Oxidation Behavior of Ni-3,6, 10 wt.% Al Alloys at 800°C

The oxidation behavior of Ni and Ni-3, 6, and 10Al alloys at 800°C in an N₂–O₂ gas mixture was investigated. The mass gain of each alloy depended on both the oxidation periods and Al content. NiO scale was formed on all alloy substrates accompanied by internal oxides of Al₂O₃. Many cavities were formed at the NiO/substrate interface at shorter oxidation times, and these cavities were found to be filled by metallic Ni(Al) from the matrix in the internal-oxidation zone by the development of internal oxides. The filling of cavities by Ni(Al) was more significant on higher Al alloys, which had a higher density of internal Al₂O₃. Once metallic Ni(Al) formed along the entire NiO/substrate interface, the oxidation kinetics became the same as pure Ni. It was concluded that pure Ni filling the cavities at the interface provided a diffusion path of Ni from the substrate to the NiO scale, and that controlled the oxidation kinetics.     

冲击角度对SiC/钢基表面复合材料冲蚀磨损性能的影响

采用负压铸渗工艺制备SiC／钢基表面复合材料，研究不同冲击角度对其冲蚀磨损性能的影响及其冲蚀磨损机理。结果表明，复合材料的冲蚀磨损率随冲击角α的增大先增大后减小，60°时最大；SiC／钢基表面复合材料的相对耐冲蚀性在45°时最大，为Q235钢的3．82倍。随着冲击角度的变化，切削作用和冲击作用对基体的支撑效应和颗粒对基体的阴影效应产生很大的影响，从而影响复合材料的冲蚀磨损性能。     

轻轨换轮装置液压系统管路特性分析

液压系统的管路动态特性分析是一个非常复杂的问题，特别是对于复杂的管路系统。本文针对轻轨换轮装置液压缸前的管道偶尔产生强烈振动的现象，采用传递矩阵方法对液压管路和油缸的振动特性建立了数学模型，并在MATLAB中进行了仿真，结果表明预先增大油缸中的充油容积、增大油液粘度、减小管道直径可避免此现象的发生。     

原位AlN-TiC粒子增强铝基复合材料

在真空感应炉中，900-1200℃，以合适的方位将含N，C原子的气体注入熔融的含Ti等的铝合金中，直接原位反应生成0．2-1．2μm的AlN和2-5μm的TiC粒子，均布于铝合金基体中，制成性能优异的复合材料，本工艺具有增强颗粒生成速度快的特点。     

GCr15钢花键轴套冷挤成形

对GCr15钢花键轴套零件的冷挤压工艺进行了分析 ,制定了先正挤花键后镦挤球头体的挤压方案 ,并介绍了该零件的冷挤压模结构及其特点     

硼酸铝晶须增强Al复合材料的性能及界面结构

采用挤压铸造工艺制备出复合良好的9Al_2O_3 2B_2O_3晶须增强6061Al合金及纯Al复合材料研究表明,T6处理不能提高9Al_2O_3 2B_2O_3w/6061Al复合材料的力学性能,其原因是T6处理后复合材料中的界面反应明显加重利用透射电子显微术对此复合材料界面的观察与分析认为,界面上存在着严重的化学反应,反应物为Al_2MgO_4将制造态与T6态的界面结构对比发现,正是这种界面化学反应对材料的性能产生不利影响而在9Al_2O_3 2B_2O_3w/纯Al界面上未发现任何化学反应。界面能谱EDS成分分析结果表明,上述界面化学反应是由材料制造过程中基体合金中的Mg在界面上原子偏聚造成的     

碳化硅颗粒增强铝基复合材料的重熔和铸造工艺特征

介绍了SiC颗粒增强铸造铝基复合材料的铸锭重熔、除气和铸造过程的特征。由于颗粒的存在 ,这些工艺过程和普通铝合金有一定的差异。在铸锭重熔时 ,需要控制熔炼温度和对熔体施加搅拌 ,以防止颗粒反应和下沉。普通铝合金采用的熔盐和气体除气工艺不适合于复合熔体的除气精炼 ,而真空除气具有很好的效果。复合熔体具有高的粘度 ,流动性较差 ,在大气自由重力浇注时容易卷入气体而导致铸件气孔缺陷。为了防止铸件缺陷的形成 ,复合材料在大气自由重力浇注下的浇注系统需要设计集气、集渣冒口和阻流口等特殊组元。真空差压浇注工艺大大简化了浇注系统 ,降低了材料消耗 ,同时消除了大气自由重力浇注时容易产生的铸造缺陷。通过该工艺可获得形状复杂、表面光洁、尺寸精确的铝基复合材料精密铸件     

等离子熔化-注射WC金属陶瓷层组织研究

采用等离子熔化-注射技术,在Q235钢表面制备WC-17%颗粒增强金属陶瓷复合层,利用扫描电镜(SEM)和X射线衍射仪(XRD)对金属陶瓷复合层进行组织形貌观察和分析,结果表明等离子熔化-注射技术制备的复合层与基体为冶金结合,复合层内WC颗粒分布均匀,没有明显的沉底现象,且在复合层上部还存在大量的块状组织,保留着陶瓷粉末颗粒的原始形状和尺寸,未发现裂纹.     

草酸盐共沉淀法制备金刚石金属结合剂

以制备金刚石金属结合剂为目的,本文研究了用共沉淀法制备的含草酸亚铁、草酸铜和草酸镍为所需比例的三组分共沉淀作为金属结合剂前驱体,然后还原制得金属结合剂.研究了草酸盐共沉淀中的各组分的收率,确定了共沉淀的最佳反应条件:溶液浓度(Fe2 )0.38 mol/L,反应温度50℃,反应时间1 h,氢氧化钠和草酸物质的量的比值为1～2:1.通过TPR和MS谱研究了共沉淀的分解还原过程及产物形态,研究发现,两者的加入能降低草酸亚铁的还原温度,共沉淀分解还原后生成合金粉末;对合金粉末进行了机械性能测定,结果表明:合金粉具有较好的硬度,比机械混合的结合剂提高20%以上,抗弯强度略有下降,但二者配合使用有较好的效果.     

Deformation and failure mechanism of nano-composite coatings under nano-indentation

Two nano-composite coatings based on nc-TiC particles in an a-C:H matrix are deposited via closed-field unbalanced reactive magnetron sputtering. The compositions of the coatings are varied by changing the acetylene gas flow during the depositions. A Cr/Cr–Ti/Ti–TiC graded interlayer is introduced between substrate and coating. Electron probe micro-analyses (EPMA) show that the Ti content of the coatings varies between 31.7 and 11.5 at.%. The coatings exhibit a hardness (H) of 20.0 and 15.7 GPa, and a Young's modulus (E) of 229.4 and 136.6 GPa, respectively, as measured through nano-indentations. Cube corner indentations are performed to probe the fracture toughness of the coatings through the determination of critical indentation loads (L_r) at which radial cracks start to propagate. Transmission electron microscopy (TEM) observations and energy-filtered TEM are employed to characterize the coatings nanostructures. The variation in Ti content is accompanied by a variation in TiC particle size and volumetric fraction, as well as a change in the columnar structure of the coatings. A focus ion beam (FIB) slicing technique is employed to prepare samples from nano-indented locations of coated Silicon and stainless steel (SS) substrates. TEM inspection of the FIB sliced samples determines that the most brittle phase in the coating is the C-enriched columnar boundary, and identifies the location of failure within the interlayer. As a consequence of the different nanostructure, the coatings exhibit different elastic recovery properties and toughness.