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研究了橡胶共混比、硫化体系、高耐磨炭黑用量及共混工艺等对EPDM/CR共混物性能的影响,考察了共混物的力学性能、耐高温硝酸性能、热空气老化性能、耐辐射性能和相容性。试验结果表明,采用炭黑全部加入EPDM中然后与CR混合的共混工艺,所得硫化胶的力学性能超过两种橡胶硫化胶力学性能的加和值;共混胶中EPDM采用硫黄硫化才能得到比较好的力学性能。硫化动力学研究表明CR的硫化速度较EPDM的硫化速度对温度的依赖性小。DSC和DVA分析结果表明共混胶具有两个明显的玻璃化转变温度,为热力学不相容体系。研制的EPDM/CR共混物具有耐老化、耐高温硝酸、耐辐射、粘合好等优良性能。 相似文献
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采用有机过氧化物硫化体系,通过动态硫化方法制备高聚合度聚氯乙烯(HPVC)/SBR共混型热塑性弹性体,测试共混物硫化胶的力学性能。结果表明,当HPVC/SBR并用比为80/20,过氧化二异丙苯(硫化剂DCP)用量为15份时,加入1~3份不同种类的相容剂,可改善共混物的力学性能,其中以氯化聚乙烯(CPE)的作用效果最好;返炼次数对共混物力学性能没有明显影响 相似文献
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PVC/SBR热塑性弹性体的研制 总被引:1,自引:0,他引:1
以ABS、氯丁橡胶(CR)、马来酸酐(MA)接枝SBR(SBR-MA)作增容剂对PVC/SBR的共混比、增容剂、增塑剂用量做了优化选择。同时对动态硫化PVC/SBR的硫化体系、硫化工艺条件进行了探讨,并比较了动态硫化对共混体性能的影响。结果表明:PVC/SBR为80/20,增容剂ABS/SBR-MA为5/5时,选用半有效硫化体系,165℃下动态硫化6min,共混物综合性能最佳 相似文献
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讨论了炭黑变量对充油顺丁橡胶(BR9075)/丁苯橡交(SBR1502)和顺丁橡胶(BR9000)/充油丁苯橡胶(SBR1712)两种共混胶物理性能的影响,结果表明BF9075/SBR1712共混胶物理性能和Brabender挤出性能的影响,认为该共混体系的理想共混比为BR9075/SBR1712=40/60,中超耐磨炭黑最佳用量为75份。 相似文献
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用马来酸酐接枝聚丙烯(MP)/胺/端羧基液体工腈橡胶(CTBN)反应,生成PP-NBR嵌段共聚物作为相容剂制备NBR/PP动态硫化共混型热塑性弹性体效果很好,其中尤以MP/1.6-己二胺/CTBN效果最为理想。相容剂用量控制在6%左右。PP的熔融指数越小,共混体的性能越好。硫化体系采用酚酸树脂2402/氯化亚锡(8/0.5)、加入一定量的增塑剂邻苯二甲酸二辛酯和补强剂高耐磨炭黑,可获得性能较好的共混体。 相似文献
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J. R. Aldrich S. P. Carroll W. R. Lusby M. J. Thompson J. P. Kochansky R. M. Waters 《Journal of chemical ecology》1990,16(1):199-210
Scentless plant bugs (Heteroptera: Rhopalidae) are so named because adults of the Serinethinae have vestigial metathoracic scent glands. Serinethines are seed predators of Sapindales, especially Sapindaceae that produce toxic cyanolipids. In two serinethine species whose ranges extend into the southern United States,Jadera haematoloma andJ. sanguinolenta, sequestration of host cyanolipids as glucosides renders these gregarious, aposematic insects unpalatable to a variety of predators. The blood glucoside profile and cyanogenesis ofJadera varies depending on the cyanolipid chemistry of hosts, and adults and larvae fed golden rain tree seeds (Koelreuteria paniculata) excrete the volatile lactone, 4-methyl-2(5H)-furanone, to which they are attracted.Jadera fed balloon vine seeds (Cardiospermum spp.) do not excrete the attractive lactone. Loss of the usual heteropteran defensive glands in serinethines may have coevolved with host specificity on toxic plants, and the orientation ofJadera to a volatile excretory product could be an adaptive response to save time.Mention of a commercial product does not consititute an endorsement by the USDA. 相似文献
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M. S. J. Simmonds W. M. Blaney F. Delle Monache M. Marquina Mac-Quhae G. B. Marini Bettolo 《Journal of chemical ecology》1985,11(12):1593-1599
Vismiones and ferruginins, representatives of a new class of lypophilic anthranoids from the genusVismia were found to inhibit feeding in larvae of species ofSpodoptera, Heliothis, and inLocusta migratoria. 相似文献
