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Zhou Yu Fang Bijun Zhang Shuai Lu Xiaolong Ding Jianning 《Journal of Materials Science: Materials in Electronics》2022,33(14):10977-10989
Journal of Materials Science: Materials in Electronics - 0.95(Li0.02Na0.50K0.48)(Nb0.95Sb0.05)O3–0.05AgTaO3@BaZrO3 (LNKNbSAT@BZ) lead-free ceramics were prepared via a sol–gel... 相似文献
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This paper deals with a class of fast diffusion p-Laplace equation with logarithmic non-linearity in a bounded smooth domain with homogeneous Dirichlet boundary condition. By using energy estimates and some ordinary differential inequalities, we study the conditions on extinction and non-extinction of global solutions. The results of this paper extend and complete the previous studies on this equation.
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The coupling of reaction and diffusion between neighboring active sites in the catalyst pore leads to the spatiotemporal fluctuation in component concentration, which is very important to catalyst performance and hence its optimal design. Molecular dynamics simulation with hard-sphere and pseudo-particle modeling has previously revealed the non-stochastic concentration fluctuation of the reactant/product near isolated active site due to such coupling, using a simple model reaction of A → B in 2D pores. The topic is further developed in this work by studying the concentration fluctuation due to such coupling between neighboring active sites in 3D pores. Two 3D pore models containing an isolated active site and two adjacent active sites were constructed, respectively. For the isolated site, the concentration fluctuation intensifies for larger pores, but the product yield decreases, and for a given pore size, the product yield reaches a peak at a certain reactant concentration. For two neighboring sites, their distance (d) is found to have little effect on the reaction, but significant to the diffusion. For the same reaction competing at both sites, larger d leads to more efficient diffusion and better overall performance. However, for sequential reactions at the two sites, higher overall performance presents at a smaller d. The results should be helpful to the catalyst design and reaction control in the relevant processes. 相似文献
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Journal of Materials Science - Silicon is getting much attention as the promising next-generation negative electrode materials for lithium-ion batteries with the advantages of abundance, high... 相似文献
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