特种工程胎硫化外胎质量缺陷原因分析以及解决措施

我公司使用的硫化机采用氮气定型,二次水硫化的工艺。由于特种工程胎胎体偏厚且大,成型机都比较大,生产过程中的帘布筒、钢丝、胎侧等部件都比较重且大。成型胎面使用胎面缠绕机缠绕,所以整个生产过程难度较大。特种工程胎硫化外胎的主要质量问题有:胎面皮泡、胎侧缺胶、胎侧泡、胎肩侧皮泡、子口内侧露线、子口缺胶、胎肚内缺(窝气)、胎肚露线、胎肚皮泡、胎肚串泡、子口支边、胎冠支边、子口鼓包、外胎花缺等。通过对特种工程胎硫化外胎质量缺陷原因分析,找到相应的解决措施,从而减少硫化外胎质量缺陷。     

Evidence of fluid evolution of Baoshan Cu−Pb−Zn polymetallic deposit: Constraints from in-situ sulfur isotope and trace element compositions of pyrite

In-situ LA-ICP-MS and S isotopes of pyrite from the Baoshan Cu polymetallic deposit were conducted to investigate the ore-forming process and the enrichment mechanism of elements. Three generations of pyrite (Py I, Py II, and Py III) in the skarn-type ores and pyrite in the carbonate-hosted sulfide ores from central, western, and northern (C_Py, W_Py, and N_Py) mining districts are selected for comparison. Compared with Py I and Py III, the contents of most elements in Py II are apparently higher. The As and Se contents are high within a wide range and are decoupled in the growth band of the C_Py. The highest As, Se, and Pb contents were found in W_Py and N_Py. These results indicate the drastic changes in the temperature and fluid mixing during the mineralization. The occurrence of fluctuation and change in temperature and f(O₂) was triggered by intermittent pulses of magmatic-hydrothermal fluids, mixing with meteoric water, and water−rock interactions. The sulfur isotopes of all species of pyrite indicated the magmatic source. The change in the f(O₂) conditions caused slight differences in the sulfur isotope compositions. Consequently, a metallogenic model was proposed to explain the ore-forming processes.     

一种新型的室温快速固化胶黏剂的研制

本文开发了一种新型的方舱夹芯板用室温固化高强度环氧结构胶黏剂,验证了其物化特性、相关力学性能和环境适应性。结果表明此胶黏剂具有优良性能,可以满足方舱用大板胶黏剂的使用需求。     

关于多功能液压支架拖运车的电控系统设计

本文简介多功能液压支架拖运车的电控系统,包括电控箱的设计和主要电气元件的性能和选择依据。此电控系统能够一般电控系统的各种功能和保护,而且能够通过摄像头做到操作盲区和使用遥控器进行远程控制,从而提高液压支架的拖运效率、降低劳动强度和提高安全保障。     

A modified Kozeny–Carman equation for predicting saturated hydraulic conductivity of compacted bentonite in confined condition

Kozeny–Carman (KC) equation is a well-known relation between hydraulic conductivity and pore properties in porous material. The applications of KC equation to predicting saturated hydraulic conductivities of sands and non-expansive soils are well documented. However, KC equation is incapable of predicting saturated hydraulic conductivity of expansive soil (e.g. bentonite) well. Based on a new dual-pore system, this study modified KC equation for improving the prediction of saturated hydraulic conductivities of bentonites. In this study, an assumption that inter-layer space (micropore) has limited effect on fluid flow performance of compacted bentonite was adopted. The critical parameters including total porosity and total tortuosity in conventional KC equation were replaced by macroporosity and tortuosity of macropore, respectively. Macroporosity and microporosity were calculated by basal spacing of compacted bentonite, which was estimated by assuming that specific surface area is changeable during saturation process. A comprehensive comparison of bentonite's saturated hydraulic conductivity predictions, including modified KC equation proposed in this study, conventional KC equation, and prediction method based on diffuse double layer (DDL) theory, was carried out. It was found that the predicted saturated hydraulic conductivity of bentonites calculated using modified KC equation fitted the experimental data better than others to a certain extent.     

Hydraulic reactivity and cement formation of baghdadite

In this study, the hydraulic reactivity and cement formation of baghdadite (Ca₃ZrSi₂O₉) was investigated. The material was synthesized by sintering a mixture of CaCO₃, SiO₂, and ZrO₂ and then mechanically activated using a planetary mill. This leads to a decrease in particle and crystallite size and a partial amorphization of baghdadite as shown by X-ray powder diffraction (XRD) and laser diffraction measurements. Baghdadite cements were formed by the addition of water at a powder to liquid ratio of 2.0 g/ml. Maximum compressive strengths were found to be ~2 MPa after 3-day setting for a 24-h ground material. Inductively coupled plasma mass spectrometry (ICP-MS) measurements showed an incongruent dissolution profile of set cements with a preferred dissolution of calcium and only marginal release of zirconium ions. Cement formation occurs under alkaline conditions, whereas the unground raw powder leads to a pH of 11.9 during setting, while prolonged grinding increased pH values to approximately 12.3.     