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It is well established that a wide range of drugs of abuse acutely boost the signaling of the sympathetic nervous system and the hypothalamic–pituitary–adrenal (HPA) axis, where norepinephrine and epinephrine are major output molecules. This stimulatory effect is accompanied by such symptoms as elevated heart rate and blood pressure, more rapid breathing, increased body temperature and sweating, and pupillary dilation, as well as the intoxicating or euphoric subjective properties of the drug. While many drugs of abuse are thought to achieve their intoxicating effects by modulating the monoaminergic neurotransmitter systems (i.e., serotonin, norepinephrine, dopamine) by binding to these receptors or otherwise affecting their synaptic signaling, this paper puts forth the hypothesis that many of these drugs are actually acutely converted to catecholamines (dopamine, norepinephrine, epinephrine) in vivo, in addition to transformation to their known metabolites. In this manner, a range of stimulants, opioids, and psychedelics (as well as alcohol) may partially achieve their intoxicating properties, as well as side effects, due to this putative transformation to catecholamines. If this hypothesis is correct, it would alter our understanding of the basic biosynthetic pathways for generating these important signaling molecules, while also modifying our view of the neural substrates underlying substance abuse and dependence, including psychological stress-induced relapse. Importantly, there is a direct way to test the overarching hypothesis: administer (either centrally or peripherally) stable isotope versions of these drugs to model organisms such as rodents (or even to humans) and then use liquid chromatography-mass spectrometry to determine if the labeled drug is converted to labeled catecholamines in brain, blood plasma, or urine samples. 相似文献
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2008~2009年世界塑料工业进展 总被引:4,自引:1,他引:3
中蓝晨光化工研究院有限公司《塑料工业》编辑部 《塑料工业》2010,38(3)
收集了2008年7月~2009年6月世界塑料工业的相关资料,介绍了2008~2009年国外塑料工业的发展情况,提供了世界塑料产量、消费量及全球各类树脂的需求量及产能情况。按通用热塑性树脂(聚乙烯、聚丙烯、聚苯乙烯、聚氯乙烯、ABS树脂)、工程塑料(尼龙、聚碳酸酯、聚甲醛、热塑性聚酯、聚苯醚)、特种工程塑料(聚苯硫醚、液晶聚合物、聚醚醚酮)、通用热固性树脂(酚醛、聚氨酯、环氧树脂、不饱和聚酯树脂)不同品种的顺序,对树脂的产量、消费量、供需状况及合成工艺、产品应用开发、树脂品种的延伸及应用的进一步扩展等技术作了详细介绍。 相似文献
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Halyomorpha halys (Stål) (Pentatomidae), called the brown marmorated stink bug (BMSB), is a newly invasive species in the eastern USA that is rapidly spreading from the original point of establishment in Allentown, PA. In its native range, the BMSB is reportedly attracted to methyl (E,E,Z)-2,4,6-decatrienoate, the male-produced pheromone of another pentatomid common in eastern Asia, Plautia stali Scott. In North America, Thyanta spp. are the only pentatomids known to produce methyl 2,4,6-decatrienoate [the (E,Z,Z)-isomer] as part of their pheromones. Methyl 2,4,6-decatrienoates were field-tested in Maryland to monitor the spread of the BMSB and to explore the possibility that Thyanta spp. are an alternate host for parasitic tachinid flies that use stink bug pheromones as host-finding kairomones. Here we report the first captures of adult and nymph BMSBs in traps baited with methyl (E,E,Z)-2,4,6-decatrienoate in central Maryland and present data verifying that the tachinid, Euclytia flava (Townsend), exploits methyl (E,Z,Z)-2,4,6-decatrienoate as a kairomone. We also report the unexpected finding that various isomers of methyl 2,4,6-decatrienoate attract Acrosternum hilare (Say), although this bug apparently does not produce methyl decatrienoates. Other stink bugs and tachinids native to North America were also attracted to methyl 2,4,6-decatrienoates. These data indicate there are Heteroptera in North America in addition to Thyanta spp. that probably use methyl 2,4,6-decatrienoates as pheromones. The evidence that some pentatomids exploit the pheromones of other true bugs as kairomones to find food or to congregate as a passive defense against tachinid parasitism is discussed. 相似文献