulence on potato tuber slices. The consequences of environmental temperature on the ability of P. atrosepticum to cause disease symptoms in potato are discussed.     

Facile self-assembly approach to construct a novel MXene-decorated nano-sized phase change material emulsion for thermal energy storage

In recent years, phase change material emulsions (PCMEs) with enhanced energy storage capacities and good flow characteristics have drawn significant attention. However, due to the thermodynamically unstable nature and tiny particle confinement, the nanomaterial modification strategies at PCM/water interface to improve stabilities and reduce supercooling of nano-sized PCMEs (NPCMEs) are very limited and challenging. Herein, we report a facile strategy for constructing MXene-decorated NPCME with good stability, little supercooling, and high thermal conductivity by self-assembly of MXene nanosheets at PCM/water interface. The concentrations of MXene have great influences on the average droplet diameters, stabilities, and thermophysical properties of the NPCMEs. The results show that the PCMs have been well dispersed into the water in the form of quasi-spherical droplets, with average droplet diameters of 242–805 nm. The thermal conductivity of 10 wt% n-tetradecane/water NPCME containing 9 mg ml^-1 MXene is 0.693 W m^-1·K^-1, achieving an enhancement by 15.5%, as compared to that of water. Besides, the MXene-decorated paraffin/water NPCMEs exhibit little supercooling and enhanced heat storage capacities. More importantly, this facile self-assembly strategy opens a new platform for preparing high-performance NPCMEs, which can be used as novel heat transfer fluids for thermal energy storage systems.     

基于双声表面波器件的引信加速度传感器

In view of the shortcomings of silicon micro acceleration sensor based on piezoresistive effect and capacitance principle, such as temperature drift, low resolution and poor anti-interference ability, a fuze acceleration sensor based on dual SAW devices is proposed. The sensor adopts a dual saw device structure, one is coated with a sensitive film for measurement, the other is an uncoat- ed reference channel for compensation of environmental temperature, pressure, humidity and other factors. The experimental results show that the maximum linear error is only 1.6%, the sensitivity is 54.3Hz/g, and the maximum hysteresis error is less than 1%. Compared with piezoresistive accelerometer and capacitive accelerometer, the linear error of the accelerometer is small, the sensitivi- ty is high, and it has strong anti-interference ability.     

Experimental Study on Hybrid Organic Phase Change Materials Used for Solar Energy Storage

The solar energy utilization in built environment has been limited due to its low heat flux, uneven distribution in time and space and temporal difference in day and night. The phase change materials have been used to collect the fluctuant solar energy to form a stable energy source for the terminal equipment of the buildings. In this study, the hybrid organic phase change materials was prepared for the capillary radiant heating system which formed a cascade utilization of solar energy. Firstly, lauric acid and stearic acid were selected as the basic organic phase change materials and the binary equilibrium phase diagram was completed based on the method of step cooling curve according to the experimental tests data. The results showed that the phase transition temperature of the mixed acid at the lowest eutectic point was 31.2℃ and the latent heat value was 264.3 kJ/kg when the mass mixing ratio was 70% for lauric acid and 30% for stearic acid. Secondly, the expanded graphite was used as an additive to enwrap the mixed acid and enhance the heat conductivity. The experimental results showed that when the mass proportion of expanded graphite in the mixed acid was 10%, the mixed acid could be completely enclosed by expanded graphite and the stability of melting and solidification was optimal. Additionally, the phase transition temperature of the hybrid phase change material was 31.5℃ and the latent heat value was 217.4 kJ/kg. The novel hybrid phase change material has a lower eutectic point and a higher latent heat of phase change, so it has a large application space and is quite suitable for the cascade utilization of solar energy with capillary network heating system.     

Experimental Investigation of Heat Storage and Heat Transfer Rates during Melting of Nano-Enhanced Phase Change Materials (NePCM) in a Differentially-Heated Rectangular Cavity

In this work, an experimental study of melting heat transfer of nano-enhanced phase change materials(NePCM) in a differentially-heated rectangular cavity was performed. Two height-to-width aspect ratios of the cavity, i.e., 0.9 and 1.5, were investigated. The model Ne PCM samples were prepared by dispersing graphene nanoplatelets(GNP) into 1-tetradecanol, having a nominal melting point of 37℃, at loadings up to 3 wt.%. The viscosity was found to have a more than 10-fold increase at the highest loading of GNP. During the melting experiments, the wall superheat at the heating boundary was set to be 10℃ or 30℃. It was shown that with increasing the loading of GNP, both the heat storage and heat transfer rates during melting decelerate to some extent, at all geometrical and thermal configurations. This suggested that the use of NePCM in such cavity may not be able to enhance the heat storage rate due to the dramatic growth in viscosity, which deteriorates significantly natural convective heat transfer during melting to overweigh the enhanced heat conduction by only a decent increase in thermal conductivity. This also suggested that the numerically predicted melting accelerations and heat transfer enhancements, as a result of the increased thermal conductivity, in the literature are likely overestimated because the negative effects due to viscosity growth are underestimated.