无模板剂水热合成Bi12O17Cl2纳米带及其阻燃性能研究

以β-Bi2O3为原料,采用无模板剂水热法制备了Bi_(12)O_(17)Cl_2纳米带,利用X射线衍射(XRD)、扫描电镜(SEM)、透射电镜(TEM)和高分辨透射电镜(HRTEM)对其形貌和结构进行了表征并作为阻燃剂添加到聚氯乙烯(PVC)中评价其阻燃性能。结果表明,适宜的Bi/Cl物质的量比对水热合成Bi_(12)O_(17)Cl_2纳米带及其化学计量比影响显著,当Bi/Cl物质的量比为1∶2.5时,可得到分散性好、形貌均匀的Bi_(12)O_(17)Cl_2纳米带;改变Bi/Cl物质的量比,纳米带中Bi/Cl化学计量比从6∶1变成2.4∶1。初步探讨了Bi_(12)O_(17)Cl_2纳米带可能的生长机理,在水热反应过程中,Bi 3+与Cl-发生络合反应形成BiCln3-n络合物,从而合成Bi_(12)O_(17)Cl_2纳米带。     

无机固体电解质Li7La3Zr2O12的制备及掺杂改性研究进展

无机固体电解质由于其安全性能高、能量密度大等特点备受研究者的青睐。其中Garnet型锂离子无机固体电解质Li_7La_3Zr_2O_(12)具有较高的离子导电率,较低的界面电阻,优良的稳定性能和电化学性能,在未来的全固态锂离子电池、锂空气电池等领域有着广阔的应用前景。主要从Li_7La_3Zr_2O_(12)的晶体结构、制备工艺和掺杂改性等方面详细阐述无机固态电解质Li_7La_3Zr_2O_(12)的研究进展。     

Effects of T5 heat treatment on extrusion welds in AZ80 hollow profile

AZ80 hollow profile was produced by porthole-die extrusion. The mechanical behavior and microstructure characteristic of extrusion welds in AZ80 hollow profile during different T5 heat treatments were investigated. Five kinds of morphologies of β-Mg₁₇Al₁₂ were observed in turn in weld regions under various temperatures. Extrusion weld is not weakest region in AZ80 hollow profile in terms of hardness, the peak hardness of weld regions is roughly equal to the weld-free regions at different aging temperatures, which is attributed to similar volume fraction, morphology, and size of β-Mg₁₇Al₁₂ precipitate in weld regions and weld-free regions. The precipitate-free zones (PFZs) usually form near the welds interface in aging process, and the hardness of PFZs is usually lower than those of weld regions and weld-free regions. Aging at 200°C for 24?h is suitable heat treatment system for AZ80 hollow profile, which can achieve excellent mechanical property and simultaneously reduce the width of PFZs.     

Bending impact on the performance of a flexible Li4Ti5O12-based all-solid-state thin-film battery

The growing demand of flexible electronic devices is increasing the requirements of their power sources. The effect of bending in thin-film batteries is still not well understood. Here, we successfully developed a high active area flexible all-solid-state battery as a model system that consists of thin-film layers of Li₄Ti₅O₁₂, LiPON, and Lithium deposited on a novel flexible ceramic substrate. A systematic study on the bending state and performance of the battery is presented. The battery withstands bending radii of at least 14 mm achieving 70% of the theoretical capacity. Here, we reveal that convex bending has a positive effect on battery capacity showing an average increase of 5.5%, whereas concave bending decreases the capacity by 4% in contrast with recent studies. We show that the change in capacity upon bending may well be associated to the Li-ion diffusion kinetic change through the electrode when different external forces are applied. Finally, an encapsulation scheme is presented allowing sufficient bending of the device and operation for at least 500 cycles in air. The results are meant to improve the understanding of the phenomena present in thin-film batteries while undergoing bending rather than showing improvements in battery performance and lifetime.     

基于均方误差修正的渗碳12CrNi3钢疲劳强度预测模型

为对渗碳12CrNi₃合金钢提供一种安全可靠的高周疲劳强度预测方法,本文利用高频疲劳测试机,在10⁴～10⁸循环周次内对渗碳12CrNi₃合金钢疲劳试样开展应力比为-1的高周疲劳实验。采用灰色估计法对渗碳12CrNi₃钢疲劳数据的威布尔W(α,β,γ)参数进行评估,并通过估算的威布尔参数,进一步确定渗碳12CrNi₃合金钢强度预测模型的参数。考虑应力-寿命关系,结合疲劳数据的威布尔分布规律,建立了失效概率为1%时的渗碳12CrNi₃合金钢高周疲劳强度预测模型。从预测疲劳强度安全可靠性出发,通过均方误差(MSE)方法对模型进行修正,并将修正后模型99%MSE下界线与渗碳12CrNi₃合金钢疲劳寿命P-S-N曲线(不同存活率P的S-N曲线)进行对比,研究发现12CrNi₃合金钢疲劳寿命数据点均位于模型99%MSE下界线内,预测结果很好。研究表明,在以渗碳12CrNi₃合金钢...     

嵌入式地址智能分配系统的设计与实现

针对传统的地址固化方式存在设备维修互换困难的问题,提出了一种嵌入式地址智能分配系统的设计方案。该系统从第一个通信模块即第一台设备开始,由近及远依次自动编号,地址号存入到每个通信模块的数据存储器中,并可随时通过串口输出。该系统中所有的通信模块的硬、软件完全相同,使设备的维修互换不受任何影响、摆放位置不受限制。实际应用表明,该系统设计合理,能够准确地分配地址。     

基于STC12C5A08AD教室节能控制系统的设计

教室节能系统主要以节电为主要目标,以STC12C5A08AD单片机作为系统的控制器,通过光照度检测电路,红外人数检测电路检测教室内的光照情况和人员数量,控制器根据检测到的数据计算出需要打开的灯管数量,并向电源控制电路发出控制命令,合理的安排教室内的灯管使用数量,实现节能目的。     

基于蓝牙技术的智能车实时监测系统的研究

研究开发了以Freescale公司MC9S12DG128单片机为核心控制单元的智能车无线监测系统。系统主要由传感器模块、数据采集与处理模块、UART通讯模块、蓝牙通讯模块、上位机模块组成。详细介绍了以上4个模块的设计开发。经过测试表明,此系统工作稳定,对于摄像头图像的显示,速度曲线的绘制,PID参数修正等功能完全满足智能车调试的需求。     

HCS12X单片机的SD卡FAT文件系统读写设计

基于HCS12X单片机SPI模块读取Micro SD卡与SD卡,并解析SD卡上FAT文件系统以实现文件的读取与写入。测试证明,系统对FAT文件系统的读取稳定,误差小,速度较快。使用HCS12X类单片机对SD卡进行读取,在汽车智能设计和单片机调试方面有较高的应用价值。     

从MC9S12D到MC9S12XS

从第四届全国大学生"飞思卡尔"杯智能车竞赛开始,竞赛组委会推荐使用MC9S12XS128单片机替代前三届竞赛中使用的MC9S12DG128。S12X是新一代双核单片机,制造工艺从0.25μm进步到0.18μm;总线频率从25MHz提高到40MHz;S12XS单片机保留了S12X CPU,去掉了另一个CPU-XGate,保留了技术进步,提高了性能,简化了操作。