Nanolayer CrAlN/TiSiN coating designed for tribological applications

With the goal to produce a hard and tough coating intended for tribological applications, CrAlN/TiSiN nanolayer coating was prepared by alternative deposition of CrAlN and TiSiN layers. In the first part of the article, a detailed study of phase composition, microstructure, and layer structure of CrAlN/TiSiN coating is presented. In the second part, its mechanical properties, fracture and tribological behavior are compared to the nanocomposite TiSiN coating. An industrial magnetron sputtering unit was used for coating deposition. X-ray photoelectron spectroscopy, energy dispersive X-ray spectroscopy, X-ray diffraction, scanning electron microscopy, and transmission electron microscopy were used for compositional and microstructural analysis. Mechanical properties and fracture behavior were studied by instrumented indentation and focused ion beam techniques. Tribological properties were evaluated by ball-on-disk test in a linear reciprocal mode. A complex layer structure was found in the nanolayer coating. The TiSiN layers were epitaxially stabilized inside the coating which led to formation of dislocations at interfaces, to introduction of disturbances in the coating growth, and as a result, to development of fine-grained columnar microstructure. Indentation load required for the onset of fracture was twice lower for the nanolayer CrAlN/TiSiN, compared to the nanocomposite TiSiN coating. This agrees very well with their mechanical properties, with H³/E² being twice higher for the TiSiN coating. However, the nanolayer coating experienced less severe damage, which had a strong impact on tribological behavior. A magnitude of order lower wear rate and four times lower steady state friction coefficient were found for the nanolayer coating.     

A survey of nitrate and nitrite content of fruit and vegetables grown in Slovenia during 1996-2002

Monitoring of nitrate (NO₃^-) and nitrite (NO₂^-) content in agricultural products in Slovenia has been carried out since 1996. The results of monitoring over the period 1996-2002 are presented. During this time 924 samples of 14 different agricultural products (potato, lettuce, apples, carrot, silage maize, cabbage, grapes, peaches, string beans, cereals, pears, cucumbers, strawberries and tomato) were analysed. The samples were taken at the time of maturity directly from growing sites and they were analysed using segmented flow analysis. The average nitrate contents were the highest in lettuce (1074 mg kg^-1), cabbage (881 mg kg^-1), string beans (298 mg kg^-1) and carrot (264 mg kg^-1), and they were moderately high in potato (158 mg kg^-1), silage maize (122 mg kg^-1), strawberries (94 mg kg^-1), cucumbers (93 mg kg^-1) and cereals (49 mg kg^-1). Low nitrate contents (below 6 mg kg^-1) were found in fruit (grapes, peaches, apples and pears) and tomato. With the exception of cereals (8.9 mg kg^-1), apples (1.5 mg kg^-1), potato (1.2 mg kg^-1) and pears (1.0 mg kg^-1) the content of nitrites did not exceed 0.5 mg kg^-1. It may be concluded that the results of the monitoring were in most cases similar to the results of investigations obtained in other countries.     

Synthesis, structure and magnetic properties of β-MnO 2 nanorods

We present synthesis, structure and magnetic properties of structurally well-ordered single-crystalline β-MnO₂ nanorods of 50–100 nm diameter and several μm length. Thorough structural characterization shows that the basic β-MnO₂ material is covered by a thin surface layer (∼2.5 nm) of α-Mn₂O₃ phase with a reduced Mn valence that adds its own magnetic signal to the total magnetization of the β-MnO₂ nanorods. The relatively complicated temperature-dependent magnetism of the nanorods can be explained in terms of a superposition of bulk magnetic properties of spatially segregated β-MnO₂ and α-Mn₂O₃ constituent phases and the soft ferromagnetism of the thin interface layer between these two phases.     

