正交试验法优化好氧颗粒污泥培养条件的研究

利用自制的SBR反应器,在厌-好氧交替运行条件下,采用逐步提高进水负荷的调控方法培养好氧颗粒污泥。针对好氧颗粒污泥的特点,选取影响好氧颗粒污泥成粒的进水COD、进水C/N比、厌氧时长、水力停留时间和曝气量5个因素,采用正交试验方法,探索其对好氧颗粒污泥形成的影响度,找到好氧颗粒污泥形成的最优培养条件。实验证明:在现有实验条件下影响颗粒化率的显著程度依次为:进水COD—沉降时间—厌氧时长—进水C/N比—曝气量—水力停留时间。最优培养条件是进水COD为600~1 300 mg/L,沉降时间为10 m in,厌氧时长为30 m in,进水C/N为10∶1,曝气量为0.2 m3/h,水力停留时间为270 m in,此条件下培养的好氧颗粒污泥COD去除率和氨氮去除率分别达到96%和83%。     

活性炭为载体的好氧颗粒污泥培养及性能研究

好氧颗粒污泥是一种应用于废水生化处理中的新型活性污泥技术,具有结构致密,沉降性能优越,生物处理能力强等特点.通过在气升式内循环间歇反应器启动阶段,接种活性污泥的同时添加活性炭颗粒(AC)的方法,缩短好氧颗粒污泥颗粒化时间,成功培养出了沉降速率大,结构稳定,除氮效果好的活性炭好氧颗粒污泥.并考察了活性污泥絮体-出现颗粒污泥-成熟颗粒污泥-储存-解体-修复的过程,验证了载体强化型好氧颗粒污泥处理低碳氮比废水的可行性.实验结果证明:活性炭好氧颗粒污泥反应器稳定运行时,COD、氨氮、总氮去除率分别可以达到80％ ～ 90％、99％、80％.将成熟活性炭好氧颗粒污泥储存12个月,经过恢复培养,物理特性及脱氮性能能够完全恢复到储存前的水平.     

好氧颗粒污泥快速恢复活性的试验研究

利用正交实验法,采用啤酒废水,在SBR反应器中对在4℃的冰箱中储存7周的好氧颗粒污泥进行活性恢复,观察储存对颗粒污泥的影响及确定颗粒污泥的最佳恢复条件。经过储存的好氧颗粒污泥,其粒径、平均沉降速率无明显变化;上层变黑的好氧颗粒污泥能较快恢复至棕黄色。好氧颗粒污泥恢复活性的最佳操作条件为进水COD持续800 mg/L,水力停留时间8 h,曝气量0.15 m3/h,沉降时间10 min。     

好氧颗粒污泥反应器快速启动及除碳脱氮试验

为快速启动好氧颗粒污泥反应器,在SBR反应器中同时接种硝化污泥和厌氧颗粒污泥,控制反应条件,温度23~25℃,pH值7.5~8.5,DO质量浓度1.5 mg/L左右,15 d即完成反应器快速启动。形成的好氧颗粒污泥粒径1.5~2.5 mm,SVI值54 mL/g。颗粒污泥结构紧密,沉降性能良好。反应器连续运行40多天,改变进水COD及NH4+-N浓度,COD和NH4+-N去除率均能稳定在80%以上,反应器内发生了同步硝化反硝化过程。     

梯度进水对好氧颗粒污泥特性及番茄酱废水去除性能的影响

新疆番茄酱生产过程中产生的废水具有浓度高、处理难度大、易污染地表水等特点，研究降解该废水处理技术具有重要意义。在室温下接种絮体污泥于间歇式活性污泥反应器(SBR)R1和R2中，以人工配制番茄酱废水为进水基质，采用阶梯式进水COD浓度方式培养好氧颗粒污泥(AGS)，探究进水COD浓度变化对AGS形态、污泥理化特性及除污效能的影响。结果表明：梯度进水COD浓度固定为350 mg/L,R1和R2中污泥完全颗粒化后，颗粒粒径分别为780μm和1 060μm;R1、R2对番茄酱废水中COD、NH₃-N、TN和PO₄^3--P平均去除率分别为95.2%、96.03%、85%、92.07%和93%、89.54%、78%、89%。进水COD浓度为346～750、750～900、900～1 200 mg/L时，颗粒形态由丝状菌骨架、孔洞结构和块状聚集体构成。氨氧化菌(AOB)和硝化菌(NOB)主要存在于小粒径AGS的外层和次外层，聚磷菌(PAOs)和聚糖菌(GAOs)主要存在于反应器底部的大颗粒污泥中。在梯度进水COD浓度不变下，高浓度的进...     

