Review: the latest advances in biomedical applications of chitosan hydrogel as a powerful natural structure with eye-catching biological properties

Journal of Materials Science - Chitosan is one of the natural cationic polymers with unique properties such as non-toxicity, biodegradability, biocompatibility, environmentally friendly that has...     

A high step‐up half‐bridge DC/DC converter with a special coupled inductor for input current ripple cancelation and extended voltage doubler circuit for power conditioning of fuel cell systems

This paper presents a high step‐up soft switched dc–dc converter having the feature of current ripple cancelation in the input stage that is specialized for power conditioning of fuel cell systems. The converter comprises a special half‐bridge converter and a rectifier stage based upon the voltage‐doubler circuit, in which the coupled‐inductor technology is amalgamated with switched‐capacitor circuit. The input current with no ripple is the principal characteristics of this topology that is achieved by utilizing a small coupled inductor. In addition, the low clamped voltage stress across both power switches and output diodes is another advantage of the proposed converter, which allows employing the metal–oxide–semiconductor field‐effect transistors with minuscule on‐state resistance and diodes with lower forward voltage‐drop, and thereby, the semiconductors' conduction losses diminish considerably. The inherent nature of this topology handles the switching scheme based on the asymmetrical pulse width modulation in order for switches to establish the zero voltage switching, leading to lower switching losses. Besides, because of the absence of the reverse‐recovery phenomenon, all diodes turn off with zero current switching. At last, a 250‐W laboratory prototype with the input voltage 24 V and output voltage 380 V is implemented to verify the especial features of the proposed converter. Copyright © 2015 John Wiley & Sons, Ltd. Copyright © 2015 John Wiley & Sons, Ltd.     

An encoding scheme based on fractional number for querying and updating XML data

In order to facilitate the XML query processing, several labeling schemes have been proposed to directly determine the structural relationships between two arbitrary XML nodes without accessing the original XML documents. However, the existing XML labeling schemes have to re-label the pre-existing nodes or re-calculate the label values when a new node is inserted into the XML document during an update process. In this paper, we devise a novel encoding scheme based on the fractional number to encode the labels of the XML nodes. Moreover, we propose a mapping method to convert our proposed fractional number based encoding scheme to bit string based encoding scheme with the intention to minimize the label size and save the storage space. By applying our proposed bit string encoding scheme to the range-based labeling scheme and the prefix labeling scheme, the process of re-labeling the pre-existing nodes can be avoided when nodes are inserted as leaf nodes and sibling nodes without affecting the order of XML nodes. In addition, we propose an algorithm to control the increment of label size when new nodes are inserted frequently at a fix place of an XML tree. Experimental results show that our proposed bit string encoding scheme provides efficient support to the process of XML updating without sacrificing the query performance when it is applied to the range-based labeling schemes.     

Query processing optimization in broadcasting XML data in mobile communications

Todays, XML as a de facto standard is used to broadcast data over mobile wireless networks. In these networks, mobile clients send their XML queries over a wireless broadcast channel and recieve their desired XML data from the channel. However, downloading the whole XML data by a mobile device is a challenge since the mobile devices used by clients are small battery powered devices with limited resources. To meet this challenge, the XML data should be indexed in such a way that the desired XML data can be found easily and only such data can be downloaded instead of the whole XML data by the mobile clients. Several indexing methods are proposed to selectively access the XML data over an XML stream. However, the existing indexing methods cause an increase in the size of XML stream by including some extra information over the XML stream. In this paper, a new XML stream structure is proposed to disseminate the XML data over a broadcast channel by grouping and summarizing the structural information of XML nodes. By summarizing such information, the size of XML stream can be reduced and therefore, the latency of retrieving the desired XML data over a wirless broadcast channel can be reduced. The proposed XML stream structure also contains indexes in order to skip from the irrelevant parts over the XML stream. It therefore can reduce the energy consumption of mobile devices in downloading the results of XML queries. In addition, our proposed XML stream structure can process different types of XML queries and experimental results showed that it improves the performace of XML query processing over the XML data stream compared to the existing research works in terms of access and tuning times.

     

Raman spectroscopy and TEM characterization of solid particulate matter emitted from soot generators and aircraft turbine engines

To obtain reliable mass concentrations of solid particulate matter (PM) in the exhaust emissions from engines using optical instruments, it is essential that the solid PM used for instrument calibration has similar optical properties to the solid PM emitted from the engines being tested. The solid PM emitted from combustion engines is predominantly soot. The optical properties of soot are dictated by its chemical structure, size, and morphology. In this work, the chemical bond structure, primary-particle diameters, aggregate sizes, and morphological parameters of the soot emitted from two laboratory soot generators, widely used for calibrating instruments, are compared to those of soot emitted from three aircraft turbine engines using Raman spectroscopy and transmission electron microscopy. The Raman spectral properties, size, and morphology of soot emitted from aircraft engines are distinctly different from the properties of soot emitted from the soot generators operating under globally near-stoichiometric and fuel-rich conditions. These differences can be attributed to the variations in the size and orientation of the graphitic crystallites, amorphous-carbon content, amount of polyacetylene compounds, deposition of organic material, and extent of oxidation. Conversely, general agreement is observed between the chemical structure, size, and morphology of soot emitted from aircraft engines and the soot emitted from the soot generators operating at globally fuel-lean conditions. The findings of this investigation can be useful for identifying suitable soot particles for the calibration of instruments to measure the mass concentration of solid PM emissions from engines, and for other types of soot.