A large-displacement 65Pb(Mg1/3Nb2/3)O3–35PbTiO3/Pt bimorph actuator prepared by screen printing

In this paper we present a novel approach to preparing large-displacement 65Pb(Mg_1/3Nb_2/3)O₃–35PbTiO₃/Pt (65/35 PMN–PT/Pt) bimorph actuators. These “substrate-free”, bending-type actuators were prepared by screen-printing the 65/35 PMN–PT and Pt thick-film pastes as the electrodes on alumina substrates. After this screen printing and the subsequent firing the 65/35 PMN–PT/Pt composites were peeled off from the substrates. Displacements of nearly 100 μm at 18 V were achieved for actuators with dimensions of 1.8 cm × 2.5 mm × 50 μm for the 65/35 PMN–PT layer. The normalized displacement (the displacement per unit length) was 40 μm/cm at 18 V. The experimental results together with a computation procedure were used to obtain the material parameters for a finite-element analysis of the 65/35 PMN–PT/Pt bimorph actuators.     

Influence of Particle Size Distribution,Moisture Content,and Particle Shape on the Flow Properties of Bulk Solids

Abstract

There has been a great deal of research on characterising bulk solids. However, some of the characteristics, particularly the time‐dependent and random changes of properties, still remain insufficiently understood. The focus of this article is to study the influence of particle size, size distribution, moisture content, and particle shape on the unconfined yield strength of bulk solids. We present some interesting results about the influence of the particle size distribution on the unconfined yield strength of a bulk solid and a new method for determining the influence of particle shape on the unconfined yield strength of a bulk solid, which was made possible by the design and use of a novel attritor.     

Permutation routing in double-loop networks: design and empirical evaluation

A double-loop network is an undirected graph whose nodes are integers 0,1,…,n−1 and each node u is adjacent to four nodes u±h₁(mod>n), u±h₂(mod>n), where 0<h₁<h₂<n/2. There are initially n packets, one at each of the n nodes. The packet at node u is destined to node π(u), where the mapping uπ(u) is a permutation. The aim is to minimize the number of routing steps to route all the packets to their destinations. If ℓ is the tight lower bound for this number, then the best known permutation routing algorithm takes, on average, 1.98ℓ routing steps (and 2ℓ routing steps in the worst-case).Because the worst-case complexity cannot be improved, we design four new static permutation routing algorithms with gradually improved average-case performances, which are 1.37ℓ, 1.35ℓ, 1.18ℓ, and 1.12ℓ. Thus, the best of these algorithms exceeds the optimal routing by at most 12% on average.To support our algorithm design we develop a program which simulates permutation routing in a network according to the given topology, routing model as well as communication pattern and measure several quality criteria. We have tested our algorithms on a large number of double-loop networks and permutations (randomly generated and standard).     

Friction on a single MoS2 nanotube

Friction was measured on a single molybdenum disulfide (MoS₂) nanotube and on a single MoS₂ nano-onion for the first time. We used atomic force microscopy (AFM) operating in ultra-high vacuum at room temperature. The average coefficient of friction between the AFM tip and MoS₂ nanotubes was found considerably below the corresponding values obtained from an air-cleaved MoS₂ single crystal or graphite. We revealed a nontrivial dependency of friction on interaction strength between the nanotube and the underlying substrate. Friction on detached or weakly supported nanotubes by the substrate was several times smaller (0.023 ± 0.005) than that on well-supported nanotubes (0.08 ± 0.02). We propose an explanation of a quarter of a century old phenomena of higher friction found for intracrystalline (0.06) than for intercrystalline slip (0.025) in MoS₂. Friction test on a single MoS₂ nano-onion revealed a combined gliding-rolling process.PACS, 62.20, 61.46.Fg, 68.37 Ps     

Layout design of manufacturable quantum-dot cellular automata

Quantum-dot cellular automaton (QCA) is an emergent technology that is not hindered by quantum effects that limit the scaling of CMOS technology, but instead employs them to perform computation. However, this brings its own impediments, such as the influence of the thermodynamic effects. Beside that, QCA has to be coupled with CMOS circuitry of different size features to enable clocking. We discussed all these facts and devised a floorplan which would facilitate manufacturability. Based on it we developed the process of QCA layout design and defined the design rules that must be considered in order to ensure correct operation. These instructions enable the automatization of designing a QCA circuit layout.