用光刻、软刻和氧化硅球晶体模板制备表面微结构

表面微结构的制备对获得超疏水性表面和改善生物医学材料性能具有重要意义. 为了制备微米、亚微米和纳米级表面微结构, 本文采用光刻(photo-lithography)和软刻技术(soft lithography) 制备了微米尺寸长方体或圆柱体的阵列, 压印出变形长方体(塔状)或圆柱体(圆盘状)阵列的微结构表面; 采用单分散氧化硅球自集聚紧密堆积而成的胶体晶体为模板, 制备了亚微米/纳米 尺寸网状微结构的表面. 用光学和扫描电子显微镜表征了所获得的表面微结构.     

White light emission from Dy3+-doped LiLuF4 single crystal grown by Bridgman method

Lithium lutetium fluoride （LiLuF4） single crystals doped with different Dy3＋ ion concentrations were grown by Bridgman method. The Judd-Ofelt （J-O） strength parameters （Ω2, Ω4, Ω6） of Dy3＋ in LiLuF4 crystal are calculated according to the measured absorption spectra and the J-O theory, by which the asymmetry of the Dy3＋：LiLuF4 single crystal and the possibility of attaining stimulated emission from 4F9/2 level are analyzed. The capability of the Dy3＋：LiLuF4 crystal in generating white light by simultaneous blue and yellow emissions under excitation with ultra- violet light is produced. The effects of excitation wavelength and doping concentration on chromaticity coordinates and photoluminescence intensity are also investigated. Favorable CIE coordinates, x=0.319 3 and y=0.349 3, can be obtained for Dy3＋ ion in 2.701% molar doping concentration under excitation of 350 nm.     

Fabrication of Ormocer Containing Eu3＋ Ion and Their Optical Spectra

Eu3 ions were incorporated in sol and gel by a sol-gel processing using 3-glycidoxypropyltrimethoxysilane(CH2OCHCH2O(CH2)3Si(OCH3)3, GPTMS) and ethyl silicate (TEOS) as precursors. The basic chemical-physical properties such as DTA curve, FF-IR spectra and specific surface area were recorded. The characteristics of their optical spectra were measured and investigated. The results indicate that the emission intensity of Eu3 ion in ormocer is much higher and the global line width is wider than those in SiO2 gel. The relationship between the composition and structure of gels and the fluorescence intensity and width were discussed. The obtained ormocer shows good mechanical strength, which can be cut and polished in machine without broken.     

Co2+,Zn2+双掺杂铌酸锂晶体的坩埚下降法生长及其光谱特性

在LiNbO3中掺入0．1％（摩尔分数．下同）的CoO与3％,6％的ZnO,采用坩埚下降法技术生长了双掺杂的Co^2＋：Zn^2＋：LiNbO3晶体。用X射线衍射与差热分析表征了获得的晶体。测定了晶体不同部位在350～2500nm波段的吸收光谱。研究表明：Co离子位于LiNbO3晶体的崎变的氧八面体中,呈现＋2价,沿着生长方向Co^2＋在晶体中的浓度逐渐减少。ZnO的掺杂有效地抑制了Co^2＋离子在晶体中的掺入,使得Co^2＋在晶体中浓度的分布变得均匀。同时发现：ZnO的掺入使得上部晶体的熔点升高。从化学组分的角度解释了产生熔点变化的原因。观测到了750nm波长的荧光发射带。[编者按]     

Optical Spectroscopy of Er^3＋ and Er^3＋/Yb^3＋ Co-doped Bi2O3-GeO2-B2O3-ZnO Glasses

The （60 - x）Bi2O3 - xGeO2-30B2O3-10ZnO （x = 5, 10, 20, 30 molar percent） glasses doped with Er^3＋ and Er^3＋/Yb^3＋ were fabricated using the melting method. The thermal stability of the glasses was studied with their DTA curves. The results show that the difference between the glass transition temperature and the crystallization onset temperature increases with the increase of GeO2 content, indicating that the thermal stability of the glass has become better. The absorption spectra were recorded and the stimulated emission cross sections were calculated using the McCumber theory. The Ω2, O4, and Ω6 parameters,the transition probability, the radiative lifetime, and the fluorescence branch ratio of Er^3＋ for optical transition were calculated from their absorption spectra in terms of reduced matrix U^（t）（λ = 2, 4, 6） character for optical transitions. The infrared emission of Er^3＋ was measured upon excitation with 970 nm light and the full width at half-maximum （FWHM） was estimated from the emission spectra. The pumping efficiency and the intensity of the emission at the 1.54 μm band of Er^3＋ were enhanced considerably by co-doping Yb^3＋ .     

