Self-healing,elastic and deformable novel composite phase change polymer based on thermoplastic elastomer SEBS for wearable devices

Journal of Materials Science - Form-stable composite phase change materials (C-PCMs) prepared by microencapsulation method and porous matrix adsorption method need for compression molding after...     

Polydopamine modified Au/FAU catalytic membrane for CO preferential oxidation

A hollow-fiber-supported stable Au/FAU catalytic membrane was successfully synthesized through a polydopamine coating modification-removal strategy and used as a flow-through catalytic membrane reactor for preferential oxidation of CO. Small Au nanoparticles can be efficiently isolated by dopamine and the dopamine-derived carbon shells. The interactions between Au nanoparticles and zeolite layer support are enhanced during annealing at high temperature under an inert atmosphere. A zeolite membrane supported Au nanoparticle catalyst was obtained after the removal of carbon shells, which showed high catalytic activity and stability for the removal of CO from hydrogen.     

滑动式Lagrange插值法在BDS星历插值中的应用分析

该文利用滑动式Lagrange插值算法,从三个方面对BDS三种星历进行了内插精度分析,并与传统La-grange插值算法做了比较.首先对比相同阶数下两种算法的非端点处插值结果的精度;其次考虑端点龙格现象,分析两种方法的端点插值结果的精度;最后根据计算结果的均方根误差,分析插值结果整体精度的大小,并采用BDS精密星历数据进行验证.研究结果表明,滑动式Lagrange插值算法的插值精度较高,且误差分布均匀,最高可达亚毫米级别.该方法较好地适用于BDS星历的内插.     

固体碱催化法合成壬基酚甲醛树脂的工艺研究

本文研究了以壬基酚和甲醛为原料,固体碱为催化剂,合成壬基酚醛树脂的新工艺。对酚醛比、催化剂用量、反应时间、反应温度四个影响因素进行了正交优化实验,确定了优化合成工艺,得到了黏度为20000 mPa·s左右的壬基酚醛树脂,该工艺稳定可靠。     

玻璃钢缠绕制品CAD/CAM系统

玻璃钢(FRP)缠绕(FW)制品具有比强度高，比刚度大等良好的性能，广泛应用于石油、化工、航空、航天等行业。玻璃钢缠绕制品CAD／CAM系统是一个FRP FW制品设计与生产的集成系统，它实现了FRP FW制品从原材料选择到最终控制缠绕机生产的全过程的一体化，大大提高了FRP FW新产品的质量和开发效率。本文介绍了系统的基本功能和结构。     

塑性变形条件下硬质合金中重位点阵晶界的特征分布

通过五参数法,测定了一种塑性变形条件下硬质合金结构中的两类重位点阵晶界,即Σ13a晶界和Σ2晶界,的晶界特征分布。通过与未经过塑性变形的试样进行对比,发现两类重位点阵晶界的数量以及相应惯习面的赋存频率,在塑性变形条件下都有所降低。通过对硬质合金试样结构中的晶界面类型进行精确区分,塑性变形条件下晶界特征分布的演进过程得到解释。     

基于正交试验的潜水器耐压壳体的结构优化设计

潜水器的质量大小直接影响其性能,设计时要求潜水器在满足强度、刚度等要求的前提下,要尽可能减小其质量。应用正交试验的方法来实现潜水器耐压壳体结构的优化,但用正交试验方法处理约束问题比较复杂。因此将以质量最小化为目标和以强度要求为约束条件的优化设计问题转化为无约束多目标的优化设计问题。得出各个参数对壳体的强度和质量的影响规律,最后运用综合平衡法得出最优的设计方案。     

氢基质生物膜反应器在饮用水处理中的研究进展

该文对氢基质生物膜反应器(MBf R)的作用机理、特性以及对饮用水中氧化性污染物的去除可行性进行了论述,并对国内外利用该技术去除饮用水中常见氧化性污染物(如:重金属离子:重铬酸盐、砷酸盐、硒酸盐等;无机阴离子:硝酸盐、溴酸盐、高氯酸盐;卤代有机化合物:对氯硝基苯、三氯乙烷、三氯乙烯、氯仿)的研究现状进行了总结。最后指出了MBf R研究中存在的问题以及在工程应用上的现状和发展前景。     

N‐halamine‐modified polyglycolide (PGA) multifilament as a potential bactericidal surgical suture: In vitro study

In this study, new cationic homopolymer and anionic copolymer were synthesized, and deposited onto polyglycolide sutures using a layer‐by‐layer assembly technique. The coated sutures were rendered antibacterial by chlorinating with dilute solution of household bleach solution at pH 7. The chlorination treatment transformed the N? H groups of anionic copolymer into N‐halamine structures. The N‐halamine‐modified sutures were challenged with Staphylococcus aureus and Escherichia coli O157:H7 bacteria at different contact times. The suture with chlorine loading of 0.22% completely inactivated both bacterial strains in 30 min contact time. Fourier transform infrared spectroscopy, scanning electron microscopy, and analytical titration confirmed the successful deposition of the N‐halamine multilayers. The effect of layer‐by‐layer coatings of polyelectrolytes on the chlorine loading and antibacterial efficacy of sutures was evaluated. The straight‐pull and knot‐pull strength tests performed on the sutures reported slight decline in tensile properties after chlorination treatment. The in vitro hemolysis and cytocompatibility tests revealed that the N‐halamines‐based antibacterial sutures were biocompatible. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42483.     

Improving the hydrophobicity of nylon fabric by consecutive treatment with poly(acrylic acid), tetraethylorthosilicate,and octadecylamine

Nylon fabric was consecutively treated with poly(acrylic acid) (PAA), tetraethylorthosilicate (TEOS), and octadecylamine (OA) to improve its hydrophobicity. We proposed that PAA could be used as a mediator between nylon and OA to provide a high density of the carboxyl moiety. TEOS was used to increase the surface roughness of the nylon fabric by hydrolysis and condensation, and OA was used to reduce the surface energy of the nylon fabric with its long alkyl chains. Both the increase in the surface roughness and the reduction in the surface energy contributed to the improvement of the hydrophobicity of the nylon fabric. The hydrophobicity of the treated nylon fabric was evaluated by the measurement of the water contact angle, water resistance to spray, and hydrostatic pressure. Scanning electron microscopy images showed that the surface roughness of the nylon fabric was significantly increased by treatment with TEOS. The nylon fabric with the PAA/TEOS/OA consecutive treatment exhibited a water contact angle of 125°, a resistance to water spray of 90, and a hydrostatic pressure of 275 mm. It was interesting to find that the PAA/TEOS/OA consecutive treatment slightly enhanced the wrinkle recovery but had no apparent effects on the degree of whiteness and the breaking strength of the nylon fabric. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42456.