乳品废水处理初探

文章针对实际乳品废水,采用好氧颗粒污方法,在SBR反应器中,研究运行周期和COD污泥负荷对处理效果的影响。研究表明,运行周期在6 h时,COD去除率为92%,且延长运行周期COD去除率变化微弱。好氧颗粒污泥具有较强的抗冲击负荷能力,当COD污泥负荷在1.0~2.0范围内变化时,可保持93%以上的较高的处理效果。     

好氧颗粒污泥处理高浓度及难降解废水研究进展

好氧颗粒污泥以其在反应器中污泥沉降速度快、泥水分离简单、污泥浓度高,能够同时实现脱氮除磷等特点成为目前污(废)水处理领域的研究热点之一。对好氧颗粒污泥在高浓度有机废水及难降解废水(硝基苯废水、苯酚废水、氯酚废水、苯胺和氯苯胺废水、含盐废水、染料废水)处理中的研究现状进行综述,重点探讨了好氧颗粒污泥处理该类物质的影响因素、去除机制及其微生物特性等,指出其在难降解废水处理方面具有良好的应用前景。     

运行条件对好氧颗粒污泥处理乳品废水的影响

目前,针对好氧颗粒污泥的相关研究大都采用人工模拟废水,文章对基于好氧颗粒污泥的实际乳品废水处理方法,研究运行周期和原水COD浓度对处理效果的影响,为其工程应用提供试验数据。     

污水处理厂出水氨氮超标原因分析及解决途径

兰州市西固污水处理厂调试运行阶段出水氨氮超标。通过分析四种形态无机氮浓度在整个处理过程中的变化、好氧池运行操作条件和进水COD波动情况,发现好氧池硝化反应较弱,操作条件比较适宜硝化细菌的繁殖和生活,而进水COD浓度63％频次低于设计值;综合分析得到碳源不足是氨氮不达标的主要原因。采取在进水COD浓度较低时直接超越初沉池的办法补充碳源,效果较好。     

生物流化床法处理城市污水处理厂污泥回流液的可行性研究

以城市污水处理厂污泥回流液为研究对象,研究生物流化床法降低污泥回流液中氮磷浓度的效果,并分析了COD/TN与COD/TP值对生物流化床脱氮除磷的影响.结果表明,COD_(Cr)浓度对脱氮影响不大,而对除磷有较大影响.在COD_(Cr)为500 mg/L,进水TN为115 mg/L时,TN的去除率最大为72.05%,此时,COD/TN值为4.35.在COD_(Cr)为480 mg/L,进水TP为11.25 mg/L时,TP的去除率最高为36.98%,此时COD/TP为42.67.生物流化床法对降低高浓度氮磷污泥回流液具有一定的去除效果,TN去除率可达56.35%,TP去除率为28.96%.     

Optimizing sequencing batch reactor (SBR) reactor operation for treatment of dairy wastewater with aerobic granular sludge