Growth and Optical Spectra of Zn∶Er∶LiNbO_3 Crystals Using Bridgman Method

The lithiumniobate single crystal (LiNbO3,LN)is one of the most i mportant materials because of itsexcellent properties such as piezoelectricity , photo-electricity, photorefractivity , and a nonlinear opticaleffect .It has been widely used for functional applica-tions such as , in the surface acoustic wave device(SAW) ,the piezoelectric transducer (PET) ,the op-tic parameter oscillator ( OPO) , the high-resolutionholographic storage and so on[1]. The Er3 +dopedLiNbO3crystals have also …     

Eu^3＋：LiNbO3Eu单晶的坩埚下降法生长及其光谱性质

选用合适的温度梯度(20～30℃／cm)与生长速度(1～3mm／h)，用坩埚下降法成功地生长出了掺杂Eu^3 的LiNbO3单晶。用X射线衍射及DTA分析表征了获得的晶体。生长的晶体无宏观缺陷，在He-Ne激光的照射下，无散射中心。测定了从生长初期下部到生长后期上部晶体的紫外一可见吸收光谱与荧光光谱。观测到分裂的光谱线。结果表明，沿着晶体生长方向，Eu抖浓度逐步减少。Eu抖离子在晶体中取代Li与Nb格位。     

Zn:Fe:LiNbO3单晶的坩埚下降法生长及其成分研究

通过优选合适的化学原料，用坩埚下降法生长出了无宏观缺陷的Zn：Fe：LiNbO3(Zn：Fe：LN)单晶。生长的工艺参数是：用微凸生长界面生长，生长速度为1～3mm／h，温度梯度为20～30℃／cm。用X射线衍射及DTA对晶体进行了分析；测定了晶体的吸收光谱。结果表明：所有Zn：Fe：LN晶体中的Fe^2 浓度沿生长方向增加；掺杂3％ZnO(摩尔分数)的Zn：Fe：LN单晶中的Fe^2 浓度沿生长方向的变化量比掺杂6％ZnO的大。从坩埚下降法的温场特点、晶体的热处理过程、环境气氛，以及ZnO组分对Fe离子的排斥作用解释了产生Fe^2 离子浓度变化的原因。     

不同先驱体溶胶-凝胶法制备的硫化锗玻璃薄膜

分别使用氯化锗和正锗酸乙脂为溶胶-凝胶先驱体,用2种不同的操作步骤制备溶胶,采用旋转涂膜技术在单晶硅片和玻璃基片上制备了硫化锗薄膜。对所获得的样品进行了X射线衍射、远红外和Raman光谱测试,并用扫描电镜观察薄膜形貌。结果表明：采用不同先驱体制备的溶胶-凝胶硫化锗玻璃薄膜其玻璃结构具有差异,并导致薄膜折射率的不同;由GeCl4所得玻璃薄膜为富锗相,其折射率约为2、8;而由Ge(OC2H5)4所得玻璃薄膜为富硫相,折射率约为2．2。     

Tunable emission,concentration quenching and crystallographic sites of Eu^2＋ in Sr3Y（PO4）3

A series of Sr3Y（PO4）3：Eu^2＋ samples are synthesized by the high temperature solid-state method. Sr3Y（PO4）3：Eu^2＋shows an asymmetrical emission band under excitation of 350 nm. The emission peaks at 426 nm and 497 nm are assigned to the nine-coordination Eu^2＋ and six-coordination Eu^2＋, respectively. The effects of Eu^2＋ doping content on the emission intensity and color are observed, and the concentration quenching effect is also observed. For two different Eu^2＋ luminescence centers, the quenching mechanisms are dipole-dipole interaction and quadrupole-quadrupole interaction, respectively. And the critical distance of energy transfer is calculated by concentration quenching and turns out to be about 3.67 nm. The results above show that the asymmetrical emission band of Sr3Y（PO4）3：Eu^2＋ comes from two different Eu2＋ luminescence centers in the lattice.