Research on polyfluorene derivatives end-capped by N-hexyl-carbazole and benzene

Copolymers of 9,9-dioctylfluorene (DOF) and 2-thienyl-benzothiadiazole (DBT) were synthesized by Suzuki reaction and end-capped by N-hexyl-carbazole and benzene, which were abbreviated as PDOF-DBT-Cz and PDOF-DBT-B, respectively. The photophysical, electrochemical and thermal properties of the copolymers were studied. The results indicated that replacement of N-hexyl-carbazole as end-capping group of PDOF-DBT can vary light color and improve luminescence efficiency. Supported by the Major Project of Science Foundation Ministry of Education of China (Grant No. 207015) and the National Natural Science Foundation of China (Grant No. 20671068)     

Passivating Defects of Perovskite Solar Cells with Functional Donor-Acceptor–Donor Type Hole Transporting Materials

In this study, a series of donor–acceptor–donor (D-A-D) type small molecules based on the fluorene and diphenylethenyl enamine units, which are distinguished by different acceptors, as holetransporting materials (HTMs) for perovskite solar cells is presented. The incorporation of the malononitrile acceptor units is found to be beneficial for not only carrier transportation but also defects passivation via Pb–N interactions. The highest power conversion efficiency of over 22% is achieved on cells based on V1359, which is higher than that of spiro-OMeTAD under identical conditions. This st shows that HTMs prepared via simplified synthetic routes are not only a low-cost alternative to spiro-OMeTAD but also outperform in efficiency and stability state-of-art materials obtained via expensive cross-coupling methods.     

双胺芴基聚酰亚胺的合成及性能

以9,9-双(4-氨基苯基)芴(BAF)为二胺,分别与6种二酐单体——均苯四甲酸二酐(PMDA)、3,3’,4,4’-二苯醚四甲酸二酐(ODPA)、3,3’,4,4’-二苯甲酮四甲酸酐(BTDA)、3,3’,4,4’-联苯四甲酸二酐(BPDA)、4,4'-(六氟异丙烯)二酞酸酐(6FDA)和1,2,3,4-环丁烷四甲酸二酐(CBDA),经室温溶液缩聚反应得到聚酰胺酸溶液,再经化学酰亚胺化反应得到芴基聚酰亚胺(PI)。采用红外光谱、差示扫描量热分析、热重分析、溶解性测试及气体分离性能测试等手段对PI的结构和性能进行了表征。所合成的PI在N-甲基吡咯烷酮(NMP)等强极性溶剂中均具有良好的溶解性,且表现出良好的热性能,玻璃化转变温度(Tg)均在300℃以上,芳香族PI的起始热分解温度也均超过500℃,经600℃热处理的芴基PI,表现出了较好的气体渗透性能,但PI-CBDA膜的气体通量最小。     

四相相转移催化氧化芴制备芴酮

该文利用气-质联用仪确证了芴中杂质的结构和含量。反应物和产物的物料衡算揭示:在以二甲苯和水为溶剂,氢氧化钠为催化剂、季铵盐为相转移剂、空气为氧化剂氧化悬浮于二甲苯中的芴制备芴酮的反应中,芴的转化率为100%;芴100%的转化成芴酮和水,无其他副产物;反应前后原料芴中的杂质数目没有变化,每个杂质的物质的量也保持相等。用纯芴在相同的条件进行氧化反应,芴的转化率为100%,得到纯度100%的芴酮,验证了前述结果。从反应液中分离出芴酮后,溶剂、催化剂、相转移剂、水均可循环使用。同时讨论了反应的机理。     

芘修饰芴衍生物PTF的结构和光学性质

采用量子化学方法研究了一种芘修饰芴衍生物PTF的结构和光学性质。结果表明,该化合物呈现蝴蝶型结构,空穴注入传输性能强,发蓝光,这在理论上进一步证实其可作为蓝光材料或空穴材料应用于OLED。     

芴液晶的研究进展

介绍了近年来芴液晶的研究进展,包括以芴酮(醇)及9位取代芴为核心的液晶化合物,阐述了这类化合物的结构与液晶性质及光电性质之间的关系。该类化合物在光电发光材料、有机太阳能电池材料等领域有广泛的应用前景。     

Synthesis and Self-Organization of Fluorene-Conjugated Bisimidazolylporphyrin and Its Optical Properties

A conjugated-bisimidazolylporphyrin bridged by bis(ethynylfluorene) was synthesized and organized into linear polymer through self-coordination having mean molecular weights, M_w and M_n, of ~2.1 × 10⁵ Da and ~1.6 × 10⁵ Da, respectively. A large two-photon absorption cross section value of 3.4 × 10⁵ GM (per dimer unit) was observed. This value was comparable to that of the previously reported self-assembled linear polymer consisting of butadiyne-bridged imidazolylporphyrins. The two-photon absorption properties could be controlled by tuning the wavelength and absorption intensity of the one-photon absorption.     

芴衍生物TF-CF1的发光性质研究

芴类化合物是一种刚性平面联苯结构的电致发光材料,因具有宽的能隙、高的发光效率等优点,备受专家学者的关注。文章结合作者的工作实践,简述TF1可以作为一种有机电致发光的潜能型材料。     

Synthesis of a new conjugated polymer based on benzimidazole and its sensory properties using the fluorescence‐quenching effect

A new anionic conjugated polymer containing a fluorene group in the main chain was designed and synthesized from poly(2,7‐(9,9′‐dihexylfluorene)‐5,5′‐bibenzimidazole) (PFBI). The polymer showed strong blue emission with high quantum efficiency (0.64) at 450 nm in MeOH and the dramatic quenching effect by Methyl Viologen (MV²⁺). The fluorescence‐quenching effect results from the weak complex formation between an anionic polymer and electron acceptors such as bipyridinium derivatives. The linear Stern–Volmer constant (K_sv) was 3.7×10⁵ M^?1 for MV²⁺. The newly synthesized polymer is expected to show the applicability for biological and chemical sensors. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 900–904, 2004     

一种新型芴类衍生物的双光子光致漂白三维光存储

基于光致漂白的双光子吸收三维光信息存储原理,以钛蓝宝石飞秒脉冲激光在一种新型光致漂白材料芴类衍生物BMOSF中进行光致漂白双光子信息写入和读出的实验研究,实现了6层光信息存储,信息点间距和信息层间距分别为8和10μm;采用MATLAB软件对6层信息点进行信号强度识别和信号点强度对比.实验表明,芴类衍生物BMOSF可以用...