The biological wastewater treatment using aerobic granular sludge is a new and very promising method, which is predominantly used in SBR reactors which have higher volumetric conversion rates than methods with flocculent sludge. With suitable reactor operation, flocculent biomass will accumulate into globular aggregates, due to the creation of increased substrate gradients and high shearing power degrees. In the research project described in this paper dairy wastewater with a high particle load was treated with aerobic granular sludge in an SBR reactor. A dynamic mathematical model was developed describing COD and nitrogen removal as well as typical biofilm processes such as diffusion or substrate limitation in greater detail. The calibrated model was excellently able to reproduce the measuring data despite of strongly varying wastewater composition. In this paper scenario calculations with a calibrated biokinetic model were executed to evaluate the effect of different operation strategies for the granular SBR. Modeling results showed that the granules with an average diameter of 2.5 mm had an aerobic layer in between 65-95 microm. Density of the granules was 40 kgVSS/m3. Results revealed amongst others optimal operation conditions for nitrogen removal with oxygen concentrations below 5 gO2/m3. Lower oxygen concentrations led to thinner aerobic but thicker anoxic granular layers with higher nitrate removal efficiencies. Total SBR-cycle times should be in between 360-480 minutes. Reduction of the cycle time from 480 to 360 minutes with a 50% higher throughput resulted in an increase of peak nitrogen effluent concentrations by 40%. Considering biochemical processes the volumetric loading rate for dairy wastewater should be higher than 4.5 kgCOD/(m3*d). Higher COD input load with a COD-based volumetric loading rate of 9.0 kgCOD/(m3*d) nearly led to complete nitrogen removal. Under different operational conditions average nitrification rates up to 5 gNH/(m3*h) and denitrification rates up to 3.7 gNO/(m3*h) were achieved.     

ABR反应器对垃圾渗滤液的处理试验研究

ABR工艺在处理垃圾渗滤液中具有其他厌氧生物反应器所达不到的优点。尤其是对B/C低、氨氮浓度高、COD浓度高的废水处理,通过调节回流比、HRT、碱度等参数后,可以取得很好的处理效果。在本次实验中,HRT控制在18h后明显提高的垃圾渗滤液的可生化性及C/N,使ABR出水CODcr去除率达到75%,C/N为6.72,对后续好氧反应起到了重要作用。在调控一定回流比后,为提供厌氧氨氧化所需的电子受体NO-3和NO-2实现脱氮。反应器在经过120d的培养驯化,氨氮进水为460mg/L,ABR对氨氮的去除率稳定在80%。不同格室的厌氧颗粒污泥都得到很好的驯化并在其合适的环境中发挥各自的功能。     

Nitrogen removal in an upflow sludge blanket (USB) reactor combined by aerobic biofiltration systems.

A new nitrogen removal process (up-flow sludge blanket and aerobic filter, USB-AF) was proposed and tested with real sewage. In the USB reactor, the larger part of influent organic and nitrogen matters were removed, and ammonia was effectively oxidized in the subsequent aerobic filter. The role of the aerobic filter was to convert ammonia into nitrate, an electron acceptor that could convert soluble organic matters into volatile suspended solid (VSS) in the USB. The accumulated as well as influent VSS in the USB was finally degraded to fermented products that were another good carbon source for denitrification. Total COD, settleable COD and soluble COD in the raw sewage were 325, 80 and 140 mg/l, respectively. Most unsettleable COD as well as some SCOD in the influent was successfully removed in the USB. TCOD removal in the anoxic filter was by denitrification with the recycled nitrate. Low COD input to the aerobic filter could increase nitrification efficiency, reduce the start-up period and save the aeration energy in the USB-AF system. About 95% of ammonia was nitrified in the aerobic filter with no relation to the influent ammonia concentration. Denitrification efficiency of the recycled nitrate in the anoxic filter was about 85, 83, and 72% at recycle ratios of 100, 200, and 300%, respectively. T-N removal efficiency was 70% at recycle ratio of 300%.     

A two-sludge system for simultaneous biological C, N and P removal via the nitrite pathway

Nitrogen removal via the nitrite pathway results in significant savings in both aeration costs and COD requirements for denitrification when compared to the conventional biological nitrogen removal process. Implementation of the nitrite pathway for simultaneous C/N/P removal in a single sludge system has a major drawback: the aeration phase disfavours denitrifying phosphorus removal. A possible configuration to overcome this issue is the utilisation of a two-sludge system where autotrophic and heterotrophic populations are physically separated. This paper experimentally demonstrates the feasibility of a nitrite-based two-sludge system with sequencing batch reactors (SBR) for the treatment of urban wastewater: a heterotrophic SBR with denitrifying PAOs for P removal and an aerobic SBR for N removal. Partial nitrification was attained in the autotrophic SBR so that shortcut biological nitrogen removal was achieved by using the anoxic dephosphatation activity of DPAOs. Finally, the effect of operating this system without pH control was studied using different influent pH values (pH = 6.8, 7.5 and 8.2) and, despite some efficiency lost due to the pH fluctuations, the system was able to remove most of the C, N and P present in the wastewater.     

