Novel TiC-based composites with enhanced mechanical properties

Novel TiC-based composites were synthesized by reactive hot-pressing at 1800 °C for 1 h with ZrB₂ addition as a sintering aid for the first time. The effects of ZrB₂ contents on the phase composition, microstructure evolution, and mechanical properties were reported. Based on the reaction and solid solution coupling effects between ZrB₂ and TiC, the product ZrC may be partially or completely dissolved into the TiC matrix, and then phase separation within the miscibility gap is observed to form lamellar nanostructured ZrC-rich (Zr, Ti)C. The TiC-10 mol.% ZrB₂ (starting batch composition) exhibits good comprehensive mechanical properties of hardness 27.7 ± 1.3 GPa, flexural strength 659 ± 48 MPa, and fracture toughness of 6.5 ± 0.6 MPa m^1/2, respectively, which reach or exceed most TiC-based composites using ceramics as sintering aids in the previous reports.     

负极添加NMP对电池性能的影响

锂离子电池负极浆料中添加N-甲基吡咯烷酮(NMP),在极片加热干燥时不能完全除去.残留的NMP吸附在石墨表面,使得SEI膜与石墨结合不牢固.研究了其对电池性能的影响,结果显示,在电池的循环过程中,SEI膜逐渐脱落,导致电池循环寿命缩短,但对电池的容量、内阻、倍率、存储等初期性能不影响.     

Hydrogeochemical Processes and Inverse Modeling for a Multilayer Aquifer System in the Yuaner Coal Mine,Huaibei Coalfield,China

Coal mining can dramatically change hydrogeological conditions and induce serious environmental problems. Fifty groundwater samples were collected from the main aquifers in the Yuaner coal mine (Anhui Province, China). The results show that the main hydrogeochemical processes in the mine include dissolution, precipitation, pyrite oxidation, desulfurization, and cation exchange. The Neogene porous aquifer is affected by groundwater flow conditions; its main hydrogeochemical processes are dissolution of carbonate minerals and gypsum, and cation exchange. The Permian coal measure’s fractured sandstone aquifer was confirmed to be controlled by the region’s geological structure; its main hydrogeochemical processes are desulfurization and cation exchange. The Carboniferous Taiyuan limestone aquifer was determined by both groundwater flow conditions and regional geological structure; its main hydrogeochemical processes are dissolution of carbonate minerals and gypsum, pyrite oxidation, and cation exchange. Additionally, hydrogeochemical inverse modeling of the groundwater flow path confirm the hydrochemistry results and principal component analysis.

     

微波辅助孵育法富集麦胚多肽的工艺优化

目的 麦胚孵育过程中蛋白酶将蛋白质水解成肽和氨基酸，多肽具有明确的生理活性和营养调节作用。本研究以麦胚为试验原料，采用微波辅助预处理的方法，研究孵育的温度、时间、pH及料液比4种因素对孵育后的蛋白酶活力及多肽含量的影响。 方法 通过单因素和响应曲面试验进行工艺条件优化。 结果 与未进行微波辅助预处理的样品相比，微波辅助处理（600 W, 10 s）能显著提高孵育后样品中的蛋白酶酶活力（约9.4倍）和肽含量（约3.1倍）。经过微波辅助处理后，孵育温度为51.5℃、pH为4.0、时间为6.33 h、料液比为1:7时，蛋白酶活力达最高为3826.24 U/g；孵育温度为45.0 ℃、pH为4.8、时间为8 h、料液比为1:7时，肽含量达最高为262.63 mg/g。 结论 微波辅助处理能有效的激活麦胚孵育液中的内源性蛋白酶活性，促进蛋白水解反应，显著提高孵育后的肽含量。该研究结果为麦胚多肽的制备新工艺开发提供了研究基础。     

基于熵权TOPSIS的工程咨询机构BIM技术应用能力评价

构建工程咨询机构BIM技术应用能力评价的指标体系,提出改进的熵权TOPSIS评价模型,以4个典型的工程咨询单位为例,进行BIM技术运用能力评价。研究表明,BIM行业的整体水平已经有了明显的提升,但是区域间的发展还存在一定差距。     

突发疫情对染料行业影响及对策

一场新型冠状病毒肺炎疫情的爆发给染料行业的发展带来了影响,既有负面消极,也有积极影响。疫情将促进染料行业绿色发展,推动染料行业走向信息化、智能化时代,走向高质量发展,指出只要坚持绿色、创新和智能化,就能战胜疫情,推动中国染料行业稳健发展。     

基于氮掺杂碳纳米颗粒荧光猝灭-恢复方法检测还原型谷胱甘肽

分别以海藻酸钠和色氨酸为碳源和氮源,采用固相法一步合成出了量子产率为47.9%的氮掺杂荧光碳纳米颗粒(N-CNPs)。根据铜离子存在的条件下,N-CNPs荧光强度的恢复情况与还原型谷胱甘肽浓度成正比的关系,建立基于N-CNPs检测还原型谷胱甘肽的新方法。优化了溶液pH及反应时间等条件。在pH 6.0、铜离子浓度30μmol/L条件下,谷胱甘肽在0.2~45μmol/L浓度范围内与N-CNPs荧光恢复强度呈良好的线性关系,检出限为50 nmol/L。方法具有灵敏度高、选择性好、操作简单等优点,可用于实际样品中谷胱甘肽的检测。