钢混结构大型厂房整体式爆破拆除

采用整体式控制爆破拆除方案对华电扬州电厂钢筋混凝土框-排架结构厂房进行了爆破拆除。爆破前,对汽机房、厂房外墙和楼梯进行了预处理。将厂房划分为3个爆区,采用非电多回路网格式爆破网路,依靠东侧锅炉房倒塌施加在西侧锅炉房上的倾覆力矩,有效地克服了西侧锅炉房向西倒的难题,可为同类工程提供一定的参考。     

Comparative study of EICP treatment methods on the mechanical properties of sandy soil

This study analyzed the effect of different treatment methods in enzyme-induced carbonate precipitation (EICP) on the mechanical properties of soil. Soybean crude urease was used to catalyze the precipitation of calcium carbonate (CaCO₃). A multiple-phase method was proposed and further compared with commonly practiced EICP treatment methods (including the one-phase method, two-phase method, and premix-and-compact method) from the aspects of chemical conversion efficiency, CaCO₃ precipitation distribution, permeability, and unconfined compressive strength. Based on the findings, the characteristics of each method were further discussed and summarized. Although the enzymatic CaCO₃ precipitation generated from all the treatment methods could potentiate the soil strength to a great or less degree, using the proposed multiple-phase method could bring about a high chemical conversion efficiency, uniform distribution of CaCO₃ as well as preferable permeability retention. In addition, the multiple-phase method could significantly improve the efficiency of urease usage.     

Thermal transport and chemical conversion in single reacting sorbent particles

The effects of particle size and carbon dioxide concentration on chemical conversion in engineered spherical particles undergoing calcium oxide looping are investigated. Particles are thermochemically cycled in a furnace under different carbon dioxide concentrations. Changes in composition due to chemical reactions are measured using thermogravimetric analysis. Gas composition at the furnace exit is evaluated with mass spectroscopy. A numerical model of thermal transport phenomena developed previously is adapted to match the physical system investigated in the present study. The model is used to elucidate effects of reacting medium characteristics on particle temperature and reaction extent. Experimental and numerical results show that (1) an increase in particle size results in a decrease in carbonation extent, and (2) the carbonation step consists of fast and slow reaction regimes. The reaction rates in the fast and slow carbonation regimes increase with increasing carbon dioxide concentration. The effect of carbon dioxide concentration and the distinction between the fast and slow regimes become more pronounced with increasing particle size.     

Extraction and characterization of hydroxyapatite-based materials from grey triggerfish skin and black scabbardfish bones

The conversion of food industry by-products to compounds with high added value is nowadays a significant topic, for social, environmental, and economic reasons. In this paper, calcium phosphate-based materials were obtained from black scabbardfish (Aphanopus carbo) bones and grey triggerfish (Balistes capriscus) skin, which are two of the most abundant fish by-products of Madeira Island. Different calcination temperatures between 400 and 1000°C were employed. Materials obtained from calcination of bones of black scabbard fish were composed by homogeneous mixtures of hydroxyapatite (Ca₁₀(PO4)₆(OH)₂, HAp) and β-tricalcium phosphate (β-Ca₃(PO₄)₂, β-TCP). Because of the high biocompatibility of HAp and the good resorbability of β-TCP, these natural biphasic materials could be very relevant in the field of biomaterials, as bone grafts. The ratio between HAp and β-TCP in the biphasic compound was dependent on the calcination temperature. Differently, the material obtained from skin of grey triggerfish contained HAp as the main phase, together with small amounts of other mineral phases, such as halite and rhenanite, which are known to enhance osteogenesis when used as bone substitutes. In both cases, the increase of calcination temperature led to an increase in the particles size with a consequent decrease in their specific surface area. These results demonstrate that from the fish by-products of the most consumed fishes in Madeira Island it is possible to obtain bioceramic materials with tunable composition and particle morphology, which could be promising materials for the biomedical field.     

Reduced‐scale test to assess the effect of fire barriers on the flaming combustion of cored composites: An upholstery‐material case study

Herein, we describe a reduced‐scale test (“Cube” test), measuring the fire performance of specimens including a fire barrier (FB) and a flammable core material, which acts as the main fuel load. The specimen is intended to reproduce a cross‐section of a composite product where heat/mass transfer occurs primarily in a direction perpendicular to the FB. The Cube test procedure and benefits are discussed in this work by adopting residential upholstery furniture as an exemplary study. One flexible polyurethane foam, one polypropylene cover fabric, and 10 commercially available FBs were selected. They were used to compare the fire performance of FBs, measured in terms of peak of heat release rate, in the ASTM E1474‐14 standard test and the newly developed Cube test. Edge effects severely affected the performance of FBs in the ASTM E1474‐14 standard test but not in the Cube test. Furthermore, appropriate test conditions were determined in the Cube test to measure the so‐called “wetting point,” that is, the time and value of heat release rate measured when flammable liquid products were first observed on the bottom of the specimen. The relevance of the “wetting point” in terms of full‐scale fire performance and failure mechanism of FBs is discussed.     

