催化剂级配技术在加氢改质装置上的工业应用

基于柴油产品质量升级的需求,中国石化大连石油化工研究院(FRIPP)开发了FHIDW加氢改质技术及配套FF-46加氢精制催化剂、FC-14B加氢改质催化剂和FDW-3临氢降凝催化剂.该技术及催化剂级配体系在格尔木炼油厂0.8 Mt·a-1加氢改质装置上的工业应用情况表明,级配催化剂体系对原料适应性强,装置运转平稳,操作灵活性高,催化剂失活速率慢,产品分布合理且质量优异,在降低柴油产品凝点的同时可以明显改善其密度和十六烷值,解决了改造前装置生产重柴油密度偏低的问题,为炼油厂生产符合国V质量标准的柴油提供了技术保障.     

CDots-(001)TiO2纳米片的制备及其光解水制氢性能

以钛酸四丁酯、氢氟酸和石墨棒为原料,采用简单的水热法将具有高催化活性的碳点负载在TiO_2纳米片的(001)晶面上,制得CDots-(001)TiO_2纳米片。通过TiO_2纳米片高催化活性的(001)晶面与碳点的协同作用,提高TiO 2纳米片的光吸收、载流子的传输和分离效率,从而有效提高材料的光催化产氢性能。紫外-可见漫反射吸收谱(UV-visDRS)、光致发光光谱(PL)、瞬态光响应分析结果表明,暴露(001)晶面的TiO_2纳米片负载碳点后,可见光吸收增强,光生载流子的分离和传输速率加快,在间歇模拟太阳光照射下,CDots-(001)TiO 2纳米片的光电流密度约为TiO 2的4倍,当碳点的负载量为2%时,CDots-(001)TiO 2纳米片的光催化产氢速率达5859μmol/(h·g),量子效率达9.6%。     

渣油催化临氢热转化钼铁双金属催化剂的研究

Replacement of precious single metal catalysts with cost-effective, highly-dispersed composite catalysts for catalytic hydrothermal conversion of residue holds tremendous promise for the residue upgrading technologies. Organic metals were added to the feed as the oil-soluble precursors, and transformed into the catalytic active phases in this work. Physical properties and structures of the composite catalysts had been investigated by X-ray fluorescence spectroscopy, X-ray photoelectron spectroscopy, X-ray diffraction, scanning electron microscope and transmission electron microscopy. The composite catalysts were found to be highly efficient in the catalytic hydrothermal conversion of both model compound and residue. Increased metal dispersion and synergistic effects of two metals played indispensable roles in such catalytic system. Results showed that under the test conditions in the article, the catalyst had the best catalytic performance when the mass ratio of molybdenum to iron was 1.5.