Sustainable phenolic thermosets coatings derived from urushiol

The over-exploitation of finite fossil resources and/or the increased environmental and sustainable awareness inspire scientists and technologists to search for inexpensive alternatives from renewable chemicals. Phenol formaldehyde (PF) resins, the oldest type of synthetic polymers with good mechanical properties and heat resistance, are widely used in the production of coatings, laminates, molding compositions, and glues. Here, biobased urushiol-derived PF resins were synthesized from the alkali-catalyzed reaction between urushiol and formaldehyde. The chemical compositions and molecular structures of resole resins were characterized by carbon-13 nuclear magnetic resonance and Fourier transform infrared spectroscopy, and their curing behaviors were studied by differential scanning calorimetry. The as-prepared urushiol-derived resole resins had methylol (Ph−CH₂OH), ortho- and para-hemiformal groups (Ph−CH₂OCH₂OH), and the para−para/ortho−para/ortho−ortho links of methylene groups (Ph−CH₂−Ph), whereas the resole resins had low curing temperatures at about 100–113°C. Additionally, given the long side alkyl group moiety on the aromatic rings of urushiol, the films of cured urushiol-derived resole resins had low glass transition temperatures of 132 ± 2°C. Furthermore, the as-prepared urushiol-derived coatings exhibited excellent physical and mechanical properties.     

Spreading and Curing Behaviors of a Thermosetting Droplet-Silicone on a Heated Surface

Thermosetting materials are widely used as encapsulation in the electrical packaging to protect the core electronic components from external force, moisture, dust, and other factors. However, the spreading and curing behaviors of such kind of fluid on a heated surface have been rarely explored. In this study, we experimentally and numerically investigated the spreading and curing behaviors of the silicone(OE6550 A/B, which is widely used in the light-emitting diode packaging) droplet with diameter of ～2.2 mm on a heated surface with temperature ranging from 25 ℃ to 250 ℃. For the experiments, we established a setup with high-speed camera and heating unit to capture the fast spreading process of the silicone droplet on the heated surface. For the numerical simulation, we built a viscosity model of the silicone by using the Kiuna's model and combined the viscosity model with the Volume of Fluid(VOF) model by the User Defined Function(UDF) method. The results show that the surface temperature significantly affected the spreading behaviors of the silicone droplet since it determines the temperature and viscosity distribution inside the droplet. For surface temperature varied from 25 ℃ to 250 ℃, the final contact radius changed from ～2.95 mm to ～1.78 mm and the total spreading time changed from ～511 s to ～0.15 s. By further analyzing the viscosity evolution of the droplet, we found that the decreasing of the total spreading time was caused by the decrease of the viscosity under high surface temperature at initial spreading stage, while the reduction of the final contact radius was caused by the curing of the precursor film. This study supplies a strategy to tuning the spreading and curing behavior of silicone by imposing high surface temperature, which is of great importance to the electronic packaging.     

微型土压平衡盾构机液压系统故障分析

以微型土压平衡(Earth Pressure Balance,EPB)盾构机推进液压系统作为研究对象,介绍了推进系统的工作原理,对混入空气后的油液黏度和有效体积弹性模量进行分析,建立了推进系统数学模型,并对混入不同百分比空气的系统进行仿真运算,得到了液压缸位移响应和速度响应随系统含气量变化的关系。研究表明:随着液压系统空气含量的增加,液压缸位移响应发生迟滞,速度响应变慢,液压缸在运动时产生振动。结合各液压元件工作原理,依次对实际盾构机推进系统元件进行排气,最终排除了液压系统中混入的空气,为实现盾构机平稳推进提供了理论依据。     

稀土La2O3改性脲醛树脂的黏度特性研究

脲醛树脂(UF树脂)胶黏剂具有胶合强度高、制作简单、成本低廉、原料来源丰富等一系列特点,成为我国人造板生产的主要胶种,是市场上需求量最大的胶黏剂之一。但由于在固化时会放出刺激性的甲醛,游离甲醛高,在使用时严重危害人的健康。近年来,随着人们环保意识的提高,生产和使用低毒UF树脂胶势在必行。本文介绍了稀土氧化镧对脲醛树脂的改性过程并对改性后脲醛树脂胶的各项性能进行了测试。本实验通过在不同反应阶段加入稀土氧化镧,分别探讨它们对脲醛树脂胶黏剂性能影响。实验表明:在脲醛树脂胶中加入稀土氧化镧可以增加黏度、固化时间、固含量,并可以减少游离甲醛释放量。