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1.
Shunda Zhan Bangyan Dong Hongqiang Wang Yonghua Zhao 《Journal of the European Ceramic Society》2021,41(10):5075-5087
Bulk micromachining of single-crystal SiC has been challenging due to its extreme stability both mechanically and chemically. To address this issue, a novel tool-based electrolytic plasma etching method is proposed, with which micropatterns and micro-holes are fabricated in SiC in a hydrofluoric acid-free aqueous solution with no need for masks. The material removal is the result of the combined effects of electrolytic plasma chemistry and physics. The chemistry refers to the reaction of Si with hydroxyl radical to form various SiOx and with H to form silanes, and the reactions of C to form volatile carbon oxides or hydrocarbons, all of which are accomplished and enhanced under the electrolytic plasma atmosphere. Besides, the local high temperature of plasma thermally promotes the evaporation or dissolution of SiO2 in NaOH solution. The tool-based electrolytic plasma etching method provides alternative approaches for the fabrication of SiC-based MEMS and devices. 相似文献
2.
Chengkai Li Zheyi Zhang Haifei Zhan Zhuoqun Zheng Jingshuai Bai Yuantong Gu 《大分子材料与工程》2021,306(10):2100292
Low-dimensional carbon nanostructures are ideal nanofillers to reinforce the mechanical performance of polymer nanocomposites due to their excellent mechanical properties. Through molecular dynamics simulations, the mechanical performance of poly(vinyl alchohol) (PVA) nanocomposites reinforced with a single-layer diamond – diamane is investigated. It is found the PVA/diamane exhibits similar interfacial strengths and pull-out characteristics with the PVA/bilayer-graphene counterpart. Specifically, when the nanofiller is fully embedded in the nanocomposite, it is unable to deform simultaneously with the PVA matrix due to the weak interfacial load transfer efficiency, thus the enhancement effect is not significant. In comparison, diamane can effectively promote the tensile properties of the nanocomposite when it has a laminated structure as it deforms simultaneously with the matrix. With this configuration, the interlayer sp3 bonds endows diamane with a much higher resistance under compression and shear tests, thus the nanocomposite can reach very high compressive and shear stress. Overall, enhancement on the mechanical interlocking at the interface as triggered by surface functionalization is only effective for the fully embedded nanofiller. This work provides a fundamental understanding of the mechanical properties of PVA nanocomposites reinforced by diamane, which can shed lights on the design and preparation of next generation high-performance nanocomposites. 相似文献
3.
Da-Wang Tan Zhen-Yong Lao Zhan Zhang Wei-Ming Guo Shi-Kuan Sun Hua-Tay Lin 《Journal of the American Ceramic Society》2021,104(6):2860-2867
B4C-TiB2 ceramics (TiB2 ranging 5~70 vol%) with Mo-Co-WC as the sintering additive were prepared by spark plasma sintering. In comparison with B4C-TiB2 without additive, the enhanced densification was evident in the sintered specimen with Mo-Co-WC additive. Core-rim structured grain was observed around TiB2 grains. The interface of the rim between TiB2 and B4C phases demonstrated different feature: the inner borderline of the rim exhibited a smooth feature, whereas a sharp curved grain boundary was observed between the rim and the B4C grain. The formation mechanism is discussed: the epitaxial growth of (Ti,Mo,W)B2 rim around the TiB2 core may occur as a result of the solid solution and dissolution-precipitation between TiB2 phase and the sintering additive. It was revealed that the fracture toughness increased as the content of TiB2 content increased, alongside the decreased hardness. B4C-30 vol% TiB2 specimen demonstrated the optimal combination of mechanical properties, reaching Vickers hardness of 24.3 GPa and fracture toughness of 3.33 MPa·m1/2. 相似文献
4.
5.