Improving water retention of chicken breast meats by CaCl2 combined with pulsed electric fields

Frozen poultry meat is the most widely consumed animal-based food. However, water loss often leads to quality loss of poultry meat. Therefore, the present study sought to investigate the combined effect of calcium chloride (CaCl₂) and pulsed electric fields (PEF) treatment on chicken breast meats and the mechanisms underlying protein degradation. The results showed that the synergistic effect was superior to the single treatment. Compared with the untreated group, the combination of CaCl₂ and PEF increased water holding capacity of chicken breast meats by 16.61% and decreased cooking loss by 28.93%. Low-field nuclear magnetic resonance (LF-NMR) results indicated that the synergistic treatment promoted water molecules' binding capacity in myofibrils of poultry meat, which exhibited higher immobilised water. Additionally, the combination of CaCl₂ and PEF led to increased degradation of proteins of high-molecular weight and surface hydrophobicity of myofibrillar protein. Furthermore, the extension of the protein molecule and microenvironmental changes promoted interaction between protein and water. In conclusion, the synergistic treatment of CaCl₂ and PEF enhanced water retention and improved physicochemical properties of the myofibrillar protein in chicken breast meats.     

High-temperature behavior of oxide dispersion strengthening CoNiCrAlY

To fabricate oxide dispersion strengthened bond coatings, commercial Co–30wt-%Ni–20Cr–8Al–0?4Y powder was milled with 2% additions of Al₂O₃, Y₂O₃ or Y₂O₃ + HfO₂. Low-pressure plasma sprayed, free-standing specimens were oxidised in air + 10%H2O at 1100 °C both isothermally (100 h) and in 500, 1?h cycles. Dry air cyclic testing conducted at both ORNL and FZJ showed remarkably similar results. In general, the water vapour addition caused more scale spallation. Two LPPS specimens without oxide additions were tested for comparison. The specimens with 2%Al₂O₃ addition exhibited the best behaviour as the powder already contained 0?4%Y. Additions of 2%Y₂O₃ and especially 1%Y₂O₃ + 1%HfO₂ resulted in over-doping as evidenced by high mass gains and the formation of Y- and Hf-rich pegs. Scanning transmission electron microscopy of the isothermal specimens showed no Hf and/or Y segregation to the alumina scale grain boundaries in the over-doped specimens.     

小尺度交通信号灯的检测与状态识别

交通信号灯识别包括检测和状态识别，在智能交通系统中发挥重要作用。基于YOLOv3算法提出了一种交通信号灯检测与状态识别模型。针对交通信号灯相较于交通场景中其他目标具有尺度小的特性进行了算法的设计：降低骨干网络的下采样倍率以增加小尺度目标的特征描述能力；通过增大特征图的尺度来改进多尺度特征融合；引入广义交并比作为检测任务的损失函数来改进目标边界框的回归效果。同时，根据交通信号灯本身的特性，使用颜色和形状约束的方法对信号灯进行状态识别和类别验证。最后在公开的Bosch交通信号灯数据集上和实际的城区道路进行了实验验证。实验结果表明，所提出的算法能够提升交通信号灯识别的精度和召回率，识别准确率可以达到90%左右。     

等温滴定量热法探索酪蛋白磷酸肽单体与不同钙盐的相互作用

本研究探讨了在模拟小肠末端环境下酪蛋白磷酸肽（β-casein phosphopeptides(1-25)，简称CPP）与不同钙盐的相互作用情况。实验以等温滴定量热仪为方法，以热力学参数、化学计量数及亲和力常数为指标，评价不同钙盐与CPP的相互作用情况。结果表明，CPP与不同钙盐两两相互作用，且均为由熵驱动的自发反应（pH 8.0，37 ℃），该反应的主要推动力为离子相互作用力。不同钙盐与CPP反应时，焓变，熵变及自由能无明显差别（p>0.05），而化学计量数和亲和力常数存在显著性差异（p<0.05）。CPP与葡萄糖酸钙，乳酸钙和氯化钙相互作用时，化学计量数较高（3~4 mol/mol），而与天冬氨酸钙结合的化学计量数较低（2~3 mol/mol）。此外，相比其他钙盐，乳酸钙与CPP结合的亲和力常数最低。多肽与钙盐结合数高且亲和力较低时有利于小肠对钙的吸收。因此，相对于其他钙盐，CPP与乳酸钙结合可能更有利于小肠对钙的吸收。本研究为更好地了解CPP与不同钙盐溶液在模拟小肠末端环境下的热力学变化及结合情况奠定坚实的基础。