In this work, we report the tuning effect of the Si substitution on the magnetic and high frequency electromagnetic properties of R
2Fe
17 compounds and their paraffin composites. It is found that the introduction of Si can remarkably improve the magnetic and electromagnetic properties of the R
2Fe
17 compounds, making the R
2Fe
17–xSi
x-paraffin composites excellent microwave absorption materials (MAMs). By introducing the Si element, their saturation magnetizations decrease slightly, while much higher Curie temperatures are obtained. Furthermore, better impedance match is reached due to the decrease of the high-frequency permittivity
ε′ by about 40%–50%, which finally enhances the performance of the microwave absorption. The peak frequency (
fRL) of the reflection loss (
RL) curve moves toward high frequency domain and the qualified bandwidth (QB, RL ≤ ?10 dB) increases remarkably. The maximum QB of 3.3 GHz (12.0–15.3 GHz) is obtained for the Sm
1.5Y
0.5Fe
15Si
2-paraffin composite (
d = 1.0 mm) and the maximum
RL of ?53.6 dB is achieved for Nd
2Fe
15Si
2-paraffin composite (
d = 2.2 mm), both surpassing most of the reported MAMs. Additionally, a distinguished dielectric microwave absorption peak is observed, which further increases the QB in these composites.
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