Alternate anoxic/aerobic operation for nitrogen removal in a membrane bioreactor for municipal wastewater treatment

A large pilot-scale membrane bioreactor (MBR) with a conventional denitrification/nitrification scheme for municipal wastewater treatment has been run for one year under two different aeration strategies in the oxidation/nitrification compartment. During the first five months air supply was provided according to the dissolved-oxygen set-point and the system run as a conventional predenitrification MBR; then, an intermittent aeration strategy based on effluent ammonia nitrogen was adopted in the aerobic compartment in order to assess the impact on process performances in terms of N and P removal, energy consumption and sludge reduction. The experimental inferences show a significant improvement of the effluent quality as COD and total nitrogen, both due to a better utilization of the denitrification potential which is a function of the available electron donor (biodegradable COD) and electron acceptor (nitric nitrogen); particularly, nitrogen removal increased from 67% to 75%. At the same time, a more effective biological phosphorus removal was observed as a consequence of better selection of denitrifying phosphorus accumulating organisms (dPAO). The longer duration of anoxic phases also reflected in a lower excess sludge production (12% decrease) compared with the standard pre-denitrification operation and in a decrease of energy consumption for oxygen supply (about 50%).     

Treatment of high loaded swine slurry in an aerobic granular reactor

Aerobic granular sludge grown in a sequential batch reactor was proposed as an alternative to anaerobic processes for organic matter and nitrogen removal from swine slurry. Aerobic granulation was achieved with this wastewater after few days from start-up. On day 140 of operation, the granular properties were: 5 mm of average diameter, SVI of 32 mL (g VSS)(-1) and density around 55 g VSS (L(granule))(-1). Organic matter removal efficiencies up to 87% and nitrogen removal efficiencies up to 70% were achieved during the treatment of organic and nitrogen loading rates (OLR and NLR) of 4.4 kg COD m(-3) d(-1) and of 0.83 kg N m(-3) d(-1), respectively. However, nitrogen removal processes were negatively affected when applied OLR was 7.0 kg COD m(-3) d(-1) and NLR was 1.26 kg N m(-3) d(-1). The operational cycle of the reactor was modified by reducing the volumetric exchange ratio from 50 to 6% in order to be able to treat the raw slurry without dilution.     

Aerobic granulation in a mechanical stirred SBR: treatment of low organic loads

Aerobic granular sludge was produced in a sequencing batch reactor (SBR) characterized by a height to diameter ratio of 2.5 and the use of mechanical stirring. Compact and regular aerobic granules of up to 1.75 mm of average diameter were formed in the reactor with an organic loading rate of 1.75 kg COD/(m3 d). Settling properties of the obtained aggregates were: sludge volumetric index of 30-40 mL/g VSS and settling velocity higher than 8 m/h. The effects of different carbon to nitrogen ratios (TOC/N) in the feeding on the organic matter oxidation and nitrification process were studied. The concentration of organic matter in the feeding was stepwise reduced (from 190.0 to 37.5 mg TOC/L) and ammonium increased (from 25 to 50 mg NH4+ -N/L). TOC/N ratios of 7.50, 3.00, 1.50 and 0.75 g/g in the feeding were tested. The TOC removal percentage was around 80-95% during the whole operational period and the N removal percentages obtained in the reactor were up to 40%, however, physical properties of the granules were not maintained.     

林可霉素高浓度有机废水处理技术

采用厌氧颗粒和好氧活性污泥分别对内循环厌氧反应器(IC)和间歇式活性污泥法(SBR)进行污泥接种培养,研究水解酸化-IC-SBR工艺在林可霉素生产废水处理方面的运行效果。结果表明:在进水COD的质量浓度为6 000~9 000 mg/L,IC和SBR反应器中有机负荷分别为0.82 kg/(kg.d)和0.26 kg/(kg.d)左右的情况下,IC和SBR反应器分别运行60 d和7 d,COD平均去除率分别达到91%和61%,出水COD的质量浓度在300 mg/L以下,达到GB 8978—1996《污水综合排放标准》二级标准。