Copyright © 2017 Crown Copyright     

Synthesis, characterization and application of allyl phenol modified amberlite XAD-4 resin for preconcentration and determination of copper in water samples

A new chelating resin was prepared by coupling Amberlite XAD-4 with phenol through an azo spacer, then modified by allyl bromide and characterized (by elemental analysis and IR) and studied for preconcentration of Cu(II) using flame atomic absorption spectrometry (FAAS) for metal monitoring. The optimum pH value for sorption of the above mentioned metal ion was 4.5. The resin was subjected to chemical evaluation through batch binding and column chromatography of Cu(II). The chelating resin can be reused for 15 cycles of sorption-desorption without any significant change in sorption capacity. A recovery of 98% was obtained for the metal ion with 0.5 M HNO₃ as eluting agent. The equilibrium adsorption data of Cu(II) on modified resin were analyzed by Langmuir, Freundlich and Temkin models. Based on equilibrium adsorption data the Langmuir, Freundlich and Temkin constants were determined to be 0.061, 0.193 and 0.045 at pH 4.5 and 25 °C. The method was applied for the copper determination from industrial waste water sample.     

Effect of EPS beads in lightening a typical zeolite and cement-treated sand

Bulletin of Engineering Geology and the Environment - The current study aims to assess the influence of EPS beads inclusion on the strength properties of stabilized poorly-graded sands. Various...     

Creep analysis of an earth embankment on soft soil deposit with and without PVD improvement

In this paper, an anisotropic creep constitutive model, namely Creep-SCLAY1S is employed to study the installation effects of prefabricated vertical drains (PVDs) on the behavior of a full scale test embankment, namely Haarajoki embankment in Finland. The embankment was constructed on a natural soft soil with PVD installed to improve the drainage under one half of it. The Creep constitutive model used in this study, incorporates the effects of fabric anisotropy, structure and time within a critical state based framework. For comparison, the isotropic modified Cam clay (MCC) model and the rate-independent anisotropic S-CLAY1S model are also used for the analyses. The numerical predictions are compared with field measurements and the results indicate that the creep model provides an improved approximation of field settlements, and excess pore pressure build-up and dissipations. In addition, the application of two commonly used permeability matching techniques for two dimensional (2D) plane-strain analysis of the PVD problem is studied and the results are discussed highlighting their limitations and advantages.     

The evolution of soot morphology in a laminar coflow diffusion flame of a surrogate for Jet A-1

An experimental study is performed to investigate the evolution of soot morphology in an atmospheric pressure laminar coflow diffusion flame of a three-component surrogate for Jet A-1. The laser extinction measurement method and the rapid thermocouple insertion technique are used to obtain soot volume fraction profiles and temperature profiles, respectively. Thermophoretic sampling followed by transmission electron microscopy and atomic force microscopy is used to study the morphology of soot particles at different locations inside the flame. Soot formation on the centerline appears to be different from conventional models. Liquid-like particles, which are transparent at the wavelength of 623 nm, are formed and grow up to a volume equivalent diameter of d_p = 60 nm at temperatures below T = 1500 K. When the temperature exceeds 1500 K, transition of the transparent particles to the mature agglomerated particles happens immediately, i.e. in less than 12 ms. The volume of the liquid-like particles just before the start of their transformation to solid is about five times larger than the volume of mature primary particles. This significant size difference suggests that a large liquid-like particle does not transform into a single primary particle. In addition, multiple dark nuclei are observed in the liquid-like particles prior to carbonization. The significant size discrepancy and the presence of multiple dark nuclei may indicate that primary particle formation and agglomeration on the centerline happen inside the liquid-like particles. In contrast to the centerline, on another streamline with a significantly different temperature history, soot particles form from relatively small liquid-like particles. These particles have the same size as mature primary particles. Carbonization happens early on the streamline. A single dark nucleus grows inside each liquid-like particle and primary particles agglomerate after carbonization is completed. Most of the currently used computational soot models consider a single evolution process for all of the streamlines inside the flame which may not be an accurate assumption. This study shows that soot evolution processes may be different across the flame and are a function of temperature and the concentration of specific species inside the flame.