Kinetic analysis of crystallization of zeolite beta synthesized by direct heating

To quantitatively investigate the initial crystallization of zeolite beta synthesized by direct heating, the extent of the reaction was precisely evaluated by X-ray diffraction measurements and Rietveld structural refinement, and a kinetic analysis of crystallization was performed using the Avrami-Erofe'ev equation. The activation energy for crystallization was lower than that for hydrothermal synthesis. Reaction and synthesis time curves revealed that the initial zeolite beta crystallization consisted of three stages. The first was an induction period with nucleation by the generation of building units and the formation of an initial coordinated structure. The second stage was crystal growth by a diffusion-controlled reaction, and the third stage involved slowing down of crystallization by the limitation of dehydrocondensation. These stages could be analyzed by calculation of the rate constant and Avrami exponent for each stage.     

Isolation and identification of soil bacteria resistant to surfactants in washing detergents

Linear alkylbenzene sulfonate (LAS) and polyoxyethylene lauryl ether (POLE) are the major surfactants in washing detergents. In the present study, we isolated surfactant-resistant bacteria from soil samples collected from a sports ground and a farm field. The samples were treated with 2.0% LAS or POLE at 25°C for 30 min and cultivated on agar plates at 25°C for several days, after which manifold bacterial colonies were isolated. Thereafter, we tested the ability of each bacterial isolate to resist the antibacterial activity of the surfactant. Ten LAS-resistant strains were isolated, and all were found to be Gram-negative bacteria such as Enterobacter and Pseudomonas. On the other hand, 18 POLE-resistant strains were isolated, of which 14 were Gram-positive bacteria including Bacillus and Microbacterium. Notably, one POLE-resistant strain was identified as Bacillus cereus, a potential causative agent for foodborne illness. The genera of LAS- and POLE-resistant bacteria did not overlap. Therefore, the combination of LAS and POLE could be more effective to eliminate soil bacteria from clothes and/or daily necessities.     

Study on FBR core concepts to increase proliferation resistance of plutonium in LWR–FBR transition period

The possibility to enhance proliferation resistance of discharged plutonium in fast breeder reactor (FBR) has been investigated in terms of reactor core-design aspects. The provisional target for proliferation resistance measures based on Saito's attractiveness (ATTR) is defined. It is found that a few percent of plutonium loading and/or Am/Cm loading, which come from various types of spent fuel, might satisfy the provisional target with a minimum impact on the core neutronic performances. On Am/Cm loading core, decay heat constraints for fuel-handling aspects are found to be important and should be considered in design. There is not significant change on the current developing scenarios for light water reactor–FBR transition period by applying the measures based on Saito's ATTR. It is found that applying Kimura's proposal, 15% ²³⁸Pu content requires about 7% MA loading fraction both in the core and the blanket, and it only can be applied at limited case. The period to consume minor actinides is shorter than to consume plutonium.     

Development of Motor Model of Rotor Slot Harmonics for Speed Sensorless Control of Induction Motor

This paper proposes a novel mathematical dynamic model to represent the steady‐state and transient‐state characteristics of rotor slot harmonics of an induction motor for sensorless control. Although it is well known that the rotor slot harmonics originate from the mechanical structure of the induction motor, a mathematical model that describes the relationship between the stator/rotor currents of the induction motor and the slot harmonics has not yet been proposed. Therefore, in this paper, a three‐phase model of the induction motor that depicts the rotor slot harmonics is developed by taking into consideration the magnetomotive force harmonics and the change in the magnetic air gap caused by the rotor slots. The validity of the proposed model is verified by comparing the experimental results and the calculated values. © 2013 Wiley Periodicals, Inc. Electr Eng Jpn, 186(3): 63–74, 2014; Published online in Wiley Online Library ( wileyonlinelibrary.com ). DOI 10.1002/eej.22478     

Design of Nonlinear Servo Systems by the Fuzzy Method

This paper presents the design of nonlinear servo systems using the fuzzy method. The idea behind this control method is to divide the operating region of a nonlinear system into a collection of local linear servo control systems and apply the fuzzy method for calculation of the control input. The control input of each local linear servo system is calculated using the Davison–Smith method and the Hikita pole assignment method. We can prove that all states of the fuzzy servo system are bounded and that the output errors converge to zero by the Lyapunov method. Simulations on a nonlinear mass‐spring‐damper system illustrate the effectiveness of the proposed method.     

Remarkable effect of ordered mesoporous carbon support in tantalum oxide-catalyzed selective epoxidation of cyclooctene

The olefin epoxidation is one of the most important reactions in chemical industry. Metal oxide supports often cause drawbacks in catalytic activity and selectivity, which has been overcome by introducing hydrophobic organic groups onto the oxide supports. The present study utilizes ordered mesoporous carbon (CMK-3 and CMK-1) as structurally defined hydrophobic catalyst support. Well-dispersed tantalum oxides supported on the ordered mesoporous carbon were prepared. Their application in catalytic epoxidation of cyclooctene demonstrates that the tantalum oxide catalysts on the ordered mesoporous carbon supports show higher performances than those of the catalysts supported on activated carbon and ordered mesoporous silica SBA-15.     

Effect of Cation Doping on the Superplastic Flow in Yttria-Stabilized Tetragonal Zirconia Polycrystals

The superplastic characteristics of various cation-doped yttria-stabilized tetragonal zirconia polycrystals (Y-TZP) were examined. For 1 mol% cation doping the true stress of Y-TZP is very dependent on the ionic radii of the doped cations; for instance, smaller cation radii give rise to lower true stress when compared with the other compositions for the same grain size, strain rate, and testing temperature. The altered true stress level must be due to the change in diffusivity of the accommodation process for grain boundary sliding caused by the addition of cations in ZrO₂. The strain to failure of the doped zirconia is affected by both ionic radius and valence of the dopant cations.