Wenhui Zhu Haizhen Huan Ying Bu Xuepeng Li David Shiuan Jianrong Li Xiaotao Sun 《International Journal of Food Science & Technology》2019,54(6):2159-2168
Protein oxidation is considered as an important issue in food preservation process. In the present study, the potential influence of protein oxidation on water holding capacity and protein structure of jumbo squid (Dosidicus gigas) mantle was investigated. After the hydroxyl radical oxidation, it was found that the carbonyl, surface hydrophobicity and dityrosine content of myofibrillar protein significantly increased (P < 0.05), while the content of total sulphydryl decreased significantly (P < 0.01). Meanwhile, the fluorescence intensity of squid was weakened, and the maximum absorption peak of fluorescence red shift as the H2O2 concentration increased. The sodium dodecyl sulphate polyacrylamide gel electrophoresis (SDS-PAGE) showed that not only the protein cross-linking but also degradation could have occurred. The content of α-helix decreased, the content of β-sheet, β-turn and the unordered structures increased after oxidation. In addition, oxidation resulted in a decrease in water holding capacity. Taken together, oxidation resulted in the damage of the myofibrillar structure, the increase in muscle loss rate and the decrease in water holding capacity. 相似文献
6.
Stefanie Bußmann Harald Kruggel-Emden Mathis Reichert 《Advanced Powder Technology》2021,32(7):2171-2191
The particle based Discrete Element Method (DEM) can be applied to examine comminution processes. In this study, a DEM framework has been extended to model particle breakage without mass loss. After a breakage event occurs, spherical particles, as often considered in the DEM, are replaced by size reduced spherical fragments. During the following time steps, the fragments grow to their desired sizes, so that the mass loss can be counterbalanced. Previously defined overlaps with adjacent unbroken and broken particles (fragments) as well as walls are allowed. The breakage model has been realized in a parallelized DEM framework because comminution processes are often attributed to large numbers of particles and by parallelization the computational time can be reduced efficiently. An oedometer (one-dimensional compression in axial direction of a confined particle bed) has been modelled to investigate the parallelization efficiency and the influence of the permitted overlaps during the growth process on the growth duration. A simplified roller mill has been considered to examine the applicability of the breakage procedure considering parallelization. The results show that parallelization reduces computational time considerably. The breakage procedure is suitable to model comminution processes involving even densely packed particle systems and is superior to existing approaches. 相似文献
7.
8.
Carboxyl-terminated polybutadiene (CTPB) is a widely used telechelic liquid rubber, which is mainly prepared by anionic or free-radical polymerization of 1,3-butadiene. It is known that the microstructure of liquid polybutadiene rubber largely affects its processability and mechanical properties. However, it is hard to control its microstructure in the free radical or anionic polymerization. In this study, a series of CTPB with high cis-1,4 content has been prepared for the first time via the oxidolysis and selective oxidation of cis-polybutadiene rubber (BR). Hydrogenation of their CC double bonds with p-toluenesulfonyl hydrazide/tri-n-propylamine (TSH/TPA) reagents afforded carboxyl-terminated polyethylenes (CTPE). For comparison, commercial CTPB (FCTPB), prepared by free-radical polymerization of 1,3-butadiene, was also hydrogenated and gave FCTPE with more ethyl branches. Linear CTPE (L-CTPE) was synthesized by ring-opening metathesis polymerization of 1,5-cyclooctadiene in the presence of maleic acid and subsequent hydrogenation. The microstructure of the polymers was established by FT-IR, 1H NMR, 13C NMR, and GPC and their thermal properties were determined by DSC and TGA. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 46934. 相似文献
9.
通过金相试验方法测定42CrMo钢在890~930 ℃下保温10~240 min后的晶粒尺寸。结果表明,42CrMo钢在加热到试验温度890~930 ℃时已经完全奥氏体化,保温过程中的晶粒生长属于正常生长;加热温度对晶粒尺寸的影响较大,保温时间对晶粒尺寸的影响较小;随保温时间的延长晶粒生长缓慢,晶粒尺寸与保温时间满足指数小于1的函数关系。基于试验数据,通过线性回归得到晶粒长大的Beck模型参数,通过非线性回归得到Sellars和Anelli模型参数,3个模型的预测精度都较好,而Anelli模型的适用性要高于Beck模型和Sellars模型,故在预测42CrMo钢的奥氏体晶粒长大规律时宜使用Anelli模型。 相似文献
10.
Wireless Networks - Key generation leveraging wireless channel reciprocity can establish secret keys from unauthenticated broadcast channels and thus protect the communication of wireless networks.... 相似文献